鍚庣啛鍖栧偓鍖栧姂TAP灏�(du矛)鑱氭皑閰场娌祼(ji茅)妲�(g貌u)鐨勫奖闊�

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鑱氭皑閰场娌槸涓€绋唬娉涙噳(y墨ng)鐢ㄤ簬寤虹瓚銆佸鍏�銆佹苯杌�(ch膿)銆佸寘瑁濈瓑闋�(l菒ng)鍩熺殑楂樺垎瀛愭潗鏂�銆傚叾鎬ц兘鐨勫劒(y艒u)鍔ｇ洿鎺ュ奖闊垮埌绲傜敘(ch菐n)鍝佺殑璩�(zh矛)閲忓拰浣跨敤澹藉懡銆傚湪鑱氭皑閰场娌殑鐢熺敘(ch菐n)閬�(gu貌)绋嬩腑锛屽偓鍖栧姂鐨勯伕鎿囧拰浣跨敤灏�(du矛)娉℃搏鐨勭祼(ji茅)妲�(g貌u)鍜屾€ц兘鏈夎憲鑷抽棞(gu膩n)閲嶈鐨勫奖闊裤€傛湰鏂囧皣瑭崇窗(x矛)鎺㈣◣鍚庣啛鍖栧偓鍖栧姂TAP锛圱riethylenediamine-based Amine Polyol锛夊皪(du矛)鑱氭皑閰场娌祼(ji茅)妲�(g貌u)鐨勫奖闊�锛屽苟閫氶亷(gu貌)鐢�(ch菐n)鍝佸弮鏁�(sh霉)鍜岃〃鏍奸€�(j矛n)琛岃┏绱�(x矛)瑾�(shu艒)鏄�銆�

1. 鑱氭皑閰场娌殑鍩烘湰绲�(ji茅)妲�(g貌u)

鑱氭皑閰场娌槸鐢卞鍏冮唶銆佺暟姘伴吀閰€佸偓鍖栧姂銆佺櫦(f膩)娉″姂绛夊師鏂欓€氶亷(gu貌)鍖栧(xu茅)鍙嶆噳(y墨ng)褰㈡垚鐨勫瀛旀潗鏂�銆傚叾鍩烘湰绲�(ji茅)妲�(g貌u)鍖呮嫭纭鍜岃粺娈�锛岀‖娈典富瑕佺敱鐣版鞍閰搁叝鍜屽鍏冮唶鍙嶆噳(y墨ng)鐢熸垚鐨勬皑鍩虹敳閰搁叝閸电祫鎴�锛岃粺娈靛墖鐢卞鍏冮唶鐨勯暦(zh菐ng)閺堢祼(ji茅)妲�(g貌u)妲�(g貌u)鎴愩€傛场娌殑绲�(ji茅)妲�(g貌u)姹哄畾浜嗗叾鍔涘(xu茅)鎬ц兘銆佺啽鎬ц兘銆佸惛鑱叉€ц兘绛�銆�

2. 鍌寲鍔戝湪鑱氭皑閰场娌腑鐨勪綔鐢�

鍌寲鍔戝湪鑱氭皑閰场娌殑鐢熺敘(ch菐n)閬�(gu貌)绋嬩腑涓昏璧峰埌鍔犻€熷弽鎳�(y墨ng)鐨勪綔鐢ㄣ€傚父瑕�(ji脿n)鐨勫偓鍖栧姂鍖呮嫭鑳洪(l猫i)鍌寲鍔�銆侀噾灞偓鍖栧姂绛夈€傚偓鍖栧姂鐨勯伕鎿囦笉鍍呭奖闊垮弽鎳�(y墨ng)閫熷害锛岄倓褰遍熆娉℃搏鐨勬场瀛旂祼(ji茅)妲�(g貌u)銆佸瘑搴︺€佺‖搴︾瓑鎬ц兘銆�

2.1 鑳洪(l猫i)鍌寲鍔�

鑳洪(l猫i)鍌寲鍔戞槸鑱氭皑閰场娌敓鐢�(ch菐n)涓父鐢ㄧ殑鍌寲鍔戜箣涓€锛屼富瑕佸寘鎷彅鑳洪(l猫i)鍌寲鍔戝拰瀛ｉ姩楣介(l猫i)鍌寲鍔�銆傝兒椤�(l猫i)鍌寲鍔戜富瑕侀€氶亷(gu貌)鍌寲鐣版鞍閰搁叝鑸囧鍏冮唶鐨勫弽鎳�(y墨ng)锛屼績閫�(j矛n)娉℃搏鐨勫舰鎴愩€�

2.2 閲戝爆鍌寲鍔�

閲戝爆鍌寲鍔戜富瑕佸寘鎷尗椤�(l猫i)鍌寲鍔戝拰閴涢(l猫i)鍌寲鍔�銆傞噾灞偓鍖栧姂涓昏閫氶亷(gu貌)鍌寲鐣版鞍閰搁叝鑸囨按鐨勫弽鎳�(y墨ng)锛屼績閫�(j矛n)浜屾哀鍖栫⒊鐨勭敓鎴�锛屽緸鑰屽舰鎴愭场娌�銆�

3. 鍚庣啛鍖栧偓鍖栧姂TAP鐨勭壒鎬�

鍚庣啛鍖栧偓鍖栧姂TAP鏄竴绋熀浜庝笁涔欑儻浜岃兒鐨勮兒椤�(l猫i)鍌寲鍔�锛屽叿鏈変互涓嬬壒鎬э細

• 楂樻晥鎬�锛歍AP鑳藉椤憲鍔犻€熻仛姘ㄩ叝娉℃搏鐨勫悗鐔熷寲閬�(gu貌)绋�锛岀府鐭敓鐢�(ch菐n)鍛ㄦ湡銆�
• 绌�(w臎n)瀹氭€�锛歍AP鍦ㄩ珮婧笅浠嶈兘淇濇寔杓冮珮鐨勫偓鍖栨椿鎬�锛岄仼鐢ㄤ簬鍚勭ó鐢熺敘(ch菐n)鐠�(hu谩n)澧�銆�
• 鐠�(hu谩n)淇濇€�锛歍AP涓嶅惈閲嶉噾灞�锛屽皪(du矛)鐠�(hu谩n)澧冨弸濂姐€�

3.1 TAP鐨勫寲瀛�(xu茅)绲�(ji茅)妲�(g貌u)

TAP鐨勫寲瀛�(xu茅)绲�(ji茅)妲�(g貌u)濡備笅锛�

3.2 TAP鐨勭墿鐞嗘€ц唱(zh矛)

4. TAP灏�(du矛)鑱氭皑閰场娌祼(ji茅)妲�(g貌u)鐨勫奖闊�

4.1 娉″瓟绲�(ji茅)妲�(g貌u)

娉″瓟绲�(ji茅)妲�(g貌u)鏄仛姘ㄩ叝娉℃搏鐨勯噸瑕佺壒寰佷箣涓€锛岀洿鎺ュ奖闊挎场娌殑鍔涘(xu茅)鎬ц兘鍜岀啽鎬ц兘銆俆AP浣滅偤鍚庣啛鍖栧偓鍖栧姂锛岃兘澶犻’钁楁敼鍠勬场瀛旂祼(ji茅)妲�(g貌u)锛屼娇鍏舵洿鍔犲潎鍕诲拰绱�(x矛)灏�銆�

4.1.1 娉″瓟灏哄

寰炰笂琛ㄥ彲浠ョ湅鍑猴紝浣跨敤TAP鍚�锛岃仛姘ㄩ叝娉℃搏鐨勫钩鍧囨场瀛斿昂瀵搁’钁楁笡灏忥紝娉″瓟鏇村姞鍧囧嫽銆�

4.1.2 娉″瓟鍒嗗竷

TAP鐨勪娇鐢ㄤ娇寰楁场瀛斿垎甯冩洿鍔犲潎鍕伙紝娓涘皯浜嗘场瀛斿悎骞跺拰鐮磋鐨勭従(xi脿n)璞�銆�

4.2 瀵嗗害

瀵嗗害鏄仛姘ㄩ叝娉℃搏鐨勯噸瑕佸弮鏁�(sh霉)涔嬩竴锛岀洿鎺ュ奖闊挎场娌殑鍔涘(xu茅)鎬ц兘鍜岀啽鎬ц兘銆俆AP鐨勪娇鐢ㄨ兘澶犻’钁楁彁楂樻场娌殑瀵嗗害銆�

寰炰笂琛ㄥ彲浠ョ湅鍑�锛屼娇鐢═AP鍚�锛岃仛姘ㄩ叝娉℃搏鐨勫瘑搴﹂’钁楁彁楂�锛屾场娌洿鍔犺嚧瀵嗐€�

4.3 纭害

纭害鏄仛姘ㄩ叝娉℃搏鐨勯噸瑕佸姏瀛�(xu茅)鎬ц兘涔嬩竴锛岀洿鎺ュ奖闊挎场娌殑浣跨敤澹藉懡鍜岃垝閬╂€�銆俆AP鐨勪娇鐢ㄨ兘澶犻’钁楁彁楂樻场娌殑纭害銆�

寰炰笂琛ㄥ彲浠ョ湅鍑�锛屼娇鐢═AP鍚�锛岃仛姘ㄩ叝娉℃搏鐨勭‖搴﹂’钁楁彁楂�锛屾场娌洿鍔犲爡(ji膩n)纭�銆�

4.4 鐔辨€ц兘

鐔辨€ц兘鏄仛姘ㄩ叝娉℃搏鐨勯噸瑕佹€ц兘涔嬩竴锛岀洿鎺ュ奖闊挎场娌殑闅旂啽鎬ц兘鍜岃€愮啽鎬с€俆AP鐨勪娇鐢ㄨ兘澶犻’钁楁敼鍠勬场娌殑鐔辨€ц兘銆�

4.4.1 鐔卞皫(d菐o)鐜�

寰炰笂琛ㄥ彲浠ョ湅鍑猴紝浣跨敤TAP鍚�锛岃仛姘ㄩ叝娉℃搏鐨勭啽灏�(d菐o)鐜囬’钁楅檷浣�锛屾场娌殑闅旂啽鎬ц兘鏇村ソ銆�

4.4.2 鑰愮啽鎬�

寰炰笂琛ㄥ彲浠ョ湅鍑�锛屼娇鐢═AP鍚�锛岃仛姘ㄩ叝娉℃搏鐨勮€愮啽婧害椤憲鎻愰珮锛屾场娌殑鑰愮啽鎬ф洿濂�銆�

4.5 鍚歌伈鎬ц兘

鍚歌伈鎬ц兘鏄仛姘ㄩ叝娉℃搏鐨勯噸瑕佹€ц兘涔嬩竴锛岀洿鎺ュ奖闊挎场娌殑闅旈煶鏁堟灉銆俆AP鐨勪娇鐢ㄨ兘澶犻’钁楁敼鍠勬场娌殑鍚歌伈鎬ц兘銆�

寰炰笂琛ㄥ彲浠ョ湅鍑�锛屼娇鐢═AP鍚�锛岃仛姘ㄩ叝娉℃搏鐨勫惛鑱茬郴鏁�(sh霉)椤憲鎻愰珮锛屾场娌殑闅旈煶鏁堟灉鏇村ソ銆�

5. TAP鍦ㄤ笉鍚岄(l猫i)鍨嬭仛姘ㄩ叝娉℃搏涓殑鎳�(y墨ng)鐢�

5.1 杌熻唱(zh矛)鑱氭皑閰场娌�

杌熻唱(zh矛)鑱氭皑閰场娌唬娉涙噳(y墨ng)鐢ㄤ簬瀹跺叿銆佸簥澧�銆佹苯杌�(ch膿)搴ф绛夐牁(l菒ng)鍩�銆俆AP鐨勪娇鐢ㄨ兘澶犻’钁楁敼鍠勮粺璩�(zh矛)鑱氭皑閰场娌殑娉″瓟绲�(ji茅)妲�(g貌u)銆佸瘑搴�銆佺‖搴﹀拰鐔辨€ц兘銆�

5.1.1 娉″瓟绲�(ji茅)妲�(g貌u)

5.1.2 瀵嗗害

5.1.3 纭害

5.1.4 鐔辨€ц兘

5.2 纭唱(zh矛)鑱氭皑閰场娌�

纭唱(zh矛)鑱氭皑閰场娌唬娉涙噳(y墨ng)鐢ㄤ簬寤虹瓚淇濇韩銆佸喎閺堢墿娴佺瓑闋�(l菒ng)鍩�銆俆AP鐨勪娇鐢ㄨ兘澶犻’钁楁敼鍠勭‖璩�(zh矛)鑱氭皑閰场娌殑娉″瓟绲�(ji茅)妲�(g貌u)銆佸瘑搴�銆佺‖搴﹀拰鐔辨€ц兘銆�

5.2.1 娉″瓟绲�(ji茅)妲�(g貌u)

5.2.2 瀵嗗害

5.2.3 纭害

5.2.4 鐔辨€ц兘

5.3 鍗婄‖璩�(zh矛)鑱氭皑閰场娌�

鍗婄‖璩�(zh矛)鑱氭皑閰场娌唬娉涙噳(y墨ng)鐢ㄤ簬姹借粖(ch膿)鍏�(n猫i)椋�銆佸寘瑁濇潗鏂欑瓑闋�(l菒ng)鍩�銆俆AP鐨勪娇鐢ㄨ兘澶犻’钁楁敼鍠勫崐纭唱(zh矛)鑱氭皑閰场娌殑娉″瓟绲�(ji茅)妲�(g貌u)銆佸瘑搴�銆佺‖搴﹀拰鐔辨€ц兘銆�

5.3.1 娉″瓟绲�(ji茅)妲�(g貌u)

5.3.2 瀵嗗害

5.3.3 纭害

5.3.4 鐔辨€ц兘

6. TAP鐨勪娇鐢ㄦ柟娉�

6.1 娣诲姞閲�

TAP鐨勬坊鍔犻噺鎳�(y墨ng)鏍规摎(j霉)鍏烽珨鐢熺敘(ch菐n)姊濅欢鍜岀敘(ch菐n)鍝佽姹傞€�(j矛n)琛岃(di脿o)鏁淬€備竴鑸儏娉佷笅锛孴AP鐨勬坊鍔犻噺鐐哄鍏冮唶閲嶉噺鐨�0.5%-2%銆�

6.2 娣诲姞鏂瑰紡

TAP鍙互閫氶亷(gu貌)浠ヤ笅鏂瑰紡娣诲姞鍒拌仛姘ㄩ叝娉℃搏鐨勭敓鐢�(ch菐n)閬�(gu貌)绋嬩腑锛�

• 闋�(y霉)娣锋硶锛氬皣TAP鑸囧鍏冮唶闋�(y霉)鍏堟贩鍚�锛岀劧鍚庤垏鐣版鞍閰搁叝鍙嶆噳(y墨ng)銆�
• 鍚庢坊鍔犳硶锛氬湪鍙嶆噳(y墨ng)閬�(gu貌)绋嬩腑閫愭娣诲姞TAP锛屼互鎺у埗鍙嶆噳(y墨ng)閫熷害銆�

6.3 娉ㄦ剰浜嬮爡(xi脿ng)

• 婧害鎺у埗锛歍AP鍦ㄩ珮婧笅浠嶈兘淇濇寔杓冮珮鐨勫偓鍖栨椿鎬�锛屼絾閬�(gu貌)楂樼殑婧害鍙兘灏�(d菐o)鑷村弽鎳�(y墨ng)閬�(gu貌)蹇紝褰遍熆娉℃搏绲�(ji茅)妲�(g貌u)銆�
• 鏀媽閫熷害锛氶仼鐣�(d膩ng)?sh霉)鑷勫殺鏉蜂浚鎵斿厔顚㈣单AP鐨勫潎鍕诲垎鏁�锛屾彁楂樺偓鍖栨晥鏋溿€�
• 鍎�(ch菙)瀛樻浠�锛歍AP鎳�(y墨ng)鍎�(ch菙)瀛樺湪闄版都銆佸共鐕ョ殑鐠�(hu谩n)澧冧腑锛岄伩鍏嶉櫧(y谩ng)鍏夌洿灏勫拰楂樻韩銆�

7. TAP鐨勭稉(j墨ng)婵�(j矛)鎬у垎鏋�

7.1 鎴愭湰鍒嗘瀽

TAP鐨勬垚鏈浉灏�(du矛)杓冮珮锛屼絾鍏堕珮鏁堢殑鍌寲鏁堟灉鍜岄’钁楃殑鐢�(ch菐n)鍝佹€ц兘鎻愬崌锛屼娇寰楀叾鍦ㄨ仛姘ㄩ叝娉℃搏鐢熺敘(ch菐n)涓叿鏈夎純楂樼殑鎬�?x煤n)r(ji脿)姣�銆�

7.2 鏁堢泭鍒嗘瀽

浣跨敤TAP鍚�锛岃仛姘ㄩ叝娉℃搏鐨勭敓鐢�(ch菐n)鍛ㄦ湡绺煭锛岀敘(ch菐n)鍝佹€ц兘鎻愬崌锛屽競鍫�(ch菐ng)绔�(j矛ng)鐖�(zh膿ng)鍔涘寮�(qi谩ng)锛岃兘澶犲付渚�(l谩i)椤憲鐨勭稉(j墨ng)婵�(j矛)鏁堢泭銆�

8. 绲�(ji茅)璜�

鍚庣啛鍖栧偓鍖栧姂TAP鍦ㄨ仛姘ㄩ叝娉℃搏鐢熺敘(ch菐n)涓叿鏈夐’钁楃殑鍌寲鏁堟灉锛岃兘澶犻’钁楁敼鍠勬场娌殑娉″瓟绲�(ji茅)妲�(g貌u)銆佸瘑搴︺€佺‖搴�銆佺啽鎬ц兘鍜屽惛鑱叉€ц兘銆俆AP鐨勪娇鐢ㄤ笉鍍呮彁楂樹簡鐢�(ch菐n)鍝佺殑鎬ц兘锛岄倓绺煭浜嗙敓鐢�(ch菐n)鍛ㄦ湡锛屽寮�(qi谩ng)浜嗗競鍫�(ch菐ng)绔�(j矛ng)鐖�(zh膿ng)鍔�銆傜洝绠AP鐨勬垚鏈浉灏�(du矛)杓冮珮锛屼絾鍏堕珮鏁堢殑鍌寲鏁堟灉鍜岄’钁楃殑鐢�(ch菐n)鍝佹€ц兘鎻愬崌锛屼娇寰楀叾鍦ㄨ仛姘ㄩ叝娉℃搏鐢熺敘(ch菐n)涓叿鏈夎純楂樼殑鎬�?x煤n)r(ji脿)姣�銆傚洜姝�锛孴AP鏄竴绋€煎緱鎺ㄥ唬鍜屾噳(y墨ng)鐢ㄧ殑鍚庣啛鍖栧偓鍖栧姂銆�

9. 鏈締(l谩i)灞曟湜

闅ㄨ憲鑱氭皑閰场娌噳(y墨ng)鐢ㄩ牁(l菒ng)鍩熺殑涓嶆柗鎿�(ku貌)澶�锛屽皪(du矛)鍌寲鍔戠殑瑕佹眰涔熻秺渚�(l谩i)瓒婇珮銆傛湭渚�(l谩i)锛孴AP鐨勭爺鐧�(f膩)鍜屾噳(y墨ng)鐢ㄥ皣鏇村姞娉ㄩ噸鐠�(hu谩n)淇濇€с€侀珮鏁堟€у拰缍�(j墨ng)婵�(j矛)鎬�銆傞€氶亷(gu貌)涓嶆柗鍎�(y艒u)鍖朤AP鐨勫寲瀛�(xu茅)绲�(ji茅)妲�(g貌u)鍜岀敓鐢�(ch菐n)宸ヨ棟锛岄€�(j矛n)涓€姝ユ彁楂樺叾鍌寲鏁堟灉鍜岀敘(ch菐n)鍝佹€ц兘锛屽皣鐐鸿仛姘ㄩ叝娉℃搏琛屾キ(y猫)鐨勭櫦(f膩)灞曞付渚�(l谩i)鏂扮殑姗�(j墨)閬囧拰鎸戞埌(zh脿n)銆�

10. 闄勯寗

10.1 TAP鐨勫寲瀛�(xu茅)绲�(ji茅)妲�(g貌u)鍦�

   N
  / 
 /   
N     N
    /
   /
   N

10.2 TAP鐨勭墿鐞嗘€ц唱(zh矛)琛�

10.3 TAP鐨勪娇鐢ㄦ柟娉曡〃

10.4 TAP鐨勭稉(j墨ng)婵�(j矛)鎬у垎鏋愯〃

10.5 TAP鐨勬晥鐩婂垎鏋愯〃

11. 绺界祼(ji茅)

鍚庣啛鍖栧偓鍖栧姂TAP鍦ㄨ仛姘ㄩ叝娉℃搏鐢熺敘(ch菐n)涓叿鏈夐’钁楃殑鍌寲鏁堟灉锛岃兘澶犻’钁楁敼鍠勬场娌殑娉″瓟绲�(ji茅)妲�(g貌u)銆佸瘑搴�銆佺‖搴�銆佺啽鎬ц兘鍜屽惛鑱叉€ц兘銆俆AP鐨勪娇鐢ㄤ笉鍍呮彁楂樹簡鐢�(ch菐n)鍝佺殑鎬ц兘锛岄倓绺煭浜嗙敓鐢�(ch菐n)鍛ㄦ湡锛屽寮�(qi谩ng)浜嗗競鍫�(ch菐ng)绔�(j矛ng)鐖�(zh膿ng)鍔�銆傜洝绠AP鐨勬垚鏈浉灏�(du矛)杓冮珮锛屼絾鍏堕珮鏁堢殑鍌寲鏁堟灉鍜岄’钁楃殑鐢�(ch菐n)鍝佹€ц兘鎻愬崌锛屼娇寰楀叾鍦ㄨ仛姘ㄩ叝娉℃搏鐢熺敘(ch菐n)涓叿鏈夎純楂樼殑鎬�?x煤n)r(ji脿)姣�銆傚洜姝�锛孴AP鏄竴绋€煎緱鎺ㄥ唬鍜屾噳(y墨ng)鐢ㄧ殑鍚庣啛鍖栧偓鍖栧姂銆�

閫氶亷(gu貌)鏈枃鐨勮┏绱�(x矛)鎺㈣◣锛岀浉淇¤畝鑰呭皪(du矛)鍚庣啛鍖栧偓鍖栧姂TAP鍦ㄨ仛姘ㄩ叝娉℃搏鐢熺敘(ch菐n)涓殑鎳�(y墨ng)鐢ㄦ湁浜嗘洿娣卞叆鐨勪簡瑙ｃ€傚笇鏈涙湰鏂囪兘鐐鸿仛姘ㄩ叝娉℃搏琛屾キ(y猫)鐨勭櫦(f膩)灞曟彁渚涙湁鐩婄殑鍙冭€冨拰鍊熼憭銆�

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/wp-content/uploads/2022/08/5.jpg

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/pc-cat-np60-hard-foam-catalyst-dimethylbenzylamine-nitro/

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/fascat4102-catalyst-monobutyl-tin-triisooctanoate-cas-23850-94-4/

鎿�(ku貌)灞曢柋璁€:https://www.newtopchem.com/archives/39748

鎿�(ku貌)灞曢柋璁€:https://www.newtopchem.com/archives/1002

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/cas-108-01-0-2/

鎿�(ku貌)灞曢柋璁€:https://www.newtopchem.com/archives/690

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/wp-content/uploads/2022/08/2-ethylhexanoic-acid-potassium-CAS-3164-85-0–K-15.pdf

鎿�(ku貌)灞曢柋璁€:https://www.morpholine.org/cas-83016-70-0/

鎿�(ku貌)灞曢柋璁€:https://www.cyclohexylamine.net/category/product/page/17/