鎶楁哀鍔�330鍦ㄤ氦鑱�(li谩n)鑱氫箼鐑疿LPE闆荤簻绲曠罚鏉愭枡涓殑鎳�(y墨ng)鐢�

涓€銆佸紩瑷€锛氳畵闆荤窔鈥滄案钁嗛潚鏄モ€濈殑绉樺瘑姝﹀櫒

鍦ㄧ従(xi脿n)浠ｇぞ鏈冿紝闆诲姏濡傚悓琛€娑蹭竴鑸搏绌夸簬鎴戝€戠殑鐢熸椿锛岃€岄浕绾滃墖鍍忚绠′竴妯ｈ矤璨�(z茅)杓搁€侀€欒偂鍔涢噺銆傜劧鑰�锛屽氨鍍忎汉椤炵殑琛€绠℃渻鍥犺€佸寲鑰屽嚭鐝�(xi脿n)鍟忛锛岄浕绾滀篃闈㈣嚚钁楅浼肩殑棰�(f膿ng)闅€斺€旈毃钁楁檪闁撴帹绉�锛屽叾鍏�(n猫i)閮ㄦ潗鏂欏彲鑳藉洜姘у寲浣滅敤鑰屾€ц兘涓嬮檷锛岀敋鑷冲皫(d菐o)鑷存暣鍊嬬郴绲�(t菕ng)澶辨晥銆傜偤浜嗗欢闀烽浕绾滅殑澹藉懡骞剁⒑淇濆叾绌�(w臎n)瀹氶亱琛�锛岀瀛�(xu茅)瀹跺€戠爺鐧�(f膩)浜嗕竴绋濂囩殑鐗╄唱(zh矛)鈥斺€旀姉姘у姂330锛圓ntioxidant 330锛夛紝瀹冪尪濡備竴浣嶉毐褰㈢殑瀹堣鑰�锛岄粯榛樼偤闆荤簻鎻愪緵闃茶锛岃畵瀹冨€戔€滄案钁嗛潚鏄モ€濄€�

1.1 浠€涔堟槸鎶楁哀鍔�330锛�

鎶楁哀鍔�330鏄竴绋兒椤炴姉姘у寲鍔戯紝鍖栧(xu茅)鍚嶇ū鐐篘,N’-闆�-(尾-钀樺熀)-灏嶄簩鑳猴紙N,N’-bis(尾-naphthyl)-p-phenylenediamine锛�銆傚畠鐨勫垎瀛愮祼(ji茅)妲�(g貌u)璩︿簣浜嗗畠寮峰ぇ鐨勬姉姘у寲鑳藉姏锛岃兘澶犳湁鏁堟姂鍒惰仛鍚堢墿鏉愭枡涓殑鑷敱鍩洪張寮忓弽鎳�(y墨ng)锛屽緸鑰屽欢绶╂垨闃绘鏉愭枡鐨勮€佸寲閬庣▼銆傜敤閫氫織鐨勮┍渚嗚锛屾姉姘у姂330灏辨槸涓€绋€滈槻鑵愬姂鈥�锛屽彧涓嶉亷瀹冪殑浣滅敤灏嶈薄涓嶆槸椋熷搧锛岃€屾槸濉戞枡鍜屾鑶犵瓑楂樺垎瀛愭潗鏂�銆�

1.2 XLPE闆荤簻鐨勯噸瑕佹€�

浜よ伅(li谩n)鑱氫箼鐑紙Cross-linked Polyethylene锛岀啊绋盭LPE锛夋槸鐩墠楂樺鍜岃秴楂樺闆荤簻涓父鐢ㄧ殑绲曠罚鏉愭枡涔嬩竴銆傝垏鏅€氳仛涔欑儻鐩告瘮锛孹LPE閫氶亷鍖栧(xu茅)浜よ伅(li谩n)宸ヨ棟褰㈡垚浜嗕笁缍恫(w菐ng)鐙€绲�(ji茅)妲�(g貌u)锛岄€欑ó绲�(ji茅)妲�(g貌u)椤憲鎻愰珮浜嗘潗鏂欑殑鑰愮啽鎬у拰姗熸寮峰害锛屼娇鍏舵垚鐐虹悊鎯崇殑閬告搰銆傜劧鑰岋紝鍗充究濡傛鈥滃挤澹€�锛孹LPE浠嶇劧鐒℃硶瀹屽叏閬垮厤姘у寲甯朵締鐨勬悕瀹炽€傚洜姝�锛屽湪鍒堕€犻亷绋嬩腑娣诲姞閬╅噺鐨勬姉姘у姂330椤緱灏ょ偤閲嶈銆�

鎺ヤ笅渚嗭紝鎴戝€戝皣娣卞叆鎺㈣◣鎶楁哀鍔�330鐨勪綔鐢ㄦ鐞�銆佺敘(ch菐n)鍝佸弮鏁�(sh霉)浠ュ強濡備綍鍦╔LPE闆荤簻涓櫦(f膩)鎻匠鏁堟灉銆傚鏋滀綘灏嶉€欎簺瑭遍鎰熻垐瓒�锛岃珛绻肩簩(x霉)闁辫畝鍚�锛佺暍绔�锛岀瀛�(xu茅)鐨勪笘鐣岀附鏄厖婊块鍠�锛岃€屾姉姘у姂330鐨勬晠浜嬫墠鍓涘墰闁嬪銆�

浜屻€佹姉姘у姂330鐨勪綔鐢ㄦ鐞嗭細寰炲井瑙€鍒板畯瑙€鐨勪繚璀�

瑕佺悊瑙ｆ姉姘у姂330鐐轰綍濡傛閲嶈锛屾垜鍊戦鍏堥渶瑕佷簡瑙ｆ哀鍖栧弽鎳�(y墨ng)鐨勫熀鏈師鐞�銆傜啊鍠締瑾�锛屾哀鍖栨槸鎸囩墿璩�(zh矛)鑸囨哀姘ｇ櫦(f膩)鐢熷寲瀛�(xu茅)鍙嶆噳(y墨ng)鐨勯亷绋嬶紝鑰岄€欎竴閬庣▼寰€寰€浼撮毃钁楄嚜鐢卞熀鐨勭敘(ch菐n)鐢�銆傝嚜鐢卞熀鏄竴绋叿鏈夋湭鎴愬皪闆诲瓙鐨勫師瀛愭垨鍒嗗瓙锛屽畠鍊戦潪?锛涢挻S涓斿鏄撳紩鐧�(f膩)閫ｉ帠鍙嶆噳(y墨ng)锛岀祩灏�(d菐o)鑷存潗鏂欐€ц兘涓嬮檷銆傚皪浜庨浕绾滅禃绶ｆ潗鏂欒€岃█锛屾哀鍖栦笉鍍呮渻褰遍熆鍏堕浕姘ｆ€ц兘锛岄倓鍙兘灏�(d菐o)鑷存姊版€ц兘鎯″寲锛岄€茶€屽▉鑴呮暣鍊嬮浕鍔涚郴绲�(t菕ng)鐨勫畨鍏�銆�

2.1 鑷敱鍩洪張寮忓弽鎳�(y墨ng)鐨勭牬澹炲姏

鎯宠薄涓€涓嬶紝浣犵殑鎴块枔鍦版澘涓婃暎钀借憲瑷卞鐏煷妫�锛屽彧瑕佹湁涓€鏍硅榛炵噧锛屽氨鍙兘寮曠櫦(f膩)涓€鍫村ぇ鐏�銆傚悓妯ｅ湴锛岃嚜鐢卞熀涓€鏃﹀舰鎴愶紝灏辨渻鍍忕伀鏌翠竴妯ｈ繀閫熷偝鎾兘閲�锛岃垏鍏朵粬鍒嗗瓙纰版挒骞剁敓鎴愭洿澶氱殑鑷敱鍩�銆傞€欏€嬮亷绋嬭绋辩偤鑷敱鍩洪張寮忓弽鎳�(y墨ng)锛屽畠鏄哀鍖栨悕鍌风殑鏍稿績姗熷埗銆傚叿楂斿埌XLPE闆荤簻涓紝閫欑ó鍙嶆噳(y墨ng)鏈冨皫(d菐o)鑷翠互涓嬪悗鏋滐細

• 鍒嗗瓙閺堟柗瑁�锛氶珮鍒嗗瓙閺堥€愭几璁婄煭锛屾潗鏂欒畩寰楄剢寮便€�
• 浜よ伅(li谩n)瀵嗗害闄嶄綆锛氬師鏈穵瀵嗙殑涓夌董缍�(w菐ng)绲�(lu貌)绲�(ji茅)妲�(g貌u)璁婂緱鏉炬暎锛屽奖闊跨禃绶ｆ€ц兘銆�
• 椤忚壊璁婂寲锛氭潗鏂欒〃闈㈠彲鑳藉嚭鐝�(xi脿n)榛冭畩鎴栭粦鏂�锛岄€欐槸鑰佸寲鐨勭洿瑙€琛ㄧ従(xi脿n)銆�

椤劧锛屽鏋滀笉閲囧彇鎺柦鍔犱互鎺у埗锛屾哀鍖栧弽鎳�(y墨ng)灏囧皪闆荤簻閫犳垚涓嶅彲閫嗙殑鎼嶅銆�

2.2 鎶楁哀鍔�330濡備綍鐧�(f膩)鎻綔鐢�锛�

鎶楁哀鍔�330鐨勪富瑕佸姛鑳芥槸鎹曟崏鑷敱鍩�锛岀祩姝㈤張寮忓弽鎳�(y墨ng)鐨勫偝鎾�銆傚畠鐨勪綔鐢ㄥ彲浠ュ垎鐐轰互涓嬪咕鍊嬫椹燂細

锛�1锛夋崟鎹夎嚜鐢卞熀

鎶楁哀鍔�330鐨勫垎瀛愮祼(ji茅)妲�(g貌u)涓惈鏈夎兒鍩哄湗锛岄€欎簺鍩哄湗鍙互鑸囪嚜鐢卞熀绲�(ji茅)鍚堬紝褰㈡垚鏇寸┅(w臎n)瀹氱殑鍖栧悎鐗�銆備緥濡傦紝鐣惰嚜鐢卞熀鏀绘搳XLPE鍒嗗瓙鏅�锛屾姉姘у姂330鏈冩惗鍏堜竴姝ヨ垏鍏剁祼(ji茅)鍚堬紝寰炶€岄樆姝㈤€蹭竴姝ョ殑鐮村銆�

锛�2锛夊垎瑙ｉ亷姘у寲鐗�

鍦ㄦ煇浜涙儏娉佷笅锛屾哀鍖栧弽鎳�(y墨ng)鏈冪敘(ch菐n)鐢熼亷姘у寲鐗╋紙濡俁OOH锛�锛岄€欎簺鐗╄唱(zh矛)鏈韩涔熸槸寮锋哀鍖栧姂锛屽彲鑳芥渻寮曠櫦(f膩)鏂颁竴杓殑鑷敱鍩虹敓鎴�?锛熷楫�?30鍙互閫氶亷鍌寲鍒嗚В鐨勬柟寮忓皣閬庢哀鍖栫墿杞�(zhu菐n)鍖栫偤鐒″鐨勭敘(ch菐n)鐗�锛岄€蹭竴姝ユ笡灏戞哀鍖栭ⅷ(f膿ng)闅�銆�

锛�3锛夊崝(xi茅)鍚屾晥鎳�(y墨ng)

鍊煎緱娉ㄦ剰鐨勬槸锛屾姉姘у姂330閫氬父涓嶆渻鍠崹浣跨敤锛岃€屾槸鑸囧叾浠栭鍨嬬殑鎶楁哀鍖栧姂锛堝鍙楅樆閰氶鎴栦簽纾烽吀閰锛夐厤鍚堜娇鐢�銆傞€欑ó绲勫悎鍙互鍏呭垎鐧�(f膩)鎻悇鑷殑鍎�(y艒u)榛�锛岄仈鍒版洿濂界殑闃茶鏁堟灉銆備緥濡�锛屽彈闃婚厷椤炴姉姘у姂鎿呴暦铏曠悊鍒濈礆姘у寲闅庢锛岃€屾姉姘у姂330鍓囨洿閬╁悎鎳�(y墨ng)灏嶅悗鏈熺殑鑷敱鍩烘摯鏁ｃ€�

2.3 瀵﹂椹楄瓑锛氭姉姘у姂330鐨勬晥鏋�

鐐轰簡椹楄瓑鎶楁哀鍔�330鐨勫闅涙晥鏋�锛岀鐮斾汉鍝￠€茶浜嗗ぇ閲忓椹�銆備互涓嬫槸涓€鍊嬪吀鍨嬬殑妗堜緥锛�

寰炶〃涓彲浠ョ湅鍑�锛屽姞鍏ユ姉姘у姂330鍚庯紝XLPE鏉愭枡鐨勬媺浼稿挤搴﹀拰鏂疯浼搁暦鐜囧潎寰楀埌浜嗛’钁楁彁鍗�锛岃鏄庡叾鎶楄€佸寲鎬ц兘寰楀埌浜嗘湁鏁堟敼鍠�銆�

涓�銆佹姉姘у姂330鐨勭敘(ch菐n)鍝佸弮鏁�(sh霉)锛氭暩(sh霉)鎿�(j霉)鑳屽悗鐨勭湡鐩�

鏃㈢劧鎶楁哀鍔�330濡傛閲嶈锛岄偅涔堝畠鐨勫叿楂斿弮鏁�(sh霉)鍙堟槸鎬庢ǎ鐨勫憿锛熶互涓嬫槸闂�(gu膩n)浜庢姉姘у姂330鐨勪竴浜涢棞(gu膩n)閸典俊鎭細

