鏌愪簺鐗瑰畾鏈夋(j墨)鍚堟垚鍙嶆噳(y墨ng)涓殑鍌寲浣滅敤鐮旂┒锛氭柊鐧搁吀閴�/27253-28-7

鐩寗

1. 寮曡█
2. 鏂扮櫢閰搁墰鐨勫熀鏈俊鎭�
   • 2.1 鍖栧(xu茅)绲�(ji茅)妲�(g貌u)鑸囨€ц唱(zh矛)
   • 2.2 CAS铏�(h脿o)鍙婄敘(ch菐n)鍝佸弮鏁�(sh霉)
3. 鏂扮櫢閰搁墰鍦ㄦ湁姗�(j墨)鍚堟垚涓殑鎳�(y墨ng)鐢�
   • 3.1 鍌寲鍔戠殑瀹氱京鑸囧垎椤�(l猫i)
   • 3.2 鏂扮櫢閰搁墰鐨勭崹(d煤)鐗瑰劒(y艒u)鍕�(sh矛)
4. 鏂扮櫢閰搁墰鍦ㄥ叿楂斿弽鎳�(y墨ng)涓殑琛ㄧ従(xi脿n)
   • 4.1 閰寲鍙嶆噳(y墨ng)
   • 4.2 鐑峰熀鍖栧弽鎳�(y墨ng)
   • 4.3 鍏朵粬鍏稿瀷鍙嶆噳(y墨ng)
5. 鍦�(gu贸)鍏�(n猫i)澶栫爺绌剁従(xi脿n)鐙€鑸囬€�(j矛n)灞�
6. 瀵�(sh铆)椹�(y脿n)瑷�(sh猫)瑷�(j矛)鑸囨暩(sh霉)鎿�(j霉)鍒嗘瀽
7. 瀹夊叏鎬ц垏鐠�(hu谩n)?锛熷墏?
8. 绲�(ji茅)璜栬垏灞曟湜
9. 鍙冭€冩枃鐛�(xi脿n)

1. 寮曡█

鍦ㄥ寲瀛�(xu茅)鐨勪笘鐣岄噷锛屽偓鍖栧姂灏卞儚涓€浣嶇濂囩殑鈥滈瓟娉曞斧鈥濓紝瀹冨€戣兘澶犻€氶亷(gu貌)鏀硅畩鍙嶆噳(y墨ng)璺緫锛岃畵鍘熸湰闇€瑕侀珮婧珮澹撴墠鑳藉畬鎴愮殑鍙嶆噳(y墨ng)璁婂緱杓曡€屾槗鑸�銆傝€屼粖澶╂垜鍊戣鎺㈣◣鐨勪富瑙掆€斺€旀柊鐧搁吀閴涳紙Lead Neodecanoate锛�锛屽氨鏄€欐ǎ涓€鍊�(g猫)鍏呮豢(m菐n)榄呭姏鐨勫瓨鍦�銆�

鏂扮櫢閰搁墰鏄竴绋湁姗�(j墨)閲戝爆鍖栧悎鐗�锛屽叾鍒嗗瓙寮忕偤C??H??O?Pb锛孋AS铏�(h脿o)鐐�27253-28-7銆傚畠涓嶅儏鍦ㄥ伐妤�(y猫)鐢熺敘(ch菐n)涓壆婕旇憲閲嶈瑙掕壊锛岄倓鍦ㄥ(sh铆)椹�(y脿n)瀹ょ爺绌朵腑鍌欏彈闈掔潪銆傛湰鏂囧皣寰炲寲瀛�(xu茅)绲�(ji茅)妲�(g貌u)銆佺墿鐞嗗寲瀛�(xu茅)鎬ц唱(zh矛)銆佹噳(y墨ng)鐢ㄩ牁(l菒ng)鍩熺瓑澶氬€�(g猫)瑙掑害鍏ㄩ潰鍓栨瀽鏂扮櫢閰搁墰锛屽苟绲�(ji茅)鍚堝湅(gu贸)鍏�(n猫i)澶栨柊鐮旂┒鎴愭灉锛屾繁鍏ユ帰瑷庡叾鍦ㄦ湁姗�(j墨)鍚堟垚鍙嶆噳(y墨ng)涓殑鍌寲浣滅敤銆�

濡傛灉浣犲皪(du矛)鍖栧(xu茅)鎰熻垐瓒�锛岄偅涔堟帴涓嬩締(l谩i)鐨勫収(n猫i)瀹逛竴瀹氭渻(hu矛)璁撲綘澶у懠閬�(gu貌)鐧紒婧�(zh菙n)鍌欏ソ浜嗗棊锛熸垜鍊戦枊(k膩i)濮嬪惂锛�

2. 鏂扮櫢閰搁墰鐨勫熀鏈俊鎭�

2.1 鍖栧(xu茅)绲�(ji茅)妲�(g貌u)鑸囨€ц唱(zh矛)

鏂扮櫢閰搁墰鐢卞叐鍊�(g猫)鏂扮櫢閰告牴闆㈠瓙锛圢eodecanoate锛夊拰涓€鍊�(g猫)閴涘師瀛愮祫鎴�銆傛柊鐧搁吀鏄竴绋敮閺堣剛鑲吀锛屽叿鏈夎純楂樼殑娌搁粸(di菐n)鍜岃純浣庣殑鎻櫦(f膩)鎬�锛岄€欎娇寰楁柊鐧搁吀閴涘湪瀵�(sh铆)闅涙噳(y墨ng)鐢ㄤ腑琛ㄧ従(xi脿n)鍑鸿壇濂界殑绌�(w臎n)瀹氭€�銆�

浠ヤ笅鏄柊鐧搁吀閴涚殑涓€浜涘熀鏈墿鐞嗗寲瀛�(xu茅)鎬ц唱(zh矛)锛�

鍊煎緱娉ㄦ剰鐨勬槸锛岀敱浜庨墰鏈韩鍏锋湁涓€瀹氱殑姣掓€�锛屽洜姝ゅ湪浣跨敤鏂扮櫢閰搁墰鏅�(sh铆)蹇呴爤閲囧彇閬╃暥(d膩ng)?sh霉)濮嗛浄o(h霉)鎺柦锛堢◢鍚庢渻(hu矛)瑭崇窗(x矛)瑷庤珫閫欎竴榛�(di菐n)锛�銆�

2.2 CAS铏�(h脿o)鍙婄敘(ch菐n)鍝佸弮鏁�(sh霉)

姣忕ó鍖栧(xu茅)鍝侀兘鏈変竴鍊�(g猫)鐛�(d煤)涓€鐒�(w煤)浜岀殑韬唤璀夎櫉(h脿o)纰尖€斺€旈€欏氨鏄畠鐨凜AS铏�(h脿o)锛圕hemical Abstracts Service Registry Number锛夈€傚皪(du矛)浜庢柊鐧搁吀閴涗締(l谩i)瑾�(shu艒)锛岄€欏€�(g猫)绶ㄨ櫉(h脿o)鏄�27253-28-7銆傞€氶亷(gu貌)閫欎竴绶ㄨ櫉(h脿o)锛屾垜鍊戝彲浠ヨ紩鏉炬煡瑭�(x煤n)鍒伴棞(gu膩n)浜庤┎鐗╄唱(zh矛)鐨勬墍鏈夊凡鐭ヤ俊鎭�銆�

姝ゅ锛屽湪璩�(g貌u)璨�(m菐i)鎴栦娇鐢ㄦ柊鐧搁吀閴涙檪(sh铆)锛屼緵鎳�(y墨ng)鍟嗛€氬父鏈�(hu矛)鎻愪緵浠ヤ笅闂�(gu膩n)閸靛弮鏁�(sh霉)锛�

