鍩轰簬N,N-浜岀敳鍩虹挵(hu谩n)宸辫兒鐨勯珮鏁堣仛姘ㄩ叝鐧�(f膩)娉￠珨绯�

鐩寗

1. 寮曡█
2. 鑱氭皑閰櫦(f膩)娉￠珨绯绘杩�
3. N,N-浜岀敳鍩虹挵(hu谩n)宸辫兒鐨勭壒鎬�
4. 鍩轰簬N,N-浜岀敳鍩虹挵(hu谩n)宸辫兒鐨勮仛姘ㄩ叝鐧�(f膩)娉￠珨绯�
5. 鐢�(ch菐n)鍝佸弮鏁�(sh霉)鑸囨€ц兘
6. 鎳夌敤闋樺煙
7. 绲�(ji茅)璜�

1. 寮曡█

鑱氭皑閰紙Polyurethane, PU锛夋槸涓€绋唬娉涙噳鐢ㄤ簬寤虹瓚銆佹苯杌娿€佸鍏�銆佸寘瑁濈瓑闋樺煙鐨勯珮鍒嗗瓙鏉愭枡銆傚叾鐛ㄧ壒鐨勭墿鐞嗗拰鍖栧鎬ц兘浣垮叾鎴愮偤鐝�(xi脿n)浠ｅ伐妤�(y猫)涓笉鍙垨缂虹殑鏉愭枡涔嬩竴銆傝仛姘ㄩ叝鐧�(f膩)娉￠珨绯绘槸鑱氭皑閰潗鏂欑殑閲嶈绲勬垚閮ㄥ垎锛屽叾鎬ц兘鐩存帴褰遍熆鍒扮祩鐢�(ch菐n)鍝佺殑璩�(zh矛)閲�銆傛湰鏂囧皣瑭崇窗浠嬬垂鍩轰簬N,N-浜岀敳鍩虹挵(hu谩n)宸辫兒锛圢,N-Dimethylcyclohexylamine, DMCHA锛夌殑楂樻晥鑱氭皑閰櫦(f膩)娉￠珨绯伙紝鍖呮嫭鍏剁壒鎬�銆佺敘(ch菐n)鍝佸弮鏁�(sh霉)銆佹€ц兘鍙婃噳鐢ㄩ牁鍩熴€�

2. 鑱氭皑閰櫦(f膩)娉￠珨绯绘杩�

鑱氭皑閰櫦(f膩)娉￠珨绯讳富瑕佺敱澶氬厓閱�銆佺暟姘伴吀閰€佸偓鍖栧姂銆佺櫦(f膩)娉″姂銆佺┅(w臎n)瀹氬姂绛夌祫鎴�銆傚叾涓紝鍌寲鍔戝湪鐧�(f膩)娉￠亷绋嬩腑璧峰埌闂滈嵉浣滅敤锛岃兘澶犲姞閫熷弽鎳夐€熺巼锛屾帶鍒剁櫦(f膩)娉￠亷绋嬶紝寰炶€屽奖闊跨祩鐢�(ch菐n)鍝佺殑鎬ц兘銆�

2.1 澶氬厓閱�

澶氬厓閱囨槸鑱氭皑閰櫦(f膩)娉￠珨绯讳腑鐨勪富瑕佹垚鍒嗕箣涓€锛屽叾鍒嗗瓙绲�(ji茅)妲�(g貌u)涓惈鏈夊鍊嬬茎鍩猴紙-OH锛�锛岃兘澶犺垏鐣版鞍閰搁叝鍙嶆噳鐢熸垚鑱氭皑閰€傚鍏冮唶鐨勭ó椤炲拰鍒嗗瓙閲忓皪鐧�(f膩)娉￠珨绯荤殑鎬ц兘鏈夐噸瑕佸奖闊�銆�

2.2 鐣版鞍閰搁叝

鐣版鞍閰搁叝鏄仛姘ㄩ叝鐧�(f膩)娉￠珨绯讳腑鐨勫彟涓€涓昏鎴愬垎锛屽叾鍒嗗瓙绲�(ji茅)妲�(g貌u)涓惈鏈夌暟姘伴吀閰熀鍦橈紙-NCO锛�锛岃兘澶犺垏澶氬厓閱囧弽鎳夌敓鎴愯仛姘ㄩ叝銆傚父鐢ㄧ殑鐣版鞍閰搁叝鍖呮嫭浜岀暟姘伴吀閰紙TDI锛夈€佷簩鍩虹敳鐑蜂簩鐣版鞍閰搁叝锛圡DI锛夌瓑銆�

2.3 鍌寲鍔�

鍌寲鍔戝湪鑱氭皑閰櫦(f膩)娉￠珨绯讳腑璧峰埌鍔犻€熷弽鎳夌殑浣滅敤锛屽父鐢ㄧ殑鍌寲鍔戝寘鎷彅鑳洪鍖栧悎鐗�銆佹湁姗熼尗鍖栧悎鐗╃瓑銆侼,N-浜岀敳鍩虹挵(hu谩n)宸辫兒锛圖MCHA锛夋槸涓€绋珮鏁堢殑鍙旇兒椤炲偓鍖栧姂锛屽唬娉涙噳鐢ㄤ簬鑱氭皑閰櫦(f膩)娉￠珨绯讳腑銆�

2.4 鐧�(f膩)娉″姂

鐧�(f膩)娉″姂鍦ㄨ仛姘ㄩ叝鐧�(f膩)娉￠珨绯讳腑璧峰埌鐢�(ch菐n)鐢熸埃娉＄殑浣滅敤锛屽父鐢ㄧ殑鐧�(f膩)娉″姂鍖呮嫭姘淬€佺墿鐞嗙櫦(f膩)娉″姂锛堝HCFC銆丠FC绛夛級绛�銆�

2.5 绌�(w臎n)瀹氬姂

绌�(w臎n)瀹氬姂鍦ㄨ仛姘ㄩ叝鐧�(f膩)娉￠珨绯讳腑璧峰埌绌�(w臎n)瀹氭埃娉＄祼(ji茅)妲�(g貌u)鐨勪綔鐢紝甯哥敤鐨勭┅(w臎n)瀹氬姂鍖呮嫭纭呮补銆佽〃闈㈡椿鎬у姂绛�銆�

3. N,N-浜岀敳鍩虹挵(hu谩n)宸辫兒鐨勭壒鎬�

N,N-浜岀敳鍩虹挵(hu谩n)宸辫兒锛圖MCHA锛夋槸涓€绋珮鏁堢殑鍙旇兒椤炲偓鍖栧姂锛屽叿鏈変互涓嬬壒鎬э細

3.1 楂樻晥鍌寲

DMCHA鑳藉椤憲鍔犻€熷鍏冮唶鑸囩暟姘伴吀閰殑鍙嶆噳閫熺巼锛岀府鐭櫦(f膩)娉℃檪闁�锛屾彁楂樼敓鐢�(ch菐n)鏁堢巼銆�

3.2 鑹ソ鐨勬憾瑙ｆ€�

DMCHA鍦ㄥ鍏冮唶鍜岀暟姘伴吀閰腑鍏锋湁鑹ソ鐨勬憾瑙ｆ€�锛岃兘澶犲潎鍕诲垎鏁ｅ湪鐧�(f膩)娉￠珨绯讳腑锛岀⒑淇濆弽鎳夌殑鍧囧嫽鎬�銆�

3.3 浣庢埃鍛�

DMCHA鍏锋湁杓冧綆鐨勬埃鍛�锛岃兘澶犳笡灏戠敓鐢�(ch菐n)閬庣▼涓殑鐣板懗锛屾敼鍠勫伐浣滅挵(hu谩n)澧冦€�

3.4 鐠�(hu谩n)淇濇€�

DMCHA涓嶅惈閲嶉噾灞拰鏈夊鐗╄唱(zh矛)锛岀鍚堢挵(hu谩n)淇濊姹�锛岄仼鐢ㄤ簬缍犺壊鐠�(hu谩n)淇濆瀷鑱氭皑閰櫦(f膩)娉￠珨绯�銆�

4. 鍩轰簬N,N-浜岀敳鍩虹挵(hu谩n)宸辫兒鐨勮仛姘ㄩ叝鐧�(f膩)娉￠珨绯�

鍩轰簬N,N-浜岀敳鍩虹挵(hu谩n)宸辫兒鐨勮仛姘ㄩ叝鐧�(f膩)娉￠珨绯诲叿鏈夐珮鏁�銆佺挵(hu谩n)淇�銆佷綆姘ｅ懗绛夊劒(y艒u)榛�锛屽唬娉涙噳鐢ㄤ簬寤虹瓚銆佹苯杌�銆佸鍏�銆佸寘瑁濈瓑闋樺煙銆備互涓嬫槸瑭茬櫦(f膩)娉￠珨绯荤殑绲勬垚鍙婂弽鎳夋鐞�銆�

4.1 绲勬垚

4.2 鍙嶆噳姗熺悊

鍦ㄨ仛姘ㄩ叝鐧�(f膩)娉￠珨绯讳腑锛孌MCHA浣滅偤鍌寲鍔�锛岃兘澶犲姞閫熷鍏冮唶鑸囩暟姘伴吀閰殑鍙嶆噳锛岀敓鎴愯仛姘ㄩ叝銆傚弽鎳夐亷绋嬪涓嬶細

1. 澶氬厓閱囪垏鐣版鞍閰搁叝鍙嶆噳锛�
   [
   text{R-OH} + text{R’-NCO} xrightarrow{text{DMCHA}} text{R-O-CO-NH-R’}
   ]
   瑭插弽鎳夌敓鎴愯仛姘ㄩ叝閺堟銆�

2. 鐧�(f膩)娉″姂鍒嗚В锛�
   鐧�(f膩)娉″姂锛堝姘达級鑸囩暟姘伴吀閰弽鎳夌敓鎴愪簩姘у寲纰虫埃楂旓紝鐢�(ch菐n)鐢熸埃娉★細
   [
   text{H}_2text{O} + text{R’-NCO} xrightarrow{text{DMCHA}} text{R’-NH}_2 + text{CO}_2
   ]

3. 姘ｆ场绌�(w臎n)瀹�锛�
   绌�(w臎n)瀹氬姂锛堝纭呮补锛夎兘澶犵┅(w臎n)瀹氭埃娉＄祼(ji茅)妲�(g貌u)锛岄槻姝㈡埃娉＄牬瑁傛垨鍚堝苟锛岀⒑淇濈櫦(f膩)娉￠珨鐨勫潎鍕绘€с€�

5. 鐢�(ch菐n)鍝佸弮鏁�(sh霉)鑸囨€ц兘

鍩轰簬N,N-浜岀敳鍩虹挵(hu谩n)宸辫兒鐨勮仛姘ㄩ叝鐧�(f膩)娉￠珨绯诲叿鏈夊劒(y艒u)鐣扮殑鐗╃悊鍜屽寲瀛告€ц兘锛屼互涓嬫槸鍏朵富瑕佺敘(ch菐n)鍝佸弮鏁�(sh霉)鑸囨€ц兘銆�

5.1 鐢�(ch菐n)鍝佸弮鏁�(sh霉)

5.2 鎬ц兘鐗归粸

1. 楂樻姉澹撳挤搴�锛氬熀浜嶥MCHA鐨勮仛姘ㄩ叝鐧�(f膩)娉￠珨绯诲叿鏈夎純楂樼殑鎶楀寮峰害锛岃兘澶犳壙鍙楄純澶х殑澶栭儴澹撳姏锛岄仼鐢ㄤ簬寤虹瓚銆佹苯杌婄瓑闋樺煙銆�

2. 浣庡皫鐔辩郴鏁�(sh霉)锛氳┎鐧�(f膩)娉￠珨绯诲叿鏈夎純浣庣殑灏庣啽绯绘暩(sh霉)锛岃兘澶犳湁鏁堥殧鐔憋紝閬╃敤浜庝繚婧潗鏂�銆�

3. 楂橀枆瀛旂巼锛氶珮闁夊瓟鐜囪兘澶犳湁鏁堥槻姝㈡按鍒嗗拰姘ｉ珨鐨勬徊閫�锛屾彁楂樻潗鏂欑殑鑰愪箙鎬у拰绌�(w臎n)瀹氭€�銆�

4. 鑹ソ鐨勫昂瀵哥┅(w臎n)瀹氭€�锛氳┎鐧�(f膩)娉￠珨绯诲湪婧害璁婂寲涓嬪叿鏈夎壇濂界殑灏哄绌�(w臎n)瀹氭€э紝鑳藉淇濇寔褰㈢媭涓嶈畩褰�銆�

5. 寤ｆ硾鐨勪娇鐢ㄦ韩搴﹁寖鍦�锛氳┎鐧�(f膩)娉￠珨绯诲湪-40鈩冭嚦+120鈩冪殑婧害鑼冨湇鍏�(n猫i)鍏锋湁鑹ソ鐨勬€ц兘锛岄仼鐢ㄤ簬鍚勭ó鐠�(hu谩n)澧冩浠�銆�

6. 鎳夌敤闋樺煙

鍩轰簬N,N-浜岀敳鍩虹挵(hu谩n)宸辫兒鐨勮仛姘ㄩ叝鐧�(f膩)娉￠珨绯诲唬娉涙噳鐢ㄤ簬浠ヤ笅闋樺煙锛�

6.1 寤虹瓚闋樺煙

1. 淇濇韩鏉愭枡锛氳┎鐧�(f膩)娉￠珨绯诲叿鏈変綆灏庣啽绯绘暩(sh霉)鍜岄珮闁夊瓟鐜囷紝閬╃敤浜庡缓绛戝澧�銆佸眿闋傘€佸湴鏉跨瓑閮ㄤ綅鐨勪繚婧潗鏂�銆�

2. 闅旈煶鏉愭枡锛氳┎鐧�(f膩)娉￠珨绯诲叿鏈夎壇濂界殑闅旈煶鎬ц兘锛岄仼鐢ㄤ簬寤虹瓚闅旈煶澧�銆侀殧闊冲湴鏉跨瓑銆�

6.2 姹借粖闋樺煙

1. 搴ф濉厖鏉愭枡锛氳┎鐧�(f膩)娉￠珨绯诲叿鏈夐珮鎶楀寮峰害鍜岃壇濂界殑鑸掗仼鎬э紝閬╃敤浜庢苯杌婂骇妞呭～鍏呮潗鏂�銆�

2. 闅旈煶闅旂啽鏉愭枡锛氳┎鐧�(f膩)娉￠珨绯诲叿鏈夎壇濂界殑闅旈煶闅旂啽鎬ц兘锛岄仼鐢ㄤ簬姹借粖鍏�(n猫i)椋�銆佺櫦(f膩)鍕曟鑹欑瓑閮ㄤ綅鐨勯殧闊抽殧鐔辨潗鏂�銆�

6.3 瀹跺叿闋樺煙

1. 娌欑櫦(f膩)濉厖鏉愭枡锛氳┎鐧�(f膩)娉￠珨绯诲叿鏈夐珮褰堟€у拰鑹ソ鐨勮垝閬╂€�锛岄仼鐢ㄤ簬娌欑櫦(f膩)銆佸簥澧婄瓑瀹跺叿鐨勫～鍏呮潗鏂欍€�

2. 鍖呰鏉愭枡锛氳┎鐧�(f膩)娉￠珨绯诲叿鏈夎壇濂界殑绶╂矕鎬ц兘锛岄仼鐢ㄤ簬瀹跺叿鍖呰鏉愭枡銆�

6.4 鍖呰闋樺煙

1. 绶╂矕鍖呰鏉愭枡锛氳┎鐧�(f膩)娉￠珨绯诲叿鏈夎壇濂界殑绶╂矕鎬ц兘锛岄仼鐢ㄤ簬闆诲瓙鐢�(ch菐n)鍝�銆佺幓鐠冨埗鍝佺瓑鏄撶鍝佺殑绶╂矕鍖呰鏉愭枡銆�

2. 淇濇韩鍖呰鏉愭枡锛氳┎鐧�(f膩)娉￠珨绯诲叿鏈変綆灏庣啽绯绘暩(sh霉)锛岄仼鐢ㄤ簬椋熷搧銆佽棩鍝佺瓑闇€瑕佷繚婧殑鍖呰鏉愭枡銆�

7. 绲�(ji茅)璜�

鍩轰簬N,N-浜岀敳鍩虹挵(hu谩n)宸辫兒鐨勯珮鏁堣仛姘ㄩ叝鐧�(f膩)娉￠珨绯诲叿鏈夐珮鏁堝偓鍖�銆佺挵(hu谩n)淇�銆佷綆姘ｅ懗绛夊劒(y艒u)榛�锛屽唬娉涙噳鐢ㄤ簬寤虹瓚銆佹苯杌�銆佸鍏�銆佸寘瑁濈瓑闋樺煙銆傝┎鐧�(f膩)娉￠珨绯诲叿鏈夐珮鎶楀寮峰害銆佷綆灏庣啽绯绘暩(sh霉)銆侀珮闁夊瓟鐜�銆佽壇濂界殑灏哄绌�(w臎n)瀹氭€у拰寤ｆ硾鐨勪娇鐢ㄦ韩搴﹁寖鍦嶇瓑鍎�(y艒u)鐣版€ц兘锛岃兘澶犳豢瓒充笉鍚岄牁鍩熺殑闇€姹傘€傞毃钁楃挵(hu谩n)淇濊姹傜殑鎻愰珮鍜屾妧琛撶殑閫叉锛屽熀浜嶯,N-浜岀敳鍩虹挵(hu谩n)宸辫兒鐨勮仛姘ㄩ叝鐧�(f膩)娉￠珨绯诲皣鍦ㄦ湭渚嗗緱鍒版洿寤ｆ硾鐨勬噳鐢ㄥ拰鐧�(f膩)灞�銆�

鎿村睍闁辫畝:https://www.bdmaee.net/monobutyltin-oxide/

鎿村睍闁辫畝:https://www.bdmaee.net/u-cat-2024-catalyst-cas135083-57-8-sanyo-japan/

鎿村睍闁辫畝:https://www.bdmaee.net/niax-dmee-low-odor-reactive-catalysts-momentive/

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