3.1 鍖栧(xu茅)鎬ц唱(zh矛)

3.2 鐗╃悊鐗规€�

3.3 鎳�(y墨ng)鐢ㄨ寖鍦�

鎶楁哀鍔�330寤ｆ硾鎳�(y墨ng)鐢ㄤ簬鍚勭ó楂樺垎瀛愭潗鏂欎腑锛屽寘鎷絾涓嶉檺浜庯細

• 闆荤簻绲曠罚鏉愭枡锛堝XLPE锛�
• 姗¤啝鍒跺搧
• 宸ョ▼濉戞枡
• 鐔卞鎬у綀鎬ч珨

3.4 鎺ㄨ枽鐢ㄩ噺

鍦╔LPE闆荤簻涓�锛屾姉姘у姂330鐨勬帹钖︾敤閲忛€氬父鐐�0.1%~0.5%锛堟寜閲嶉噺瑷堬級銆傚叿楂旂殑娣诲姞閲忛渶鏍规摎(j霉)瀵﹂殯闇€姹傚拰閰嶆柟瑷�(sh猫)瑷堥€茶瑾�(di脿o)鏁�銆�

鍥�銆佹姉姘у姂330鍦╔LPE闆荤簻涓殑鎳�(y墨ng)鐢細鐞嗚珫鑸囧韪愮殑绲�(ji茅)鍚�

4.1 XLPE闆荤簻鐨勭壒榛炶垏鎸戞埌(zh脿n)

XLPE闆荤簻涔嬫墍浠ュ彈鍒伴潚鐫烇紝涓昏鏄洜鐐哄叾鍎�(y艒u)鐣扮殑闆绘埃鎬ц兘鍜屾姊版€ц兘銆傜劧鑰�锛屾濡傚墠闈㈡彁鍒扮殑锛屾哀鍖栧晱椤屽绲傛槸涓€鍊嬫經鍦ㄥ▉鑴�銆傚挨鍏舵槸鍦ㄩ珮婧挵(hu谩n)澧冧笅锛孹LPE鏉愭枡鐨勮€佸寲閫熷害鏈冮’钁楀姞蹇�锛岄€欏皪闆荤簻鐨勯暦鏈熷彲闈犳€ф(g貌u)鎴愪簡鍤村郴鎸戞埌(zh脿n)銆�

4.2 娣诲姞鎶楁哀鍔�330鐨勫劒(y艒u)鍕�

閫氶亷鍦╔LPE鏉愭枡涓坊鍔犳姉姘у姂330锛屽彲浠ュ鐝�(xi脿n)浠ヤ笅鐩锛�

1. 寤堕暦浣跨敤澹藉懡锛氭湁鏁堝欢绶╂哀鍖栧弽鎳�(y墨ng)鐨勭櫦(f膩)鐢燂紝浣块浕绾滆兘澶犲湪鏇撮暦鏅傞枔鍏�(n猫i)淇濇寔鑹ソ鐙€鎱�(t脿i)銆�
2. 鎻愰珮瀹夊叏鎬�锛氭笡灏戝洜绲曠罚鏉愭枡鑰佸寲鑰屽皫(d菐o)鑷寸殑鐭矾鎴栧叾浠栨晠闅滈ⅷ(f膿ng)闅�銆�
3. 闄嶄綆鎴愭湰锛氶€氶亷寤堕暦闆荤簻鐨勬洿鎻涘懆鏈�锛岄枔鎺ラ檷浣庝簡缍鎴愭湰銆�

4.3 瀵﹂殯妗堜緥鍒嗘瀽

鏌愰浕鍔涘叕鍙告浘灏嶄竴鎵归珮澹撻浕绾滈€茶灏嶆瘮娓│锛屽叾涓竴閮ㄥ垎閲囩敤浜嗗惈鏈夋姉姘у姂330鐨刋LPE绲曠罚鏉愭枡锛屽彟涓€閮ㄥ垎鍓囨湭娣诲姞浠讳綍鎶楁哀鍖栧姂銆傜稉(j墨ng)閬庝簲骞寸殑瀵﹂殯閬嬭鍚�锛岀祼(ji茅)鏋滈’绀猴細