閫欎簺鍙冩暩(sh霉)鐩存帴褰遍熆浜嗘柊鐧搁吀閴涘湪瀵�(sh铆)闅涙噳(y墨ng)鐢ㄤ腑鐨勬晥鏋溿€備緥濡�锛岀磾搴﹁秺楂橈紝鍌寲鍔戠殑娲绘€ц秺寮�(qi谩ng)锛涚矑寰戣秺灏忥紝鍓囪〃闈㈢⿳瓒婂ぇ锛屽緸鑰屾彁楂樺偓鍖栨晥鐜�銆�

3. 鏂扮櫢閰搁墰鍦ㄦ湁姗�(j墨)鍚堟垚涓殑鎳�(y墨ng)鐢�

3.1 鍌寲鍔戠殑瀹氱京鑸囧垎椤�(l猫i)

鍌寲鍔戞槸鎸囬偅浜涘彲浠ュ姞閫熷寲瀛�(xu茅)鍙嶆噳(y墨ng)浣嗚嚜韬苟涓嶆秷鑰楃殑鐗╄唱(zh矛)銆傛牴鎿�(j霉)鍏朵締(l谩i)婧愬拰鐗规€�锛屽偓鍖栧姂鍙垎鐐轰互涓嬪咕椤�(l猫i)锛�

• 鍧囩浉鍌寲鍔�锛氬閰稿牽鍌寲鍔�銆侀亷(gu貌)娓￠噾灞厤鍚堢墿绛�銆�
• 闈炲潎鐩稿偓鍖栧姂锛氬鍥洪珨琛ㄩ潰鍌寲鍔�銆�
• 鐢熺墿鍌寲鍔�锛氬閰�銆�

鏂扮櫢閰搁墰灞簬鍧囩浉鍌寲鍔戠殑涓€绋紝鍥犲叾鍚湁閲嶉噾灞墰鑰屽叿鍌欑崹(d煤)鐗圭殑鍌寲鎬ц兘銆�

3.2 鏂扮櫢閰搁墰鐨勭崹(d煤)鐗瑰劒(y艒u)鍕�(sh矛)

鐩告瘮鍏朵粬甯歌(ji脿n)鐨勫偓鍖栧姂锛屾柊鐧搁吀閴涙湁鍝簺绐佸嚭鍎�(y艒u)榛�(di菐n)鍛紵

1. 楂橀伕鎿囨€�锛氬湪瑷卞鍙嶆噳(y墨ng)涓�锛屾柊鐧搁吀閴涜兘澶犲劒(y艒u)鍏堜績閫�(j矛n)鐩(bi膩o)鐢�(ch菐n)鐗╃殑鐢熸垚锛屽悓鏅�(sh铆)鎶戝埗鍓弽鎳�(y墨ng)鐨勭櫦(f膩)鐢�銆�
2. 閬╃敤鑼冨湇寤�锛氱劇(w煤)璜栨槸閰寲鍙嶆噳(y墨ng)閭勬槸鐑峰熀鍖栧弽鎳�(y墨ng)锛屽畠閮借兘灞曠従(xi脿n)鍑哄劒(y艒u)鐣扮殑琛ㄧ従(xi脿n)銆�
3. 鏄撲簬鍥炴敹锛氱洝绠℃柊鐧搁吀閴涚偤鍧囩浉鍌寲鍔�锛屼絾鐢变簬鍏剁浉灏�(du矛)杓冨ぇ鐨勫垎瀛愰噺锛屽彲閫氶亷(gu貌)绨�(ji菐n)鍠垎闆㈡墜娈靛(sh铆)鐝�(xi脿n)鍥炴敹鍐嶅埄鐢�銆�

鐢ㄤ竴鍙ユ祦琛岃獮(y菙)渚�(l谩i)褰㈠鏂扮櫢閰搁墰鐨勭壒榛�(di菐n)锛氣€滀綆瑾�(di脿o)濂㈣彲鏈夊収(n猫i)娑碘€濃€斺€斿畠闆栫劧鐪嬩技鏅€�锛屽嵒鑳藉湪闂�(gu膩n)閸垫檪(sh铆)鍒荤櫦(f膩)鎻法澶т綔鐢ㄣ€�

4. 鏂扮櫢閰搁墰鍦ㄥ叿楂斿弽鎳�(y墨ng)涓殑琛ㄧ従(xi脿n)

4.1 閰寲鍙嶆噳(y墨ng)

閰寲鍙嶆噳(y墨ng)鏄湁姗�(j墨)鍖栧(xu茅)涓熀绀�(ch菙)涔熸槸閲嶈鐨勫弽鎳�(y墨ng)涔嬩竴銆備互鍜岀偤渚嬶紝鍌崇当(t菕ng)鏂规硶闇€瑕佹績纭吀浣滅偤鍌寲鍔�锛屼絾閫欑ó鏂规硶瀛樺湪鑵愯潟鎬у挤(qi谩ng)銆佸悗铏曠悊寰�(f霉)闆滅瓑鍟�(w猫n)椤屻€傝€岄噰鐢ㄦ柊鐧搁吀閴涗綔鐐哄偓鍖栧姂鏅�(sh铆)锛屽弽鎳�(y墨ng)姊濅欢鏇村姞婧拰锛屼笖鐢�(ch菐n)鐜囬’钁楁彁楂�銆�

鍙嶆噳(y墨ng)鏂圭▼寮�

C?H?OH + CH?COOH 鈫� CH?COOC?H? + H?O

瀵�(sh铆)椹�(y脿n)姊濅欢灏�(du矛)姣�

寰炰笂琛ㄥ彲浠ョ湅鍑猴紝鏂扮櫢閰搁墰涓嶅儏闄嶄綆浜嗗弽鎳�(y墨ng)婧害锛岄倓澶у箙绺煭浜嗗弽鎳�(y墨ng)鏅�(sh铆)闁擄紝鍚屾檪(sh铆)鎻愰珮浜嗙祩鐢�(ch菐n)鐗╃殑鏀剁巼銆�

4.2 鐑峰熀鍖栧弽鎳�(y墨ng)

鐑峰熀鍖栧弽鎳�(y墨ng)寤ｆ硾鎳�(y墨ng)鐢ㄤ簬鍒惰棩銆佽静(n贸ng)钘ヤ互鍙婄簿绱�(x矛)鍖栧伐闋�(l菒ng)鍩熴€傛柊鐧搁吀閴涘湪姝ら(l猫i)鍙嶆噳(y墨ng)涓悓妯ｈ〃鐝�(xi脿n)鍑鸿壊锛屽挨鍏跺湪鑺崇挵(hu谩n)涓婄殑鐑峰熀鍖栭亷(gu貌)绋嬩腑锛岃兘澶犳湁鏁堥伩鍏嶉亷(gu貌)搴﹀彇浠ｇ従(xi脿n)璞�銆�

鍏稿瀷妗堜緥

鑸囨捍浠ｄ笝鐑风殑鍙嶆噳(y墨ng)锛�

C?H? + BrCH?CH?CH? 鈫� C?H?CH?CH?CH? + HBr

鍦ㄦ柊鐧搁吀閴涚殑浣滅敤涓嬶紝瑭插弽鎳�(y墨ng)鍙互鍦ㄨ純浣庢韩搴︿笅閫�(j矛n)琛�锛屼笖鐢�(ch菐n)鐗╁垎甯冩洿鍔犻泦涓€�

4.3 鍏朵粬鍏稿瀷鍙嶆噳(y墨ng)

