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鍦ㄧ敓鐢�(ch菐n)閬庣▼涓紝浜炵７閰镐笁鐧搁叝閭勮兘鏈夋晥鎻愰珮鍔犲伐鏁堢巼銆傚叾鑹ソ鐨勭浉瀹规€у拰鍒嗘暎鎬т娇寰楀畠鑳藉鍧囧嫽鍒嗗竷鍦ㄦ潗鏂欓珨绯讳腑锛屽緸鑰岄檷浣庤ō鍌欑（鎼嶅拰宸ヨ棟鏁呴殰鐜�銆傛牴鎿�(j霉)澶氬浼佹キ(y猫)鐨勫闅涘弽楗�锛屼娇鐢ㄥ惈浜炵７閰镐笁鐧搁叝鐨勯厤鏂瑰悗锛岀敓鐢�(ch菐n)绶氱殑鍋滄鏅傞枔骞冲潎娓涘皯浜嗙磩25%锛岀敘(ch菐n)閲忔彁鍗囦簡绱�18%锛圕hen & Liu, 2022锛夈€�

姝ゅ锛屼簽纾烽吀涓夌櫢閰殑浣庢彯鐧�(f膩)鎬у拰楂樼啽绌�(w臎n)瀹氭€т篃鐐哄叾鍦ㄩ珮婧姞宸ョ挵(hu谩n)澧冧腑鐨勬噳鐢ㄦ彁渚涗簡淇濋殰銆傚嵆浣垮湪娉ㄥ銆佹摖鍑虹瓑楂樻韩宸ヨ棟姊濅欢涓�锛屽畠渚濈劧鑳藉淇濇寔绌�(w臎n)瀹氱殑鎬ц兘琛ㄧ従(xi脿n)锛岄伩鍏嶄簡鍌崇当(t菕ng)绌�(w臎n)瀹氬姂瀹规槗鍒嗚В鐨勫晱椤�銆�

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寰炲畨鍏ㄨ搴︿締鐪�锛屼簽纾烽吀涓夌櫢閰殑鐠�(hu谩n)淇濈壒鎬т篃鐐虹敘(ch菐n)鍝佺鐖姏鍔犲垎涓嶅皯銆傜浉姣旀煇浜涘惈鏈夐噸閲戝爆闆㈠瓙鐨勫偝绲�(t菕ng)绌�(w臎n)瀹氬姂锛屼簽纾烽吀涓夌櫢閰畬鍏ㄧ鍚堟瓙鐩烺EACH娉曡(gu墨)鍜孯oHS鎸囦护鐨勮姹�锛屾槸涓€绋稜鑹插畨鍏ㄧ殑閬告搰銆傞€欎笉鍍呮湁鍔╀簬浼佹キ(y猫)闁嬫嫇鍦嬮殯甯傚牬锛岄倓鑳芥彁鍗囧搧鐗屽舰璞�锛岃磸寰楁洿澶氭秷璨昏€呯殑淇′换銆�

缍滀笂鎵€杩帮紝浜炵７閰镐笁鐧搁叝閫氶亷澶氱董搴︾殑鎬ц兘鎻愬崌锛岀偤浼佹キ(y猫)甯朵締浜嗛’钁楃殑绔剁埈鍎�(y艒u)鍕€€傜劇璜栨槸寤堕暦鐢�(ch菐n)鍝佸＝鍛�銆佹敼鍠勫瑙€璩�(zh矛)閲�锛岄倓鏄彁楂樺姞宸ユ晥鐜囧拰澧炲挤瀹夊叏鎬ц兘锛屽畠閮借兘鐧�(f膩)鎻噸瑕佷綔鐢�銆傛濡備竴浣嶈硣娣卞伐绋嬪斧鎵€瑾細"浜炵７閰镐笁鐧搁叝灏卞儚鏄郸鐢�(ch菐n)鍝佺┛涓婁簡涓€浠跺鍔熻兘闃茶鏈嶏紝璁撳畠鍊戝湪鍚勭ó鎯″姡鐠�(hu谩n)澧冧腑閮借兘淇濇寔浣崇媭鎱�(t脿i)銆�"

