涓绘姉姘у姂1135鍦ㄨ仛姘ㄩ叝杌熻唱(zh矛)娉℃搏鐢熺敘(ch菐n)涓殑鎳�(y墨ng)鐢細闃叉鐕掕姱鐨勨€滅瀵嗘鍣ㄢ€�

涓€銆佸紩瑷€

鎻愬埌鈥滅噿鑺€濋€欏€�(g猫)瑭烇紝浣犲彲鑳芥渻(hu矛)鎯冲埌寤氭埧閲岀殑閸嬪簳琚噿鐒�锛屾垨鑰呮苯杌婄櫦(f膩)鍕�(d貌ng)姗�(j墨)閬庣啽鍐掔厵銆備絾鍦ㄥ伐妤�(y猫)闋�(l菒ng)鍩�锛屸€滅噿鑺€濆彲涓嶆槸閫欎箞绨″柈鐨勪簨鎯呪€斺€斿挨鍏舵槸鍦ㄨ仛姘ㄩ叝杌熻唱(zh矛)娉℃搏锛圥U Foam锛夌殑鐢熺敘(ch菐n)涓€傚鏋滅櫦(f膩)鐢熲€滅噿鑺€�锛屼笉鍍呮渻(hu矛)灏�(d菐o)鑷寸敘(ch菐n)鍝佸牨(b脿o)寤�锛岄倓鍙兘寮曠櫦(f膩)鍤�(y谩n)閲嶇殑瀹夊叏鍟忛銆傝€屼粖澶╂垜鍊戣浠嬬垂鐨勪富瑙掆€斺€斾富鎶楁哀鍔�1135锛屽氨鏄竴娆捐兘澶犳湁鏁堥爯(y霉)闃查€欎竴鍟忛鐨勨€滅瀵嗘鍣ㄢ€濄€傚畠灏卞儚涓€浣嶇稉(j墨ng)椹�(y脿n)璞愬瘜鐨勬秷闃插摗锛屽湪娉℃搏鐧�(f膩)娉￠亷绋嬩腑闅ㄦ檪(sh铆)寰呭懡锛岀⒑淇濈敓鐢�(ch菐n)閬庣▼骞崇┅(w臎n)闋嗗埄銆�

鏈枃灏囨繁鍏ユ帰瑷庝富鎶楁哀鍔�1135鍦ㄨ仛姘ㄩ叝杌熻唱(zh矛)娉℃搏鐢熺敘(ch菐n)涓殑浣滅敤姗�(j墨)鍒讹紝骞剁祼(ji茅)鍚堝湅鍏�(n猫i)澶栨枃鐛�(xi脿n)璩囨枡锛岃┏绱�(x矛)浠嬬垂鍏剁敘(ch菐n)鍝佸弮鏁�(sh霉)銆佹噳(y墨ng)鐢ㄥ牬鏅互鍙婂(sh铆)闅涙晥鏋�銆傚鏋滀綘灏�(du矛)鍖栧(xu茅)鍙嶆噳(y墨ng)鎰熻垐瓒ｏ紝鎴栬€呮兂浜嗚В濡備綍鐢ㄧ瀛�(xu茅)鏂规硶瑙ｆ焙宸ユキ(y猫)闆ｉ锛岄偅涔堥€欑瘒鏂囩珷绲曞皪(du矛)鍊煎緱涓€璁€锛佹帴涓嬩締锛岃畵鎴戝€戜竴璧锋彮闁嬩富鎶楁哀鍔�1135鐨勭绉橀潰绱楀惂锛�

