鎶楁哀鍔�1076鍦ㄥ悎鎴愭鑶犱腑鐨勬噳(y墨ng)鐢ㄦ杩�

鍦ㄦ鑶犲伐妤�(y猫)閫欏€�(g猫)鍏呮豢娲诲姏鐨勯牁(l菒ng)鍩熶腑锛屾姉姘у姂1076濡傚悓涓€浣嶉毐褰㈢殑瀹堣(h霉)鑰�锛岄粯榛樼董绯昏憲鍚堟垚姗¤啝鍒跺搧鐨勯暦(zh菐ng)澹借垏绌�(w臎n)瀹�銆備綔鐐洪厷椤炴姉姘у姂瀹舵棌涓殑浣间郊鑰咃紝瀹冨湪SBR锛堜竵姗¤啝锛夊拰BR锛堥爢涓佹鑶狅級绛夊悎鎴愭鑶犻珨绯讳腑鎵紨钁楄嚦闂�(gu膩n)閲嶈鐨勮鑹�銆傛兂璞′竴涓嬶紝濡傛灉娌掓湁閫欎綅"鎶楁哀鍖栧ぇ甯�"鐨勭簿蹇冨懙璀�(h霉)锛屾鑶犲埗鍝佸彲鑳芥渻(hu矛)鍍忚闄藉厜鐏煎偡鐨勮姳鐡ｄ竴妯ｈ繀閫熻€佸寲锛屽け鍘诲師鏈夌殑褰堟€у拰鍏夋兢銆�

鎶楁哀鍔�1076涔嬫墍浠ヨ兘鍦ㄧ溇澶氭姉姘у姂涓劔绌庤€屽嚭锛屼富瑕佸緱鐩婁簬鍏跺崜瓒婄殑鎬ц兘琛ㄧ従(xi脿n)銆傞鍏�锛屽畠鍏锋湁鍑鸿壊鐨勭啽绌�(w臎n)瀹氭€�锛岃兘澶犲湪姗¤啝鍔犲伐閬庣▼涓壙鍙楅珮閬�(d谩)200鈩冧互涓婄殑楂樻韩鑰冮(y脿n)銆傚叾娆★紝瀹冪殑鐩稿鎬фサ浣�锛岃兘澶犺垏鍚勭ó姗¤啝鍩洪珨瀹岀編铻嶅悎锛屽鍚屽挅鍟¤垏鐗涘ザ鑸嚜鐒跺崝(xi茅)瑾�(di脿o)銆傛洿閲嶈鐨勬槸锛屽畠鍏峰倷闀�(zh菐ng)鏁堢殑鎶楁哀鍖栬兘鍔�锛岃兘澶犲湪姗¤啝鍒跺搧鐨勬暣鍊�(g猫)鐢熷懡鍛ㄦ湡鍏�(n猫i)鎸佺簩(x霉)鐧�(f膩)鎻綔鐢�銆�

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鎺ヤ笅渚嗭紝鎴戝€戝皣娣卞叆鎺㈣◣鎶楁哀鍔�1076鐨勫叿楂斾綔鐢ㄦ(j墨)鐞�銆佸湪涓嶅悓鍚堟垚姗¤啝楂旂郴涓殑鎳�(y墨ng)鐢ㄧ壒榛�(di菐n)锛屼互鍙婂浣曢€氶亷绉戝(xu茅)閰嶆柟瑷�(sh猫)瑷�(j矛)瀵�(sh铆)鐝�(xi脿n)浣抽槻璀�(h霉)鏁堟灉銆傚悓鏅�(sh铆)锛屾垜鍊戦倓灏囧垎鏋愬湅鍏�(n猫i)澶栫爺绌堕€�(j矛n)灞曪紝鐐鸿畝鑰呭憟鐝�(xi脿n)涓€鍊�(g猫)鍏ㄩ潰鑰屾繁鍏ョ殑鎶€琛�(sh霉)瑕栬銆�

鎶楁哀鍔�1076鐨勫熀鏈壒鎬ц垏绲�(ji茅)妲�(g貌u)鍎�(y艒u)鍕�(sh矛)

鎶楁哀鍔�1076锛屽寲瀛�(xu茅)鍚嶇ū鐐篘,N’-闆�-(3-(3,5-浜屽彅涓佸熀-4-缇ュ熀鍩�)涓�?锛�?宸变簩鑳猴紝鏄竴绋吀鍨嬬殑鍙楅樆閰氶鎶楁哀鍔�銆傚叾鍒嗗瓙绲�(ji茅)妲�(g貌u)涓寘鍚叐鍊�(g猫)闂�(gu膩n)閸靛姛鑳藉柈鍏冿細涓€鍊�(g猫)鏄綅浜庣挵(hu谩n)涓婄殑鍙斾竵鍩哄彇浠ｅ熀锛屽彟涓€鍊�(g猫)鏄€ｆ帴鍦ㄦ爱鍘熷瓙涓婄殑闀�(zh菐ng)閺堣剛鑲棌鍩哄湗(tu谩n)銆傞€欑ó鐛�(d煤)鐗圭殑鍒嗗瓙瑷�(sh猫)瑷�(j矛)璩︿簣浜嗘姉姘у姂1076璜稿鍎�(y艒u)鐣扮壒鎬�銆�

寰炵墿鐞嗘€ц唱(zh矛)渚嗙湅锛屾姉姘у姂1076鍛堢櫧鑹茬矇鏈媭锛岀啍榛�(di菐n)绱勭偤110-120鈩�锛屽瘑搴︾磩1.1g/cm3銆傚畠鍏锋湁鑹ソ鐨勭啽绌�(w臎n)瀹氭€э紝鍦�200鈩冧互涓嬪熀鏈笉鏈�(hu矛)鐧�(f膩)鐢熷垎瑙�锛岄€欎娇寰楀畠鐗瑰垾閬╁悎鐢ㄤ簬闇€瑕侀珮婧姞宸ョ殑姗¤啝鍒跺搧鐢熺敘(ch菐n)閬庣▼銆傛澶�锛屽叾婧惰В搴﹀弮鏁�(sh霉)鑸囧ぇ澶氭暩(sh霉)鍚堟垚姗¤啝鐩稿尮閰�锛屼繚璀変簡鍦ㄦ鑶犲熀楂斾腑鐨勫潎鍕诲垎鏁�銆�

鍖栧(xu茅)绲�(ji茅)妲�(g貌u)鏂归潰锛屾姉姘у姂1076鐨勬牳蹇冨劒(y艒u)鍕�(sh矛)鍦ㄤ簬鍏跺垎瀛愪腑鐨勯厷缇ュ熀鍜屽彅涓佸熀绲�(ji茅)妲�(g貌u)銆傞厷缇ュ熀鑳藉鎻愪緵鏈夋晥鐨勬矮鍘熷瓙锛岀敤浜庢崟鎹夎嚜鐢卞熀锛屽緸鑰屼腑鏂锋哀鍖栭張鍙嶆噳(y墨ng)銆傝€屽彅涓佸熀鍓囪捣鍒颁簡绌洪枔浣嶉樆鐨勪綔鐢�锛屼繚璀�(h霉)閰氱茎鍩哄厤鍙楅€�(j矛n)涓€姝ユ哀鍖�锛屽欢闀�(zh菐ng)浜嗘姉姘у姂鐨勬湁鏁堟湡銆傞€欑ó闆欓噸淇濊(h霉)姗�(j墨)鍒朵娇寰楁姉姘у姂1076鍏煎叿楂樻晥鐨勬姉姘у寲鑳藉姏鍜岃純闀�(zh菐ng)鐨勪娇鐢ㄥ＝鍛�銆�

鑸囧叾浠栧父瑕嬫姉姘у姂鐩告瘮锛屾姉姘у姂1076琛ㄧ従(xi脿n)鍑烘槑椤殑鎬ц兘鍎�(y艒u)鍕�(sh矛)銆傞鍏�锛屽畠鍏锋湁鏇撮珮鐨勬姉姘у寲鏁堢巼锛屽柈浣嶈唱(zh矛)閲忎笅鐨勬姉姘у寲鑳藉姏姣旀櫘閫氶厷椤炴姉姘у姂楂樺嚭绱�20%銆傚叾娆�锛屽叾鎻櫦(f膩)鎬ц純浣�锛屽湪楂樻韩鍔犲伐姊濅欢涓嬩笉鏄撴悕澶憋紝淇濊瓑浜嗛暦(zh菐ng)鏈熶娇鐢ㄧ殑绌�(w臎n)瀹氭€�銆傚啀鑰咃紝鎶楁哀鍔�1076鑸囨鑶犲熀楂旂殑鐩稿鎬ф洿濂�锛屼笉鏈�(hu矛)鐢�(ch菐n)鐢熼伔绉荤従(xi脿n)璞★紝閬垮厤浜嗗皪(du矛)鐢�(ch菐n)鍝佸瑙€鍜屾€ц兘鐨勫奖闊�銆�

閫欎簺鍎�(y艒u)瓒婄殑鐗╃悊鍖栧(xu茅)鐗规€�锛屼娇鎶楁哀鍔�1076鎴愮偤鍚堟垚姗¤啝闋�(l菒ng)鍩熶腑鍏风(j矛ng)鐖�(zh膿ng)鍔涚殑閬告搰涔嬩竴銆傜壒鍒ユ槸鍦ㄩ渶瑕侀暦(zh菐ng)鏅�(sh铆)闁撲娇鐢ㄥ拰鑻涘埢鐠�(hu谩n)澧冩浠朵笅鐨勬鑶犲埗鍝佷腑锛屽叾绌�(w臎n)瀹氱殑鎬ц兘琛ㄧ従(xi脿n)鍜屾寔涔呯殑闃茶(h霉)鏁堟灉寰楀埌浜嗗厖鍒嗛(y脿n)璀�銆�

鎶楁哀鍔�1076鍦⊿BR/BR涓殑鍏烽珨浣滅敤姗�(j墨)鐞�

鎶楁哀鍔�1076鍦⊿BR锛堜竵姗¤啝锛夊拰BR锛堥爢涓佹鑶狅級楂旂郴涓殑鎶楁哀鍖栦綔鐢ㄦ(j墨)鍒跺彲浠ュ垎鐐轰笁鍊�(g猫)闂�(gu膩n)閸甸殠娈碉細鑷敱鍩烘崟鐛层€侀亷姘у寲鐗╁垎瑙ｅ拰閺堢祩姝�銆傞€欎竴绯诲垪寰�(f霉)闆滅殑鍖栧(xu茅)鍙嶆噳(y墨ng)鍏卞悓妲�(g貌u)鎴愪簡鎶楁哀鍔�1076灏�(du矛)姗¤啝鏉愭枡鐨勬湁鏁堜繚璀�(h霉)缍�(w菐ng)绲�(lu貌)銆�

棣栧厛锛屽湪鑷敱鍩烘崟鐛查殠娈�锛屾姉姘у姂1076鍒嗗瓙涓殑閰氱茎鍩虹櫦(f膩)鎻憲鏍稿績浣滅敤銆傜暥(d膩ng)姗¤啝鏉愭枡鏆撮湶浜庢哀姘ｆ垨鍙楀埌鐔�銆佸厜绛夊洜绱犲奖闊挎檪(sh铆)锛屾渻(hu矛)鐢熸垚娲绘€ф哀鑷敱鍩猴紙濡俁O?锛�?锛熷楫�?076閫氶亷鍏堕厷缇ュ熀鎻愪緵姘師瀛�锛屽皣閫欎簺鏈夊鐨勮嚜鐢卞熀杞�(zhu菐n)鍖栫偤杓冪偤绌�(w臎n)瀹氱殑鍖栧悎鐗�銆傞€欎竴閬庣▼鍙互鐢ㄤ互涓嬪寲瀛�(xu茅)鏂圭▼寮忚〃绀猴細

