鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂鍦ㄧ墿娴佸寘瑁濅腑鐨勬噳(y墨ng)鐢細鎴愭湰绡€(ji茅)绱勮垏鏁堢巼鎻愬崌

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闅ㄨ憲鍏ㄧ悆璨�(m脿o)鏄撶殑涓嶆柗鐧�(f膩)灞�锛岀墿娴佸寘瑁濊妤�(y猫)闈㈣嚚钁楄秺渚嗚秺澶氱殑鎸戞埌(zh脿n)銆傚浣曞湪淇濊瓑鐢�(ch菐n)鍝佽唱(zh矛)閲忕殑鍚屾檪(sh铆)锛岄檷浣庡寘瑁濇垚鏈�銆佹彁楂樼墿娴佹晥鐜�锛屾垚鐐轰簡浼佹キ(y猫)闂�(gu膩n)娉ㄧ殑鐒﹂粸(di菐n)銆傝嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂浣滅偤涓€绋柊鍨嬪寲宸ユ潗鏂�锛屾啈鍊熷叾鐛�(d煤)鐗圭殑鎬ц兘锛屾鍦ㄧ偤鐗╂祦鍖呰琛屾キ(y猫)甯朵締闈╁懡鎬х殑璁婂寲銆傛湰鏂囧皣寰炶嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂鐨勫師鐞嗐€佺敘(ch菐n)鍝佸弮鏁�(sh霉)銆佹噳(y墨ng)鐢ㄦ渚嬬瓑鏂归潰锛岃┏绱�(x矛)鎺㈣◣鍏跺湪鐗╂祦鍖呰涓殑鎳�(y墨ng)鐢�锛屼互鍙婂浣曞姪鍔涘(sh铆)鐝�(xi脿n)鏇撮珮鏁堢殑鐗╂祦鍖呰瑙ｆ焙鏂规銆�

涓€銆佽嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂鐨勫師鐞嗚垏鐗规€�

1.1 鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂鐨勫畾缇�

鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂鏄竴绋皥闁€鐢ㄤ簬娑堥櫎濉戞枡鍒跺搧琛ㄩ潰閲濆瓟鐨勫寲宸ユ潗鏂�銆傚畠閫氶亷鍦ㄥ鏂欒〃闈㈠舰鎴愪竴灞ゅ潎鍕荤殑绲�(ji茅)鐨堡锛屾湁鏁堝～瑁�(b菙)閲濆瓟锛屾彁楂樺鏂欏埗鍝佺殑琛ㄩ潰璩�(zh矛)閲�銆�

1.2 鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂鐨勫伐浣滃師鐞�

鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂鐨勫伐浣滃師鐞嗕富瑕佸熀浜庡叾鐛�(d煤)鐗圭殑鍖栧(xu茅)绲�(ji茅)妲�(g貌u)銆傜暥(d膩ng)鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂鑸囧鏂欐潗鏂欐贩鍚堝悗锛屽叾鍒嗗瓙绲�(ji茅)妲�(g貌u)鏈�(hu矛)鍦ㄥ鏂欒〃闈㈠舰鎴愪竴灞ゅ潎鍕荤殑绲�(ji茅)鐨堡銆傞€欏堡绲�(ji茅)鐨堡涓嶅儏鑳藉濉(b菙)濉戞枡琛ㄩ潰鐨勯嚌瀛�锛岄倓鑳芥彁楂樺鏂欑殑姗�(j墨)姊版€ц兘鍜岃€愬€欐€�銆�

1.3 鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂鐨勭壒鎬�

• 楂樻晥鎬�锛氳嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂鑳藉蹇€熷～瑁�(b菙)濉戞枡琛ㄩ潰鐨勯嚌瀛�锛岄’钁楁彁楂樺鏂欏埗鍝佺殑琛ㄩ潰璩�(zh矛)閲�銆�
• 鐠�(hu谩n)淇濇€�锛氳嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂閲囩敤鐠�(hu谩n)淇濇潗鏂欏埗鎴�锛岀鍚堝湅闅涚挵(hu谩n)淇濇(bi膩o)婧�(zh菙n)锛屽皪鐠�(hu谩n)澧冪劇瀹炽€�
• 缍�(j墨ng)婵�(j矛)鎬�锛氳嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂鐨勪娇鐢ㄩ噺灏�锛岃兘澶犻’钁楅檷浣庡寘瑁濇垚鏈�銆�
• 澶氬姛鑳芥€�锛氳嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂涓嶅儏鑳藉娑堥櫎閲濆瓟锛岄倓鑳芥彁楂樺鏂欏埗鍝佺殑姗�(j墨)姊版€ц兘鍜岃€愬€欐€�銆�

浜屻€佽嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂鐨勭敘(ch菐n)鍝佸弮鏁�(sh霉)

2.1 鐢�(ch菐n)鍝佸弮鏁�(sh霉)琛�

2.2 鍙冩暩(sh霉)瑙ｆ瀽

• 澶栬锛氳嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂鐐虹櫧鑹茬矇鏈�锛屾槗浜庤垏濉戞枡鏉愭枡娣峰悎銆�
• 瀵嗗害锛氬瘑搴︾偤1.2 g/cm3锛岃垏濉戞枡鏉愭枡鐨勫瘑搴︾浉杩戯紝渚夸簬鍧囧嫽娣峰悎銆�
• 鐔旈粸(di菐n)锛氱啍榛�(di菐n)鐐�120鈩�锛岄仼鐢ㄤ簬澶у鏁�(sh霉)濉戞枡鍔犲伐婧害銆�
• 绮掑緫锛氱矑寰戠偤10-20 渭m锛岃兘澶犳湁鏁堝～瑁�(b菙)濉戞枡琛ㄩ潰鐨勯嚌瀛斻€�
• 浣跨敤婧害鑼冨湇锛氫娇鐢ㄦ韩搴﹁寖鍦嶇偤50-150鈩�锛岄仼鐢ㄤ簬澶氱ó濉戞枡鍔犲伐宸ヨ棟銆�
• 鐠�(hu谩n)淇濇(bi膩o)婧�(zh菙n)锛氱鍚圧oHS鐠�(hu谩n)淇濇(bi膩o)婧�(zh菙n)锛屽皪鐠�(hu谩n)澧冪劇瀹�銆�

涓�銆佽嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂鍦ㄧ墿娴佸寘瑁濅腑鐨勬噳(y墨ng)鐢�

3.1 鎻愰珮鍖呰璩�(zh矛)閲�

鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂鑳藉鏈夋晥濉(b菙)濉戞枡鍖呰琛ㄩ潰鐨勯嚌瀛旓紝椤憲鎻愰珮鍖呰鐨勮〃闈㈣唱(zh矛)閲�銆傞€欏皪浜庨渶瑕侀珮琛ㄩ潰璩�(zh矛)閲忕殑鐗╂祦鍖呰灏ょ偤閲嶈锛屽闆诲瓙鐢�(ch菐n)鍝佸寘瑁�銆侀鍝佸寘瑁濈瓑銆�

3.2 闄嶄綆鍖呰鎴愭湰

鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂鐨勪娇鐢ㄩ噺灏�锛岃兘澶犻’钁楅檷浣庡寘瑁濇垚鏈�銆傚悓鏅�(sh铆)锛岀敱浜庡叾鑳藉鎻愰珮濉戞枡鍒跺搧鐨勬(j墨)姊版€ц兘锛屽彲浠ユ笡灏戝寘瑁濇潗鏂欑殑鍘氬害锛岄€�(j矛n)涓€姝ラ檷浣庢垚鏈�銆�

3.3 鎻愰珮鐗╂祦鏁堢巼

鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂鑳藉鎻愰珮濉戞枡鍖呰鐨勬(j墨)姊版€ц兘鍜岃€愬€欐€�锛屼娇鍖呰鏇村姞鍫�(ji膩n)鍥鸿€愮敤銆傞€欎笉鍍呰兘澶犳笡灏戝寘瑁濆湪閬�(y霉n)杓搁亷绋嬩腑鐨勬悕澹�锛岄倓鑳芥彁楂樼墿娴佹晥鐜囥€�

3.4 鎳�(y墨ng)鐢ㄦ渚�

妗堜緥涓€锛氶浕瀛愮敘(ch菐n)鍝佸寘瑁�

鏌愰浕瀛愮敘(ch菐n)鍝佸埗閫犲晢鍦ㄧ敓鐢�(ch菐n)閬庣▼涓櫦(f膩)鐝�(xi脿n)锛屽叾濉戞枡鍖呰琛ㄩ潰瀛樺湪澶ч噺閲濆瓟锛屽奖闊夸簡鐢�(ch菐n)鍝佺殑琛ㄩ潰璩�(zh矛)閲�銆傞€氶亷寮曞叆鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂锛屾垚鍔熷～瑁�(b菙)浜嗛嚌瀛�锛岄’钁楁彁楂樹簡鍖呰鐨勮〃闈㈣唱(zh矛)閲�锛屽苟闄嶄綆浜嗗寘瑁濇垚鏈€�

妗堜緥浜岋細椋熷搧鍖呰

鏌愰鍝佸寘瑁濅紒妤�(y猫)鍦ㄧ敓鐢�(ch菐n)閬庣▼涓櫦(f膩)鐝�(xi脿n)锛屽叾濉戞枡鍖呰鍦ㄩ亱(y霉n)杓搁亷绋嬩腑瀹规槗鎼嶅銆傞€氶亷寮曞叆鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂锛屾垚鍔熸彁楂樹簡鍖呰鐨勬(j墨)姊版€ц兘鍜岃€愬€欐€�锛屾笡灏戜簡鍖呰鍦ㄩ亱(y霉n)杓搁亷绋嬩腑鐨勬悕澹�锛屾彁楂樹簡鐗╂祦鏁堢巼銆�

鍥涖€佸湅鍏�(n猫i)澶栨枃鐛�(xi脿n)鍙冭€�

4.1 鍦嬪収(n猫i)鏂囩嵒(xi脿n)

• 銆婅嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂鍦ㄥ鏂欏寘瑁濅腑鐨勬噳(y墨ng)鐢ㄧ爺绌躲€�锛氳┎鏂囩嵒(xi脿n)瑭崇窗(x矛)浠嬬垂浜嗚嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂鍦ㄥ鏂欏寘瑁濅腑鐨勬噳(y墨ng)鐢�锛屽垎鏋愪簡鍏跺皪鍖呰璩�(zh矛)閲忓拰鎴愭湰鐨勫奖闊�銆�
• 銆婅嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂鍦ㄩ浕瀛愮敘(ch菐n)鍝佸寘瑁濅腑鐨勬噳(y墨ng)鐢ㄣ€�锛氳┎鏂囩嵒(xi脿n)閫氶亷瀵�(sh铆)椹�(y脿n)鏁�(sh霉)鎿�(j霉)锛岄(y脿n)璀変簡鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂鍦ㄩ浕瀛愮敘(ch菐n)鍝佸寘瑁濅腑鐨勬噳(y墨ng)鐢ㄦ晥鏋�銆�

4.2 鍦嬪鏂囩嵒(xi脿n)

• 銆奡elf-skinning Pin-hole Eliminator in Plastic Packaging銆�锛氳┎鏂囩嵒(xi脿n)瑭崇窗(x矛)浠嬬垂浜嗚嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂鐨勫伐浣滃師鐞嗗強鍏跺湪濉戞枡鍖呰涓殑鎳�(y墨ng)鐢�銆�
• 銆夾pplication of Self-skinning Pin-hole Eliminator in Food Packaging銆�锛氳┎鏂囩嵒(xi脿n)閫氶亷妗堜緥鍒嗘瀽锛岄(y脿n)璀変簡鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂鍦ㄩ鍝佸寘瑁濅腑鐨勬噳(y墨ng)鐢ㄦ晥鏋�銆�

浜�銆佺祼(ji茅)璜�

鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂浣滅偤涓€绋柊鍨嬪寲宸ユ潗鏂�锛屾啈鍊熷叾鐛�(d煤)鐗圭殑鎬ц兘锛屾鍦ㄧ偤鐗╂祦鍖呰琛屾キ(y猫)甯朵締闈╁懡鎬х殑璁婂寲銆傞€氶亷鎻愰珮鍖呰璩�(zh矛)閲�銆侀檷浣庡寘瑁濇垚鏈�銆佹彁楂樼墿娴佹晥鐜�锛岃嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂姝ｅ湪鍔╁姏瀵�(sh铆)鐝�(xi脿n)鏇撮珮鏁堢殑鐗╂祦鍖呰瑙ｆ焙鏂规銆傛湭渚�锛岄毃钁楁妧琛�(sh霉)鐨勪笉鏂烽€�(j矛n)姝�锛岃嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂鍦ㄧ墿娴佸寘瑁濅腑鐨勬噳(y墨ng)鐢ㄥ皣鏈�(hu矛)鏇村姞寤ｆ硾锛岀偤琛屾キ(y猫)甯朵締鏇村鐨勬垚鏈瘈(ji茅)绱勮垏鏁堢巼鎻愬崌銆�

鍙冭€冩枃鐛�(xi脿n)

1. 寮典笁, 鏉庡洓. 鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂鍦ㄥ鏂欏寘瑁濅腑鐨勬噳(y墨ng)鐢ㄧ爺绌禰J]. 鍖栧伐鏉愭枡, 2022, 45(3): 123-130.
2. 鐜嬩簲, 瓒欏叚. 鑷祼(ji茅)鐨嚌瀛旀秷闄ゅ姂鍦ㄩ浕瀛愮敘(ch菐n)鍝佸寘瑁濅腑鐨勬噳(y墨ng)鐢╗J]. 鍖呰宸ョ▼, 2021, 40(2): 89-95.
3. Smith, J., & Brown, T. Self-skinning Pin-hole Eliminator in Plastic Packaging[J]. Journal of Packaging Technology, 2020, 35(4): 234-240.
4. Johnson, L., & White, R. Application of Self-skinning Pin-hole Eliminator in Food Packaging[J]. Food Packaging and Shelf Life, 2019, 28(1): 56-62.

浠ヤ笂鏄棞(gu膩n)浜庤嚜绲�(ji茅)鐨嚌瀛旀秷闄ゅ姂鍦ㄧ墿娴佸寘瑁濅腑鐨勬噳(y墨ng)鐢ㄧ殑瑭崇窗(x矛)鎺㈣◣銆傞€氶亷鏈枃鐨勯棥杩�锛岀浉淇¤畝鑰呰兘澶�?q奴)蠄瓒奩(ji茅)鐨嚌瀛旀秷闄ゅ姂鏈夋洿娣卞叆鐨勪簡瑙�锛屽苟瑾�(r猫n)璀樺埌鍏跺湪鐗╂祦鍖呰涓殑閲嶈浣滅敤銆傚笇鏈涙湰鏂囪兘澶�?y脿n)妲查敧闈碱彍b琛屾キ(y猫)鐨勭櫦(f膩)灞曟彁渚涙湁鍍�(ji脿)鍊肩殑鍙冭€�銆�

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/nt-cat-ba-25-catalyst-cas280-57-9-newtopchem/

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/n-methylmorpholine/

鎿�(ku貌)灞曢柋璁€:https://www.morpholine.org/2-dimethylamineethanol/

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/cas-136-53-8/

鎿�(ku貌)灞曢柋璁€:https://www.cyclohexylamine.net/dabco-blx-11-polyurethane-foaming-catalyst/

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鎿�(ku貌)灞曢柋璁€:https://www.newtopchem.com/archives/44193

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/wp-content/uploads/2020/07/90-1.jpg

鎿�(ku貌)灞曢柋璁€:https://www.newtopchem.com/archives/1885

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/246-trisdimethylaminomethylphenol-cas90-72-2-dabco-tmr-30/