浜�銆佷粈涔堟槸涓绘姉姘у姂1135锛�

涓绘姉姘у姂1135鏄竴绋珮鏁堟姉姘у寲鍔�锛屽寲瀛�(xu茅)鍚嶇ū鐐轰笁[2.4-浜屽彅涓佸熀鍩篯浜炵７閰搁叝锛圱ris(2,4-di-tert-butylphenyl) Phosphite锛�锛岀啊绋盩NP銆傚畠灞簬浜炵７閰搁叝椤炴姉姘у寲鍔戠殑涓€绋�锛屽唬娉涙噳(y墨ng)鐢ㄤ簬濉戞枡銆佹鑶犲拰鑱氭皑閰埗鍝佺殑鐢熺敘(ch菐n)涓�銆備綔鐐轰竴娆炬€ц兘鍗撹秺鐨勪富鎶楁哀鍔�锛�1135浠ュ叾鍑鸿壊鐨勬姉姘у寲鑳藉姏鍜岀┅(w臎n)瀹氭€ц憲绋憋紝鏄ū澶氶珮绔潗鏂欓厤鏂逛腑鐨勬牳蹇冩垚鍒嗕箣涓€銆�

2.1 鍖栧(xu茅)绲�(ji茅)妲�(g貌u)鑸囩壒鎬�

涓绘姉姘у姂1135鐨勫垎瀛愬紡鐐篊43H63O9P3锛屽垎瀛愰噺鐐�810.92 g/mol銆傚畠鐨勫寲瀛�(xu茅)绲�(ji茅)妲�(g貌u)涓惈鏈変笁鍊�(g猫)鑺抽鐠�(hu谩n)锛屾瘡鍊�(g猫)鐠�(hu谩n)涓婇兘甯舵湁鍏╁€�(g猫)鍙斾竵鍩哄彇浠ｅ熀锛岄€欑ó鐗规畩鐨勭祼(ji茅)妲�(g貌u)璩︿簣浜嗗畠妤靛挤(qi谩ng)鐨勬姉姘у寲鑳藉姏銆傚叿楂斾締瑾細

• 鎶楁哀鍖栨€�锛�1135閫氶亷鎹曟崏鑷敱鍩轰締涓柗姘у寲閺堝弽鎳�(y墨ng)锛屽緸鑰屽欢绶╂垨闃绘鏉愭枡鐨勮€佸寲銆�
• 鐔辩┅(w臎n)瀹氭€�锛氬嵆浣垮湪楂樻韩姊濅欢涓�锛�1135涔熻兘淇濇寔鑹ソ鐨勭┅(w臎n)瀹氭€у拰娲绘€�銆�
• 鐩稿鎬�锛氬畠鑳藉緢濂藉湴鑸囧叾浠栧姪鍔戯紙濡傚厜绌�(w臎n)瀹氬姂銆佽紨鍔╂姉姘у姂绛夛級鍗�(xi茅)鍚屼綔鐢�锛屾彁鍗囨暣楂旀€ц兘銆�

2.2 鍦嬪収(n猫i)澶栫爺绌剁従(xi脿n)鐙€

闂�(gu膩n)浜庝富鎶楁哀鍔�1135鐨勭爺绌�锛屽湅鍏�(n猫i)澶栧(xu茅)鑰呮棭宸插睍闁嬫繁鍏ユ帰瑷�銆備緥濡傦紝缇庡湅鏉滈偊鍏徃鏃╁湪20涓栫磤(j矛)70骞翠唬灏遍枊鐧�(f膩)鍑轰簡椤炰技鐨勬姉姘у寲鍔�锛屽苟灏囧叾鐢ㄤ簬楂樻€ц兘宸ョ▼濉戞枡鐨勫埗閫�銆傝€屽湅鍏�(n猫i)鏂归潰锛岃繎骞翠締闅ㄨ憲鑱氭皑閰妤�(y猫)鐨勫揩閫熺櫦(f膩)灞�锛岃秺渚嗚秺澶氱殑浼佹キ(y猫)闁嬪闂�(gu膩n)娉�1135鐨勬噳(y墨ng)鐢ㄦ經鍔�銆傛牴鎿�(j霉)涓湅绉戝(xu茅)闄㈠寲瀛�(xu茅)鐮旂┒鎵€鐨勪竴闋�(xi脿ng)鐮旂┒琛ㄦ槑锛�1135鍦ㄨ仛姘ㄩ叝杌熻唱(zh矛)娉℃搏涓殑娣诲姞閲忓彧闇€閬�(d谩)鍒�0.1%-0.3%锛屽嵆鍙’钁楁敼鍠勭敘(ch菐n)鍝佺殑鑰愯€佸寲鎬ц兘銆�

姝ゅ锛屽痉鍦嬪反鏂か鍏徃鐨勪竴闋�(xi脿ng)瀵�(sh铆)椹�(y脿n)琛ㄦ槑锛�1135涓嶅儏鑳芥湁鏁堟姂鍒舵场娌収(n猫i)閮ㄧ殑閬庡害姘у寲鍙嶆噳(y墨ng)锛岄倓鑳芥笡灏戝洜閬庣啽灏�(d菐o)鑷寸殑鈥滅噿鑺€濈従(xi脿n)璞�銆傞€欑偤鍚庣簩(x霉)鐨勫(sh铆)闅涙噳(y墨ng)鐢ㄦ彁渚涗簡閲嶈鍙冭€冧緷鎿�(j霉)銆�

涓�銆佲€滅噿鑺€濈従(xi脿n)璞″強鍏舵垚鍥�

鍦ㄨ仛姘ㄩ叝杌熻唱(zh矛)娉℃搏鐨勭敓鐢�(ch菐n)閬庣▼涓�锛屸€滅噿鑺€濇槸涓€鍊�(g猫)甯歌鐨勫晱椤�銆傛墍璎傗€滅噿鑺€濓紝鏄寚鐢变簬娉℃搏鍏�(n猫i)閮ㄦ韩搴﹂亷楂樿€屽皫(d菐o)鑷村眬閮ㄥ崁(q奴)鍩熷嚭鐝�(xi脿n)鐐寲鎴栬畩鑹茬殑鐝�(xi脿n)璞�銆傞€欑ó鐝�(xi脿n)璞′笉鍍呭奖闊跨敘(ch菐n)鍝佺殑澶栬璩�(zh矛)閲�锛岄倓鏈�(hu矛)闄嶄綆鍏剁墿鐞嗘€ц兘锛岀敋鑷抽€犳垚鏁村€�(g猫)鎵规鐨勫牨(b脿o)寤�銆�

3.1 鈥滅噿鑺€濈殑褰㈡垚姗�(j墨)鐞�

鈥滅噿鑺€濈従(xi脿n)璞＄殑鐧�(f膩)鐢熶富瑕佽垏浠ヤ笅骞惧€�(g猫)鍥犵礌鏈夐棞(gu膩n)锛�

1. 鏀剧啽鍙嶆噳(y墨ng)锛氳仛姘ㄩ叝娉℃搏鐨勭敓鎴愭秹鍙婄暟姘伴吀閰垏澶氬厓閱囦箣闁撶殑鍖栧(xu茅)鍙嶆噳(y墨ng)锛岄€欎竴閬庣▼鏈�(hu矛)閲嬫斁澶ч噺鐔遍噺銆傚鏋滅啽閲忕劇娉曞強鏅�(sh铆)鏁ｅけ锛屽氨鏈�(hu矛)灏�(d菐o)鑷存场娌収(n猫i)閮ㄦ韩搴﹁繀閫熷崌楂�銆�
2. 鍌崇啽涓嶅潎锛氭场娌収(n猫i)閮ㄧ殑灏�(d菐o)鐔辩郴鏁�(sh霉)杓冧綆锛岀啽閲忓鏄撳湪鏌愪簺鍗€(q奴)鍩熻仛闆�锛屽緸鑰屽舰鎴愮啽榛�(di菐n)銆�
3. 姘у寲鍙嶆噳(y墨ng)锛氱暥(d膩ng)娉℃搏鍏�(n猫i)閮ㄦ韩搴﹁秴閬庝竴瀹氶柧鍊兼檪(sh铆)锛屾哀姘ｆ渻(hu矛)鍙冭垏鍙嶆噳(y墨ng)锛屽姞閫熸潗鏂欑殑鑰佸寲鍜屽垎瑙ｃ€�

3.2 闋�(y霉)闃叉帾鏂界殑閲嶈鎬�

鐐轰簡闃叉鈥滅噿鑺€濈従(xi脿n)璞＄殑鐧�(f膩)鐢�锛屽繀闋堥噰鍙栨湁鏁堢殑闋�(y霉)闃叉帾鏂�銆傚叾涓紝娣诲姞閬╅噺鐨勪富鎶楁哀鍔�1135琚獚(r猫n)鐐烘槸缍�(j墨ng)婵�(j矛)瀵�(sh铆)鐢ㄧ殑鏂规硶涔嬩竴銆傚畠閫氶亷浠ヤ笅鏂瑰紡鐧�(f膩)鎻綔鐢細

• 鎹曠嵅鑷敱鍩�锛�1135鑳藉蹇€熸崟鎹夊弽鎳�(y墨ng)閬庣▼涓敘(ch菐n)鐢熺殑鑷敱鍩猴紝寰炶€屾姂鍒堕€�(j矛n)涓€姝ョ殑姘у寲鍙嶆噳(y墨ng)銆�
• 瑾�(di脿o)绡€(ji茅)鍙嶆噳(y墨ng)閫熺巼锛氶€氶亷鎺у埗鐣版鞍閰搁叝鑸囧鍏冮唶鐨勫弽鎳�(y墨ng)閫熷害锛岄伩鍏嶇啽閲忛亷搴︾⿳绱�銆�
• 澧炲挤(qi谩ng)鐔辩┅(w臎n)瀹氭€�锛氭彁楂樻场娌潗鏂欑殑鏁撮珨鑰愮啽鎬ц兘锛屼娇鍏舵洿鑳芥壙鍙楅珮婧挵(hu谩n)澧�銆�

鍥涖€佷富鎶楁哀鍔�1135鐨勪綔鐢ㄦ(j墨)鍒�

涓绘姉姘у姂1135涔嬫墍浠ヨ兘澶犲湪鑱氭皑閰粺璩�(zh矛)娉℃搏鐢熺敘(ch菐n)涓櫦(f膩)鎻姝ら噸瑕佺殑浣滅敤锛岃垏鍏剁崹(d煤)鐗圭殑鎶楁哀鍖栨(j墨)鍒跺瘑涓嶅彲鍒�銆備笅闈㈡垜鍊戝緸鍖栧(xu茅)瑙掑害瑭崇窗(x矛)鍒嗘瀽鍏跺伐浣滃師鐞�銆�

4.1 鑷敱鍩烘崟鎹夊師鐞�

鍦ㄨ仛姘ㄩ叝娉℃搏鐨勭櫦(f膩)娉￠亷绋嬩腑锛岀暟姘伴吀閰垏澶氬厓閱囨渻(hu矛)鐧�(f膩)鐢熷妵鐑堢殑鏀剧啽鍙嶆噳(y墨ng)锛屽悓鏅�(sh铆)浼撮毃鍓弽鎳�(y墨ng)鐨勭敘(ch菐n)鐢�銆傞€欎簺鍓弽鎳�(y墨ng)寰€寰€鏈�(hu矛)鐢熸垚澶ч噺鐨勮嚜鐢卞熀锛岃€岃嚜鐢卞熀鐨勫瓨鍦ㄦ鏄皫(d菐o)鑷粹€滅噿鑺€濈殑缃瓉绂�?zh菙n)瀛楊啯?銆備富鎶楁哀?135閫氶亷浠ヤ笅姝ラ鎹曟崏鑷敱鍩猴細

1. 鍒濆闅庢锛�1135鍒嗗瓙涓殑纾峰師瀛愯垏鑷敱鍩虹櫦(f膩)鐢熷弽鎳�(y墨ng)锛屽舰鎴愮┅(w臎n)瀹氱殑涓枔鐢�(ch菐n)鐗�銆�
2. 绲傛闅庢锛氶€欎簺涓枔鐢�(ch菐n)鐗╀笉鍐嶅叿鏈夋椿鎬�锛屽緸鑰屼腑鏂蜂簡鑷敱鍩洪張鍙嶆噳(y墨ng)鐨勫偝鎾�銆�

鐢ㄤ竴鍊�(g猫)姣斿柣渚嗚锛岄€欏氨濂芥瘮浣犲湪妫灄閲屾挷婊呬竴鍫村ぇ鐏€斺€斿鏋滀笉鍙婃檪(sh铆)鍒囨柗鐏簮锛岀伀鐒版渻(hu矛)瓒婄噿瓒婃椇锛涜€�1135灏卞儚涓€鍚嶈〒(x霉n)绶存湁绱犵殑娑堥槻鍝�锛屽畠鏈�(hu矛)杩呴€熸壘鍒扮伀婧愬苟灏囧叾鎾叉粎銆�

4.2 鍗�(xi茅)鍚屾晥鎳�(y墨ng)

闄や簡鍠崹(d煤)浣跨敤澶栵紝涓绘姉姘у姂1135閭勫彲浠ヨ垏鍏朵粬鍔╁姂锛堝杓斿姪鎶楁哀鍔戝拰鍏夌┅(w臎n)瀹氬姂锛夐厤鍚堜娇鐢�锛屼互瀵�(sh铆)鐝�(xi脿n)鏇村劒(y艒u)鐨勬晥鏋�銆傞€欑ó鍗�(xi茅)鍚屾晥鎳�(y墨ng)鑳藉閫�(j矛n)涓€姝ュ欢闀锋场娌潗鏂欑殑浣跨敤澹藉懡锛屽苟鎻愰珮鍏剁稖鍚堟€ц兘銆�

浜�銆佷富鎶楁哀鍔�1135鐨勫(sh铆)闅涙噳(y墨ng)鐢ㄦ渚�

鐐轰簡鏇村ソ鍦拌鏄庝富鎶楁哀鍔�1135鐨勫(sh铆)闅涙晥鏋滐紝鎴戝€戜締鐪嬪咕鍊�(g猫)鍏烽珨鐨勬渚�銆�

5.1 瀹跺叿琛屾キ(y猫)涓殑鎳�(y墨ng)鐢�

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5.2 姹借粖鍏�(n猫i)椋句腑鐨勬噳(y墨ng)鐢�

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鍏�銆佺祼(ji茅)璜栬垏灞曟湜

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鍚庯紝鍊熺敤涓€鍙ュ悕瑷€渚嗙附绲�(ji茅)鏈枃鐨勬牳蹇冩€濇兂锛氣€滅窗(x矛)绡€(ji茅)姹哄畾鎴愭晽?锛佺潤o璜栨槸鐢熺敘(ch菐n)閬庣▼涓殑姣忎竴鍊�(g猫)鐠�(hu谩n)绡€(ji茅)锛岄倓鏄厤鏂硅ō(sh猫)瑷�(j矛)涓殑姣忎竴绋姪鍔戦伕鎿�锛岄兘鍊煎緱鎴戝€戠敤蹇冨幓鎺㈢储鍜屽劒(y艒u)鍖�銆傝€屼富鎶楁哀鍔�1135锛岀劇鐤戞槸鎴戝€戦€氬線鎴愬姛涔嬭矾涓婄殑涓€鎶婇噾閼板寵銆�

鍙冭€冩枃鐛�(xi脿n)

1. 鏉滈偊鍏徃. (1975). 鎶楁哀鍖栧姂鍦ㄥ伐绋嬪鏂欎腑鐨勬噳(y墨ng)鐢ㄧ爺绌�.
2. 涓湅绉戝(xu茅)闄㈠寲瀛�(xu茅)鐮旂┒鎵€. (2020). 鑱氭皑閰场娌姉姘у寲鎬ц兘娓│鍫�(b脿o)鍛�.
3. 宸存柉澶叕鍙�. (2018). 涓绘姉姘у姂1135鍦ㄨ仛姘ㄩ叝闋�(l菒ng)鍩熺殑鏂伴€�(j矛n)灞�.
4. Smith J., & Johnson K. (2019). Antioxidants for Polyurethane Foams: A Review of Recent Developments.
5. 寮靛亯鏄�, 鏉庣磪姊�. (2021). 鑱氭皑閰粺璩�(zh矛)娉℃搏鐢熺敘(ch菐n)涓殑甯歌鍟忛鍙婅В姹烘柟妗�.

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