C6H5OH + RO? 鈫� C6H5O? + ROH

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鍏舵鏄亷姘у寲鐗╁垎瑙ｉ殠娈�銆傚湪姗¤啝姘у寲閬庣▼涓�锛屽線寰€鏈�(hu矛)褰㈡垚閬庢哀鍖栫墿涓枔楂旓紙ROOR’锛�?锛熷楫�?076鑳藉閫氶亷鍏跺垎瀛愪腑鐨勬皑鍩虹祼(ji茅)妲�(g貌u)鍌寲閫欎簺閬庢哀鍖栫墿鍒嗚В鐐鸿純绌�(w臎n)瀹氱殑鐢�(ch菐n)鐗�锛岄槻姝㈠畠鍊戦€�(j矛n)涓€姝ュ紩鐧�(f膩)閺�?zh菙n)妞掔；?y墨ng)銆傞€欎竴閬庣▼鍙互鐢ㄤ互涓嬫柟绋嬪紡鎻忚堪锛�

ROOR’ + 2AOH 鈫� ROR’ + H2O + 2A

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鍚庢槸閺堢祩姝㈤殠娈�銆傚湪閫欏€�(g猫)闅庢锛屾姉姘у姂1076閫氶亷鍏剁壒娈婄殑鍒嗗瓙绲�(ji茅)妲�(g貌u)锛岃兘澶犺垏宸茬稉(j墨ng)褰㈡垚鐨勬哀鍖栫敘(ch菐n)鐗╃櫦(f膩)鐢熷弽鎳�(y墨ng)锛屽皣鍏惰綁(zhu菐n)鍖栫偤鏇村姞绌�(w臎n)瀹氱殑鍖栧悎鐗┿€備緥濡�锛屽畠鍙互鑸囩景鍩哄寲鍚堢墿鍙嶆噳(y墨ng)锛屽舰鎴愮┅(w臎n)瀹氱殑閰鎴栭吀椤炵墿璩�(zh矛)锛屽緸鑰岀祩姝㈡哀鍖栭張鐨勬摯(ku貌)灞�銆傞€欎竴閬庣▼鍙互鐢ㄤ互涓嬫柟绋嬪紡琛ㄧず锛�

RCHO + AOH 鈫� RC(OH)2 + A

鍊煎緱娉ㄦ剰鐨勬槸锛屾姉姘у姂1076鐨勫垎瀛愮祼(ji茅)妲�(g貌u)涓惈鏈夊叐鍊�(g猫)鐛�(d煤)绔嬬殑閰氱茎鍩哄姛鑳藉柈鍏�锛岄€欐剰鍛宠憲姣忓€�(g猫)鎶楁哀鍔戝垎瀛愬彲浠ュ湪澶氬€�(g猫)鍙嶆噳(y墨ng)姝ラ涓櫦(f膩)鎻綔鐢ㄣ€傞€欑ó澶氭晥鎬т娇鍏跺湪姗¤啝楂旂郴涓〃鐝�(xi脿n)鍑烘洿鎸佷箙鐨勬姉姘у寲鏁堟灉銆傛澶栵紝鍏跺垎瀛愪腑鐨勯暦(zh菐ng)閺堢兎鍩虹祼(ji茅)妲�(g貌u)閭勮兘鏈夋晥闄嶄綆鎶楁哀鍔戠殑閬风Щ鎬�锛岀⒑淇濆叾鍦ㄦ鑶犲熀楂斾腑鐨勫潎鍕诲垎甯冨拰鎸佺簩(x霉)浣滅敤銆�

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