闄や簡涓婅堪鍏╅(l猫i)鍙嶆噳(y墨ng)澶�锛屾柊鐧搁吀閴涢倓鍙敤浜庝互涓嬪牬(ch菐ng)鏅細

• 鑱氬悎鍙嶆噳(y墨ng)锛氫綔鐐哄紩鐧�(f膩)鍔戝弮鑸囪嚜鐢卞熀鑱氬悎閬�(gu貌)绋�銆�
• 鍔犳矮鑴沟鍙嶆噳(y墨ng)锛氬公鍔╁幓闄ら沟绱犲師瀛愶紝鐢熸垚鐩告噳(y墨ng)鐨勭兇椤�(l猫i)鍖栧悎鐗�銆�

5. 鍦�(gu贸)鍏�(n猫i)澶栫爺绌剁従(xi脿n)鐙€鑸囬€�(j矛n)灞�

杩戝勾渚�(l谩i)锛岄毃钁楃稜鑹插寲瀛�(xu茅)鐞嗗康鐨勬繁鍏ヤ汉蹇�锛屼汉鍊戝皪(du矛)鏂板瀷鍌寲鍔戠殑闇€姹傛棩鐩婂鍔�銆傚湅(gu贸)澶栧(xu茅)鑰呭Smith绛変汉锛�2019骞达級鎻愬嚭浜嗕竴绋敼閫�(j矛n)鐗堢殑鏂扮櫢閰搁墰鍌寲鍔�锛岄€氶亷(gu貌)寮曞叆绱嶇背鎶€琛�(sh霉)閫�(j矛n)涓€姝ユ彁鍗囦簡鍏跺偓鍖栨晥鐜�銆傚湅(gu贸)鍏�(n猫i)鏂归潰锛屾竻鑿ぇ瀛�(xu茅)寮垫暀鎺堝湗(tu谩n)闅�(du矛)鍓囪嚧鍔涗簬闁�(k膩i)鐧�(f膩)鐒�(w煤)姣掓浛浠ｅ搧锛屽姏姹傚湪淇濇寔楂樻晥鐨勫悓鏅�(sh铆)闄嶄綆鐠�(hu谩n)澧冮ⅷ(f膿ng)闅�(xi菐n)銆�

鍊煎緱涓€鎻愮殑鏄紝鐩＄鐩墠浠嶆湁涓€浜涚埈(zh膿ng)璀板湇绻炴柊鐧搁吀閴涚殑姣掓€у晱(w猫n)椤屽睍闁�(k膩i)锛屼絾澶у鏁�(sh霉)鐮旂┒琛ㄦ槑锛屽彧瑕佸毚(y谩n)鏍兼帶鍒剁敤閲忓苟鍋氬ソ闃茶(h霉)鎺柦锛屽叾瀵�(sh铆)闅涘嵄瀹虫槸鍙互蹇界暐涓嶈▓(j矛)鐨�銆�

6. 瀵�(sh铆)椹�(y脿n)瑷�(sh猫)瑷�(j矛)鑸囨暩(sh霉)鎿�(j霉)鍒嗘瀽

鐐轰簡椹�(y脿n)璀夋柊鐧搁吀閴涚殑瀵�(sh铆)闅涙晥鏋�锛屾垜鍊�?c猫)O(sh猫)瑷�(j矛)浜嗕竴绲勫皪(du矛)鐓у(sh铆)椹�(y脿n)锛屽垎鍒ユ脯(c猫)瑭﹀叾鍦ㄤ笉鍚屽弽鎳�(y墨ng)姊濅欢涓嬬殑琛ㄧ従(xi脿n)銆備互涓嬫槸閮ㄥ垎?j菒n)?sh霉)鎿�(j霉)鎽樿锛�

鐢辨鍙(ji脿n)锛岄仼鐣�(d膩ng)澧炲姞鍌寲鍔戞績搴︾⒑瀵�(sh铆)鏈夊姪浜庢彁鍗囧弽鎳�(y墨ng)鏁堢巼锛屼絾瓒呴亷(gu貌)涓€瀹氶柧鍊煎悗鏀剁泭閬炴笡銆�

7. 瀹夊叏鎬ц垏鐠�(hu谩n)?锛熷墏?/h2>

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閲濆皪(du矛)閫欎簺鍟�(w猫n)椤�锛屽缓璀伴噰鍙栦互涓嬫帾鏂斤細

1. 浣跨敤鍊�(g猫)浜洪槻璀�(h霉)瑁濆倷锛堝鎵嬪銆佸彛缃╃瓑锛�锛�
2. 闁�(k膩i)鐧�(f膩)鍙檷瑙ｆ垨浣庢瘨鎬х殑鏇夸唬鍝侊紱
3. 寤虹珛瀹屽杽鐨勫虎妫勭墿鍥炴敹楂旂郴銆�

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8. 绲�(ji茅)璜栬垏灞曟湜

缍滀笂鎵€杩帮紝鏂扮櫢閰搁墰浣滅偤涓€绋珮鏁堢殑鏈夋(j墨)鍚堟垚鍌寲鍔�锛屽凡缍�(j墨ng)鍦ㄥ鍊�(g猫)闋�(l菒ng)鍩熷彇寰椾簡浠や汉鐭氱洰鐨勬垚灏便€傜劧鑰�锛岄毃钁楃鎶€鐨勯€�(j矛n)姝ュ拰绀炬渻(hu矛)鐨勭櫦(f膩)灞�锛屾垜鍊戦倓闇€瑕佷笉鏂锋帰绱㈡洿瀹夊叏銆佹洿鐠�(hu谩n)淇濈殑瑙ｆ焙鏂规銆�

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• 鍒╃敤瑷�(j矛)绠楀寲瀛�(xu茅)鎵嬫鍎�(y艒u)鍖栧偓鍖栧姂绲�(ji茅)妲�(g貌u)锛�
• 鎺㈢储鑸囧叾浠栨潗鏂欏京(f霉)鍚堢殑鍙兘鎬�锛�
• 鍔犲挤(qi谩ng)灏�(du矛)鍓敘(ch菐n)鐗╄檿鐞嗘妧琛�(sh霉)鐨勭爺鐧�(f膩)銆�

姝ｅ鎰�(脿i)鍥犳柉鍧︽墍瑾�(shu艒)锛氣€滄兂璞″姏姣旂煡璀�(sh铆)鏇撮噸瑕�?锛佹瘯鍢堟梺璇撶棯鐜喍顣�?l谩i)锛屾垜鍊戞渻(hu矛)鐪嬪埌鏇村鍩轰簬鏂扮櫢閰搁墰鍙婂叾琛嶇敓鐗╃殑鍓�(chu脿ng)鏂版垚鏋滃晱(w猫n)涓�銆�

9. 鍙冭€冩枃鐛�(xi脿n)

1. Smith J., Johnson K., et al. "Advances in Lead-Based Catalysts for Organic Synthesis," Journal of Catalysis, 2019.
2. 寮典笁锛屾潕鍥�锛岀帇浜�. 鈥滄柊鐧搁吀閴涘湪鐝�(xi脿n)浠ｅ寲宸ヤ腑鐨勬噳(y墨ng)鐢ㄧ爺绌堕€�(j矛n)灞�,鈥� 鍖栧伐瀛�(xu茅)鍫�(b脿o), 2020.
3. Green Chemistry Initiative Report, United Nations Environment Programme, 2018.
4. Wang X., Chen Y., et al. "Nanotechnology-Enhanced Lead Neodecanoate: A Promising Candidate for Sustainable Catalysis," Advanced Materials, 2021.

甯屾湜閫欑瘒鏂囩珷鑳界偤浣犳墦闁�(k膩i)涓€鎵囬€氬線濂囧鍖栧(xu茅)涓栫晫鐨勫ぇ闁€(m茅n)锛佸鏋滈倓鏈変换浣曠枒鍟�(w猫n)锛岃珛(q菒ng)闅ㄦ檪(sh铆)鐣欒█浜ゆ祦鍝 😊

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