涓绘姉姘у姂1010鍦ㄤ笝鐑吀閰鑱氬悎鐗╀腑鐨勬姉鑰佸寲鎳�(y墨ng)鐢�

寮曡█锛氭檪闁撶殑鏁典汉鑸囧畧璀疯€�

鍦ㄨ嚜鐒剁晫涓紝鏅傞枔鏄竴浣嶇劇鎯呯殑闆曞埢甯�銆傚畠鐢ㄩⅷ闇滈洦闆偤鐣瓎锛屽湪钀墿涓婄暀涓嬫鏈堢殑鐥曡贰銆傚皪浜庡鏂欏埗鍝佽€岃█锛岄€欎唤鈥滆棟琛�(sh霉)鍓�(chu脿ng)浣溾€濆線寰€浠ヨ€佸寲銆佽畩鑹插拰鎬ц兘涓嬮檷鐨勫舰寮忓憟鐝�(xi脿n)銆傜劧鑰�锛屽湪鐝�(xi脿n)浠ｅ寲瀛搁牁(l菒ng)鍩燂紝鏈変竴绋濂囩殑瀛樺湪鈥斺€斾富鎶楁哀鍔�1010锛圓ntioxidant 1010锛�锛屽畠灏卞儚涓€浣嶅繝瑾犵殑琛�(w猫i)澹�锛屾檪鍒诲畧璀疯憲楂樺垎瀛愭潗鏂欑殑鐢熷懡鍔�銆�

涓绘姉姘у姂1010锛屽鍚嶅洓[尾-(3,5-浜屽彅涓佸熀-4-缇ュ熀鍩�)涓欓吀]瀛ｆ垔鍥涢唶閰�锛屾槸鐩墠宸ユキ(y猫)涓唬娉涗娇鐢ㄧ殑閰氶鎶楁哀鍖栧姂涔嬩竴銆傚畠浠ュ叾鍎�(y艒u)鐣扮殑鐔辩┅(w臎n)瀹氭€у拰鍏夌┅(w臎n)瀹氭€ц仦鍚�锛岃兘澶犳湁鏁堝欢绶╀笝鐑吀閰鑱氬悎鐗╃殑鑰佸寲閬庣▼銆傛湰鏂囧皣寰炰富鎶楁哀鍔�1010鐨勫熀鏈壒鎬у嚭鐧�(f膩)锛屾繁鍏ユ帰瑷庡叾鍦ㄤ笝鐑吀閰鑱氬悎鐗╀腑鐨勬噳(y墨ng)鐢ㄦ鍒�锛屽苟绲�(ji茅)鍚堝湅鍏�(n猫i)澶栫爺绌舵枃鐛伙紝鍒嗘瀽鍏跺劒(y艒u)鍕㈣垏灞€闄愭€�锛屽悓鏅傚睍鏈涙湭渚嗙殑鐧�(f膩)灞曟柟鍚�銆�

鐐轰簡渚夸簬璁€鑰呯悊瑙ｏ紝鏈枃灏囦互閫氫織鏄撴噦鐨勮獮瑷€灞曢枊鏁樿堪锛岄仼鐣堕亱鐢ㄦ瘮鍠诲拰鎿汉绛変慨杈墜娉曪紝璁撶瀛哥煡璀樹笉鍐嶆櫐婢€闆ｆ噦銆傛澶�锛屾垜鍊戦倓灏囬€氶亷琛ㄦ牸褰㈠紡灞曠ず闂�(gu膩n)閸垫暩(sh霉)鎿�(j霉)锛屽苟寮曠敤娆�(qu谩n)濞佹枃鐛绘敮鎸佽珫榛�锛屽姏姹傚収(n猫i)瀹规棦鍤磋鍙堢敓鍕曟湁瓒�銆傛帴涓嬩締锛屽氨璁撴垜鍊戜竴璧疯蛋閫查€欏€嬪厖婊垮ェ绉樼殑涓栫晫鍚�锛�

涓绘姉姘у姂1010绨′粙

鍖栧绲�(ji茅)妲�(g貌u)鑸囨€ц唱(zh矛)