鍦嬪収(n猫i)澶栨枃鐛绘敮鎸佽垏鎳夌敤妗堜緥鍒嗘瀽

鐐轰簡鏇村叏闈㈠湴鐞嗚В浜炵７閰镐笁鐧搁叝鍦ㄦ彁鍗囩敘(ch菐n)鍝佺鐖姏鏂归潰鐨勫闅涙晥鏋�锛屾垜鍊戝弮鑰冧簡澶ч噺鍦嬪収(n猫i)澶栨瑠濞佹枃鐛伙紝骞堕伕鍙栦簡骞惧€嬪叿鏈変唬琛ㄦ€х殑鎳夌敤妗堜緥閫茶娣卞叆鍒嗘瀽銆�

鍦嬮殯鐮旂┒閫插睍

杩戝勾渚嗭紝鍦嬮殯瀛歌鐣屽皪浜炵７閰镐笁鐧搁叝鐨勭爺绌跺彇寰椾簡瑷卞閲嶈绐佺牬銆傜編鍦嬮夯鐪佺悊宸ュ闄㈢殑涓€闋呯爺绌讹紙Brown et al., 2021锛夌櫦(f膩)鐝�(xi脿n)锛屼簽纾烽吀涓夌櫢閰湪绱嶇背寰╁悎鏉愭枡涓殑鍒嗘暎琛岀偤鑸囧叾鍒嗗瓙绲愭瀵嗗垏鐩搁棞銆傜爺绌朵汉鍝￠€氶亷鍒嗗瓙鍕曞姏瀛告ā鎿紝瑭崇窗闂¤堪浜嗗叾鍦ㄨ仛鍚堢墿鍩洪珨涓殑閬风Щ瑕�(gu墨)寰�锛岀偤鍎�(y艒u)鍖栭厤鏂硅ō瑷堟彁渚涗簡鐞嗚珫渚濇摎(j霉)銆�

寰峰湅鎱曞凹榛戝伐妤�(y猫)澶у鐨勭爺绌跺湗闅婏紙Schmidt & Meyer, 2022锛夊墖閲嶉粸闂滄敞浜嗕簽纾烽吀涓夌櫢閰湪鍏変紡鏉愭枡涓殑鎳夌敤銆備粬鍊戦枊鐧�(f膩)浜嗕竴绋柊鍨嬪皝瑁濊啝鑶�锛屽叾涓坊鍔犱簡鐗瑰畾姣斾緥鐨勪簽纾烽吀涓夌櫢閰�锛屾垚鍔熷皣绲勪欢鐨勬埗澶栦娇鐢ㄥ＝鍛藉欢闀蜂簡40%浠ヤ笂銆傞€欓爡鐮旂┒鎴愭灉宸茬嵅寰楀闋呭皥鍒╂巿娆婏紝骞惰寤ｆ硾鎳夌敤浜庡ぇ鍨嬪厜浼忛浕绔欏缓瑷腑銆�

鏃ユ湰鏉变含澶у鐨勭爺绌朵汉鍝★紙Tanaka et al., 2023锛夊墖寰炲垎瀛愭按骞虫繁鍏ユ帰瑷庝簡浜炵７閰镐笁鐧搁叝鐨勬姉姘у寲姗熷埗銆傞€氶亷鍘熶綅绱呭鍏夎瓬鎶€琛�锛屼粬鍊戦娆¤瀵熷埌浜嗙７姘ч嵉褰㈡垚鐨勫嫊鎱�(t脿i)閬庣▼锛岀偤鍚庣簩(x霉)鐢�(ch菐n)鍝侀枊鐧�(f膩)鎻愪緵浜嗛噸瑕佺殑瀵﹂鏁�(sh霉)鎿�(j霉)鏀寔銆�

鍦嬪収(n猫i)鐮旂┒鍕曟厠(t脿i)

鍦ㄥ湅鍏�(n猫i)锛屾竻鑿ぇ瀛稿寲宸ョ郴鐨勪竴鍊嬬爺绌跺皬绲勶紙Li et al., 2022锛夐嚌灏嶄簽纾烽吀涓夌櫢閰湪姹借粖鍏�(n猫i)椋炬潗鏂欎腑鐨勬噳鐢ㄩ€茶浜嗙郴绲�(t菕ng)鐮旂┒銆備粬鍊戠櫦(f膩)鐝�(xi脿n)锛岄€氶亷瑾�(di脿o)鏁存坊鍔犲姂鐨勭敤閲忓拰閰嶆瘮锛屽彲浠ラ’钁楁敼鍠勬潗鏂欑殑鑰愬€欐€ц兘锛屽悓鏅備繚鎸佽壇濂界殑瑙告劅鍜岃垝閬╂€�銆傞€欓爡鐮旂┒鎴愭灉宸茶鏌愮煡鍚嶆苯杌婂埗閫犲晢閲囩敤锛岀敤浜庢柊涓€浠ｈ粖鍨嬬殑鍏�(n猫i)椋鹃枊鐧�(f膩)銆�

寰╂棪澶у楂樺垎瀛愮瀛哥爺绌舵墍锛圸hang & Wang, 2023锛夊墖灏堟敞浜庝簽纾烽吀涓夌櫢閰湪閱�(y墨)鐢ㄦ潗鏂欎腑鐨勬噳鐢ㄦ帰绱�銆備粬鍊戠殑鐮旂┒琛ㄦ槑锛岃┎鍖栧悎鐗╄兘澶犳湁鏁堟姂鍒堕啱(y墨)鐢ㄥ皫绠″湪闀锋湡浣跨敤閬庣▼涓嚭鐝�(xi脿n)鐨勭‖鍖栧拰鑴嗚鐝�(xi脿n)璞�锛岄’钁楁彁楂樹簡鐢�(ch菐n)鍝佺殑瀹夊叏鎬у拰鍙潬鎬�銆�

瀵﹂殯鎳夌敤妗堜緥

姹借粖琛屾キ(y猫)

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鍖呰琛屾キ(y猫)

涓€瀹跺叏鐞冮牁鍏堢殑椋熷搧鍖呰浼佹キ(y猫)灏囧叾鐢熺敘(ch菐n)鐨凱ET鐡舵敼鐢ㄥ惈浜炵７閰镐笁鐧搁叝鐨勯厤鏂瑰悗锛岀敘(ch菐n)鍝佸湪璨ㄦ灦鏈熺殑琛ㄧ従(xi脿n)鏄庨’鍎�(y艒u)浜庡偝绲�(t菕ng)鐢�(ch菐n)鍝�銆傚椹楁暩(sh霉)鎿�(j霉)椤ず锛屾柊閰嶆柟鐨勭摱瀛愬湪绱绶氱収灏勪笅鐨勫姏瀛告€ц兘涓嬮檷骞呭害鍍呯偤鏅€氱敘(ch菐n)鍝佺殑涓夊垎涔嬩竴锛屾サ澶у湴寤堕暦浜嗗寘瑁濇潗鏂欑殑浣跨敤澹藉懡銆�

鍏変紡琛屾キ(y猫)

鍦嬪収(n猫i)鏌愬ぇ鍨嬪厜浼忕祫浠跺埗閫犲晢鍦ㄥ叾鏂扮敘(ch菐n)鍝佺爺鐧�(f膩)涓噰鐢ㄤ簡鍚簽纾烽吀涓夌櫢閰殑灏佽鑶犺啘銆傜稉(j墨ng)閬庡闅涢亱琛岄璀夛紝瑭茬祫浠跺湪娌欐紶鍦板崁(q奴)鐨勭櫦(f膩)闆绘晥鐜囪“娓涢€熺巼姣斿偝绲�(t菕ng)鐢�(ch菐n)鍝佷綆浜嗚繎50%銆傞€欎竴绐佺牬鎬ф垚鏋滃公鍔╀紒妤�(y猫)鎴愬姛涓澶氬€嬪ぇ鍨嬪厜浼忕櫦(f膩)闆婚爡鐩�锛屽競鍫翠唤椤嶅ぇ骞呮彁鍗�銆�

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浜炵７閰镐笁鐧搁叝鐨勬噳鐢ㄩ牁鍩熻垏甯傚牬鍓嶆櫙

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鎿村睍闁辫畝:https://www.bdmaee.net/dibutyltin-benzoate/

鎿村睍闁辫畝:https://www.morpholine.org/127-08-2/

鎿村睍闁辫畝:https://www.bdmaee.net/wp-content/uploads/2020/06/29.jpg

鎿村睍闁辫畝:https://www.newtopchem.com/archives/40390

鎿村睍闁辫畝:https://www.cyclohexylamine.net/lupragen-n104-pc-cat-nem/

鎿村睍闁辫畝:https://www.newtopchem.com/archives/44668

鎿村睍闁辫畝:https://www.bdmaee.net/niax-sa-800-tertiary-amine-catalyst-momentive/

鎿村睍闁辫畝:https://www.newtopchem.com/archives/category/products/page/140

鎿村睍闁辫畝:https://www.bdmaee.net/dibutyltin-dichloride/

鎿村睍闁辫畝:https://www.cyclohexylamine.net/delayed-tertiary-amine-catalyst-delayed-catalyst-bl-17/

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