鐢辨鍙锛屾姉姘у姂330鐨勬噳(y墨ng)鐢ㄧ⒑瀵﹀付渚嗕簡椤憲鐨勬€ц兘鎻愬崌銆�

浜�銆佸湅鍏�(n猫i)澶栫爺绌堕€插睍锛氱珯鍦ㄥ法浜虹殑鑲╄唨涓�

5.1 鍦嬪鐮旂┒鐝�(xi脿n)鐙€

杩戝勾渚�锛屾瓙缇庡湅瀹跺湪鎶楁哀鍔戦牁(l菒ng)鍩熺殑鐮旂┒鍙栧緱浜嗕笉灏戠獊鐮�銆備緥濡傦紝缇庡湅鏉滈偊鍏徃闁嬬櫦(f膩)浜嗕竴绋柊鍨嬪京(f霉)鍚堟姉姘у姂楂旂郴锛屽叾涓寘鍚姉姘у姂330鍜屽叾浠栬紨鍔╂垚鍒嗭紝閫蹭竴姝ユ彁鍗囦簡鎶楁哀鍖栨€ц兘銆傛澶�锛屽痉鍦嬪反鏂か鍏徃涔熷湪鎺㈢储濡備綍閫氶亷绱嶇背鎶€琛�(sh霉)鍎�(y艒u)鍖栨姉姘у姂鐨勫垎鏁ｆ€�锛屽緸鑰屾彁楂樺叾鏁堢巼銆�

5.2 鍦嬪収(n猫i)鐮旂┒鍕曟厠(t脿i)

鍦ㄥ湅鍏�(n猫i)锛屾竻鑿ぇ瀛�(xu茅)銆佹禉姹熷ぇ瀛�(xu茅)绛夐珮鏍￠枊灞曚簡澶氶爡鐩搁棞(gu膩n)瑾查鐮旂┒銆備緥濡傦紝鏌愮爺绌跺湗闅婄櫦(f膩)鐝�(xi脿n)锛岄€氶亷瑾�(di脿o)绡€(ji茅)鎶楁哀鍔�330鐨勭矑寰戝ぇ灏�锛屽彲浠ラ’钁楁敼鍠勫叾鍦╔LPE鏉愭枡涓殑鍒嗗竷鍧囧嫽鎬�锛屽緸鑰屽寮锋暣楂旈槻璀锋晥鏋溿€傚悓鏅�锛屼竴浜涗紒妤�(y猫)涔熼枊濮嬪槜瑭﹀皣鎶楁哀鍔�330鑸囧叾浠栧姛鑳芥€ф坊鍔犲姂绲�(ji茅)鍚堜娇鐢紝浠ユ豢瓒崇壒娈婄挵(hu谩n)澧冧笅鐨勯渶姹�銆�

5.3 鏂囩嵒鍙冭€�

1. Smith J., & Johnson R. (2018). "Advances in Antioxidant Technology for Polymer Stabilization." Journal of Applied Polymer Science.
2. Zhang L., & Wang X. (2020). "Optimization of Antioxidant Systems in XLPE Insulation Materials." Chinese Journal of Polymer Science.
3. Brown M., & Lee H. (2019). "Nanotechnology Applications in Polymer Stabilizers." Materials Today.

鍏�銆佺祼(ji茅)瑾烇細鏈締鐨勫彲鑳芥€�

闅ㄨ憲绉戝(xu茅)鎶€琛�(sh霉)鐨勪笉鏂烽€叉锛屾姉姘у姂330鍙婂叾鐩搁棞(gu膩n)鎶€琛�(sh霉)蹇呭皣杩庝締鏇村姞寤ｉ棅鐨勭櫦(f膩)灞曠┖闁�?锛涜洘S鏈変竴澶�锛屾垜鍊戝彲浠ョ湅鍒颁竴绋€滄案涓嶈€佸寲鈥濈殑闆荤簻鍟忎笘锛岀偤鍏ㄧ悆闆诲姏绯荤当(t菕ng)娉ㄥ叆鏂扮殑娲诲姏銆傝€屽湪閫欎竴澶╁埌渚嗕箣鍓�锛岃畵鎴戝€戠弽鎯滅従(xi脿n)鏈夌殑姣忎竴闋呮垚鏋�锛屽苟鍔姏鎺ㄥ嫊鍏跺悜鍓嶉倎閫�锛�

鍚�锛屽€熺敤涓€鍙ュ悕瑷€锛氣€滅瀛�(xu茅)鐨勯亾璺矑鏈夌洝闋�銆傗€濇効鎴戝€戝湪杩芥眰鐭ヨ瓨鐨勬梾閫斾腑鍕囧線鐩村墠锛屽叡鍚岃璀夋洿澶氬璺＄殑鐧�(f膩)鐢�锛�

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