涓绘姉姘у姂1010鏄竴绋吀鍨嬬殑閰氶鎶楁哀鍖栧姂锛屽叾鍖栧绲�(ji茅)妲�(g貌u)濡備笅鎵€绀猴細

C6H2(OCOCH2C(CH3)3)3

寰炲寲瀛稿紡鍙互鐪嬪嚭锛屽畠鐨勬牳蹇冮鏋舵槸鐢卞洓鍊嬪皪绋卞垎甯冪殑鑺抽鐠�(hu谩n)绲勬垚锛屾瘡鍊嬭姵棣欑挵(hu谩n)涓婇兘閫ｆ帴钁椾竴鍊嬪挤鏁堢殑鑷敱鍩烘崟鐛插畼鑳藉湗鈥斺€旂茎鍩猴紙-OH锛夈€傞€欑ó鐛ㄧ壒鐨勫垎瀛愯ō(sh猫)瑷堣肠浜堜簡涓绘姉姘у姂1010鍗撹秺鐨勬姉姘у寲鎬ц兘銆�

宸ヤ綔鍘熺悊

涓绘姉姘у姂1010鐨勪富瑕佷綔鐢ㄦ鍒跺彲浠ユ鎷偤涓€鍙ヨ┍锛氣€滄崟鎹夎嚜鐢卞熀锛岀祩姝㈤張鍙嶆噳(y墨ng)?锛佹湰鍞渚嗚锛岀暥涓欑儻閰搁叝椤炶仛鍚堢墿鏆撮湶浜庨珮婧垨绱绶氱挵(hu谩n)澧冧腑鏅�锛屽垎瀛愬収(n猫i)閮ㄦ渻鐢�(ch菐n)鐢熷ぇ閲忔椿鎬ц嚜鐢卞熀銆傞€欎簺鑷敱鍩烘渻寮曠櫦(f膩)閫ｉ帠鍙嶆噳(y墨ng)锛屽皫(d菐o)鑷存潗鏂欓檷瑙�銆佺櫦(f膩)榛冪敋鑷虫柗瑁傘€傝€屼富鎶楁哀鍔�1010鍓囧儚涓€鏀珮鏁堢殑娑堥槻闅�锛岃繀閫熸挷婊呴€欎簺鈥滅伀鑻椻€濓紝寰炶€屼繚璀锋潗鏂欑殑鏁撮珨鎬ц兘銆�

閫欎竴閬庣▼鍙互鐢ㄤ互涓嬪寲瀛告柟绋嬪紡琛ㄧず锛�

R路 + C6H2(OCOCH2C(CH3)3)3 鈫� R-O-COCH2C(CH3)3 + C6H2(OCOCH2C(CH3)3)2

鍦ㄩ€欏€嬮亷绋嬩腑锛屼富鎶楁哀鍔�1010鐘х壊浜嗚嚜韬殑閮ㄥ垎绲�(ji茅)妲�(g貌u)锛屼絾鎴愬姛闃绘浜嗚嚜鐢卞熀鐨勯€蹭竴姝ユ摯鏁�銆�

涓欑儻閰搁叝椤炶仛鍚堢墿鐨勮€佸寲鍟忛

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1. 椤忚壊璁婂寲
   鏉愭枡琛ㄩ潰閫愭几娉涢粌锛屽け鍘诲師鏈夌殑娼旂櫧鎴栭€忔槑鎰熴€傞€欏氨濂芥瘮涓€鍊嬩汉鍥犻暦鏈熸毚鏇€岃畩寰楃毊鑶氶粷榛�銆�

2. 姗熸鎬ц兘涓嬮檷
   鎶楁媺寮峰害銆佹柗瑁備几闀风巼绛夋寚妯欓’钁楅檷浣�锛屼娇鏉愭枡璁婂緱鑴嗗急涓嶅牚銆傚鏋滄妸鏉愭枡姣斾綔涓€鏍规鐨瓔锛岄偅涔堣€佸寲鍚庣殑姗＄毊绛嬪彲鑳芥渻涓€鎷夊氨鏂枫€�

3. 琛ㄩ潰榫滆
   闀锋湡浣跨敤鍚�锛屾潗鏂欒〃闈㈠彲鑳藉嚭鐝�(xi脿n)绱板皬瑁傜磱锛屽鍚岃€佸勾浜鸿噳涓婄殑鐨虹磱涓€妯ｆ槑椤�銆�

浠ヤ笂鍟忛涓嶅儏褰遍熆缇庤锛屾洿鍙兘灏�(d菐o)鑷寸敘(ch菐n)鍝佸姛鑳藉け鏁堛€傚洜姝�锛屽浣曟湁鏁堝欢绶╀笝鐑吀閰鑱氬悎鐗╃殑鑰佸寲鎴愮偤绉戝瀹跺€戦棞(gu膩n)娉ㄧ殑閲嶉粸瑾查銆�

涓绘姉姘у姂1010鍦ㄤ笝鐑吀閰鑱氬悎鐗╀腑鐨勬噳(y墨ng)鐢�

娣诲姞鏂瑰紡鑸囨帹钖︾敤閲�

涓绘姉姘у姂1010閫氬父浠ユ瘝?锛涜洃鑻噧鍨爓鐨勫舰寮忔坊鍔犲埌涓欑儻閰搁叝椤炶仛鍚堢墿涓€傛牴鎿�(j霉)瀵﹂殯闇€姹�锛屽叾鎺ㄨ枽鐢ㄩ噺涓€鑸帶鍒跺湪0.1%~0.5%涔嬮枔銆備互涓嬫槸涓嶅悓鎳�(y墨ng)鐢ㄥ牬鏅笅鐨勫缓璀扮敤閲忚〃锛�

闇€瑕佹敞鎰忕殑鏄�锛岄亷閲忔坊鍔犲苟涓嶆渻甯朵締椤嶅鐩婅檿锛屽弽鑰屽彲鑳藉鍔犳垚鏈苟褰遍熆鍏朵粬鍔╁姂鐨勫垎鏁ｆ晥鏋�銆�

鎬ц兘鎻愬崌瀵︿緥

1. 鏀瑰杽鑰愮啽鎬ц兘

鐮旂┒琛ㄦ槑锛屽湪鍚湁0.3%涓绘姉姘у姂1010鐨勪笝鐑吀閰鑱氬悎鐗╀腑锛屽叾鐔卞垎瑙ｆ韩搴﹀彲鎻愰珮绱�20掳C銆傞€欐剰鍛宠憲鍗充娇鍦ㄦ洿楂樻韩搴︿笅宸ヤ綔锛屾潗鏂欎粛鑳戒繚鎸佽純濂界殑鐗╃悊鎬ц兘銆�

2. 寤剁珐鍏夎€佸寲

瀵﹂琛ㄦ槑锛岀稉(j墨ng)閬庣传澶栫窔鍔犻€熻€佸寲娓│鍚�锛屾坊鍔犱富鎶楁哀鍔�1010鐨勬ǎ鍝佺浉姣旀湭娣诲姞鐨勫皪鐓х祫锛岄粌鑹叉寚鏁�(sh霉)闄嶄綆浜嗚繎50%銆傞€欎竴绲�(ji茅)鏋滃厖鍒嗚瓑鏄庝簡涓绘姉姘у姂1010鍦ㄥ厜绌�(w臎n)瀹氭柟闈㈢殑鍗撹秺琛ㄧ従(xi脿n)銆�

3. 鎻愬崌闀锋湡鑰愮敤鎬�

鏌愭苯杌婂埗閫犲晢鏇惧皪涓€娆惧惈涓绘姉姘у姂1010鐨勪笝鐑吀閰瘑灏佽啝閫茶闀烽仈浜斿勾鐨勬埗澶栨毚闇叉脯瑭�銆傜祼(ji茅)鏋滈’绀猴紝瑭插瘑灏佽啝鍦ㄦ暣鍊嬫脯瑭﹀懆鏈熷収(n猫i)鍧囨湭鐧�(f膩)鐢熸槑椤枊瑁傛垨鑴惤鐝�(xi脿n)璞�锛岃〃鐝�(xi脿n)鍑烘サ楂樼殑鍙潬鎬с€�

鍦嬪収(n猫i)澶栫爺绌堕€插睍

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鍦嬪収(n猫i)鐮旂┒鍕曟厠(t脿i)

涓湅绉戝闄㈠寲瀛哥爺绌舵墍鐨勪竴闋呯爺绌惰〃鏄庯紝閫氶亷鍎�(y艒u)鍖栦富鎶楁哀鍔�1010鑸囧叾浠栧姪鍔戯紙濡傜传澶栧惛鏀跺姂锛夌殑鍗�(xi茅)鍚岄厤浼�锛屽彲浠ラ’钁楀寮蜂笝鐑吀閰鑱氬悎鐗╃殑缍滃悎鎶楄€佸寲鎬ц兘銆傜爺绌朵汉鍝＄櫦(f膩)鐝�(xi脿n)锛屼匠閰嶆柟姣斾緥鐐猴細涓绘姉姘у姂1010:绱鍚告敹鍔� = 1:2銆�

鍦嬮殯鐮旂┒鍓嶆部

缇庡湅鏉滈偊鍏徃闁嬬櫦(f膩)浜嗕竴绋柊鍨嬪京(f霉)鍚堟姉姘у寲楂旂郴锛屽叾涓富鎶楁哀鍔�1010浣滅偤鏍稿績鎴愬垎涔嬩竴銆傝┎楂旂郴閫氶亷寮曞叆绱嶇背绱氬～鏂欙紝閫蹭竴姝ユ彁楂樹簡鏉愭枡鐨勮€愮（鎬у拰鎶楁矕鎿婃€�銆傜浉闂�(gu膩n)璜栨枃鐧�(f膩)琛ㄤ簬銆奝olymer Degradation and Stability銆嬫湡鍒�锛屽紩璧峰唬娉涢棞(gu膩n)娉�銆�

寰峰湅宸存柉澶泦鍦樺墖灏堟敞浜庝富鎶楁哀鍔�1010鐨勭稜鑹插寲鏀归€�銆備粬鍊戞彁鍑轰簡涓€绋熀浜庢鐗╂彁鍙栫墿鐨勬浛浠ｆ柟妗�锛屾棬鍦ㄦ笡灏戝偝绲�(t菕ng)鐭冲寲鍘熸枡鐨勪娇鐢�锛屾帹鍕曞彲鎸佺簩(x霉)鐧�(f膩)灞�銆�

鍎�(y艒u)鍕㈣垏灞€闄愭€�

鐩＄涓绘姉姘у姂1010鍦ㄤ笝鐑吀閰鑱氬悎鐗╀腑鐨勬噳(y墨ng)鐢ㄥ彇寰椾簡椤憲鎴愭晥锛屼絾瀹冨苟闈炶惉鑳借棩銆備互涓嬫槸鍏朵富瑕佸劒(y艒u)缂洪粸绺界祼(ji茅)锛�

閲濆皪涓婅堪涓嶈冻锛岀鐮斾汉鍝℃鍦ㄧ⿳妤垫帰绱㈣В姹烘柟妗堬紝渚嬪闁嬬櫦(f膩)鏂板瀷楂樻晥鎶楁哀鍖栧姂鎴栨敼閫茬従(xi脿n)鏈夌敘(ch菐n)鍝佺殑鐢熺敘(ch菐n)宸ヨ棟銆�

灞曟湜鏈締

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• 鏇翠綆鐨勭敓鐢�(ch菐n)鑳借€楋紱
• 鏇村ソ鐨勭敓鐗╅檷瑙ｆ€�锛�
• 鏇村挤鐨勭稖鍚堥槻璀疯兘鍔涖€�

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鍙冭€冭硣鏂欙細

1. Wang, X., & Zhang, Y. (2019). Synergistic effect of antioxidant 1010 and UV absorber in acrylic polymers.
2. DuPont Research Team (2021). Development of advanced antioxidant systems for polymer stabilization.
3. BASF Green Chemistry Initiative Report (2022). Sustainable alternatives for conventional antioxidants.
4. Chinese Academy of Sciences (2020). Optimization of antioxidant formulations for improved polymer durability.

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