鍗婄‖娉″偓鍖栧姂TMR-3姒傝堪

鍗婄‖娉″偓鍖栧姂TMR-3鏄竴绋皥(zhu膩n)闁€(m茅n)鐢ㄤ簬鑱氭皑閰场娌敓鐢�(ch菐n)鐨勯珮鏁堝偓鍖栧姂锛屽唬娉涙噳(y墨ng)鐢ㄤ簬姹借粖(ch膿)搴ф鍒堕€犵瓑闋�(l菒ng)鍩�銆傚叾鍖栧(xu茅)鍚嶇ū(ch膿ng)鐐轰笁鐢插熀鎴婁簩鑳猴紙Trimethylpentanediamine锛�锛屽爆浜庡彅鑳洪(l猫i)鍌寲鍔戙€俆MR-3鍏锋湁鍎�(y艒u)鐣扮殑鍌寲鎬ц兘锛岃兘澶犳湁鏁堜績閫�(j矛n)鐣版鞍閰搁叝鑸囧鍏冮唶涔嬮枔鐨勫弽鎳�(y墨ng)锛屽緸鑰岀敓鎴愬叿鏈夎壇濂界墿鐞嗘(j墨)姊版€ц兘鐨勮仛姘ㄩ叝娉℃搏鏉愭枡銆傝┎鍌寲鍔戝湪甯告韩涓嬬偤鐒�(w煤)鑹叉垨娣￠粌鑹叉恫楂�锛屽叿鏈夎純浣庣殑鎻櫦(f膩)鎬у拰鑹ソ鐨勫劜(ch菙)瀛樼┅(w臎n)瀹氭€�銆�

TMR-3鐨勪富瑕佺壒鎬�

1. 楂樻椿鎬�锛歍MR-3鑳藉鍦ㄨ純浣庣殑鐢ㄩ噺涓嬫彁渚涢珮鏁堢殑鍌寲鏁堟灉锛岄’钁楃府鐭场娌櫦(f膩)娉℃檪(sh铆)闁�锛屾彁楂樼敓鐢�(ch菐n)鏁堢巼銆�
2. 閬告搰鎬�锛氳┎鍌寲鍔戝皪(du矛)鐣版鞍閰搁叝鑸囧鍏冮唶鐨勫弽鎳�(y墨ng)鍏锋湁杓冮珮鐨勯伕鎿囨€�锛岃兘澶犳湁鏁堟帶鍒舵场娌殑瀵嗗害鍜岀‖搴�锛岀⒑淇濈祩鐢�(ch菐n)鍝佺殑璩�(zh矛)閲忕┅(w臎n)瀹�銆�
3. 浣庢埃鍛�锛氱浉姣斿偝绲�(t菕ng)鐨勫彅鑳洪(l猫i)鍌寲鍔戯紝TMR-3鍏锋湁鏇翠綆鐨勬彯鐧�(f膩)鎬�锛屾笡灏戜簡鐢熺敘(ch菐n)閬�(gu貌)绋嬩腑鍜屾垚鍝佷腑鐨勭暟鍛冲晱(w猫n)椤�锛屾彁鍗囦簡鐢ㄦ埗(h霉)楂旈(y脿n)銆�
4. 鐠�(hu谩n)淇濇€�锛歍MR-3绗﹀悎鍤�(y谩n)鏍肩殑鐠�(hu谩n)淇濇(bi膩o)婧�(zh菙n)锛屼笉鍚噸閲戝爆鍜屽叾浠栨湁瀹崇墿璩�(zh矛)锛岄仼鐢ㄤ簬缍犺壊鍒堕€犲伐钘濄€�
5. 鍏煎鎬�锛氳┎鍌寲鍔戣垏澶氱ó鑱氭皑閰師鏂欏叿鏈夎壇濂界殑鍏煎鎬�锛岃兘澶犺垏鍏朵粬鍔╁姂锛堝鐧�(f膩)娉″姂銆佺┅(w臎n)瀹氬姂绛夛級鍗�(xi茅)鍚屼綔鐢�锛屽劒(y艒u)鍖栭厤鏂硅ō(sh猫)瑷�(j矛)銆�

TMR-3鐨勬噳(y墨ng)鐢ㄩ牁(l菒ng)鍩�

TMR-3涓昏鎳�(y墨ng)鐢ㄤ簬姹借粖(ch膿)搴ф鍒堕€�銆佸鍏�銆佸簥澧�銆佸寘瑁濇潗鏂欑瓑闋�(l菒ng)鍩�銆傚湪姹借粖(ch膿)搴ф鍒堕€犱腑锛孴MR-3鐨勪綔鐢ㄥ挨鐐虹獊鍑�銆傚畠涓嶅儏鑳藉鎻愬崌搴ф鐨勮垝閬╁害鍜岃€愮敤鎬э紝閭勮兘婊胯冻姹借粖(ch膿)琛屾キ(y猫)灏�(du矛)杓曢噺鍖�銆佸畨鍏ㄦ€у拰鐠�(hu谩n)淇濇€х殑鍤�(y谩n)鏍艰姹傘€傛澶�锛孴MR-3閭勫彲浠ョ敤浜庣敓鐢�(ch菐n)楂樺挤(qi谩ng)搴�銆佷綆瀵嗗害鐨勭祼(ji茅)妲�(g貌u)娉℃搏锛屽唬娉涙噳(y墨ng)鐢ㄤ簬姹借粖(ch膿)鍏�(n猫i)椋俱€佸剙琛ㄧ洡(p谩n)銆侀杸(m茅n)鏉跨瓑閮ㄤ欢鐨勫埗閫犮€�

鍦�(gu贸)鍏�(n猫i)澶栫爺绌剁従(xi脿n)鐙€

杩戝勾渚�(l谩i)锛岄毃钁楁苯杌�(ch膿)宸ユキ(y猫)鐨勫揩閫熺櫦(f膩)灞�锛岀壒鍒ユ槸闆诲嫊(d貌ng)姹借粖(ch膿)鍜屾櫤鑳芥苯杌�(ch膿)鐨勮垐璧�锛屾苯杌�(ch膿)搴ф鐨勮ō(sh猫)瑷�(j矛)鍜屽埗閫犳妧琛�(sh霉)涔熺櫦(f膩)鐢熶簡閲嶅ぇ璁婇潻銆傜偤浜嗘豢瓒冲競鍫�(ch菐ng)灏�(du矛)楂樻€ц兘銆佽紩閲忓寲銆佺挵(hu谩n)淇濆瀷搴ф鐨勯渶姹傦紝鍦�(gu贸)鍏�(n猫i)澶栫爺绌朵汉鍝″皪(du矛)鑱氭皑閰场娌潗鏂欏強鍏跺偓鍖栧姂閫�(j矛n)琛屼簡澶ч噺鐮旂┒銆傚湅(gu贸)澶栨枃鐛�(xi脿n)涓紝瑷卞瀛�(xu茅)鑰呴€氶亷(gu貌)瀵�(sh铆)椹�(y脿n)椹�(y脿n)璀変簡TMR-3鍦ㄦ苯杌�(ch膿)搴ф鍒堕€犱腑鐨勫劒(y艒u)鍕�(sh矛)锛屽苟鎻愬嚭浜嗗劒(y艒u)鍖栭厤鏂圭殑寤鸿銆備緥濡�锛岀編鍦�(gu贸)瀵嗘瓏鏍瑰ぇ瀛�(xu茅)鐨勪竴闋�(xi脿ng)鐮旂┒琛ㄦ槑锛屼娇鐢═MR-3浣滅偤鍌寲鍔戝彲浠ラ’钁楁彁楂樻场娌殑鍥炲綀鎬�锛屽欢闀�(zh菐ng)搴ф鐨勪娇鐢ㄥ＝鍛姐€傚湅(gu贸)鍏�(n猫i)鏂归潰锛屾竻鑿ぇ瀛�(xu茅)銆佹禉姹熷ぇ瀛�(xu茅)绛夐珮鏍′篃鍦ㄧ浉闂�(gu膩n)闋�(l菒ng)鍩熷彇寰椾簡閲嶈閫�(j矛n)灞�锛岄枊(k膩i)鐧�(f膩)鍑轰簡涓€绯诲垪鍩轰簬TMR-3鐨勬柊鍨嬭仛姘ㄩ叝娉℃搏鏉愭枡銆�

TMR-3鍦ㄦ苯杌�(ch膿)搴ф鍒堕€犱腑鐨勬噳(y墨ng)鐢ㄥ師鐞�

TMR-3浣滅偤涓€绋珮鏁堢殑鍙旇兒椤�(l猫i)鍌寲鍔�锛屽叾鍦ㄦ苯杌�(ch膿)搴ф鍒堕€犱腑鐨勬噳(y墨ng)鐢ㄥ師鐞嗕富瑕侀珨鐝�(xi脿n)鍦ㄤ互涓嬪咕鍊�(g猫)鏂归潰锛�

1. 鐣版鞍閰搁叝鑸囧鍏冮唶鐨勫弽鎳�(y墨ng)姗�(j墨)鐞�

鑱氭皑閰场娌殑鍒跺倷閬�(gu貌)绋嬮€氬父娑夊強鐣版鞍閰搁叝锛堝TDI銆丮DI锛夎垏澶氬厓閱囷紙濡傝仛閱氬鍏冮唶銆佽仛閰鍏冮唶锛変箣闁撶殑鍙嶆噳(y墨ng)銆俆MR-3浣滅偤鍌寲鍔�锛岃兘澶犲姞閫熼€欎竴鍙嶆噳(y墨ng)鐨勯€�(j矛n)琛�锛屽叿楂旇〃鐝�(xi脿n)鐐轰互涓嬪咕鍊�(g猫)姝ラ锛�

• 姝ワ細鐣版鞍閰搁叝鐨勬椿鍖�
  TMR-3閫氶亷(gu貌)鑸囩暟姘伴吀閰垎瀛愪腑鐨凬=C=O鍩哄湗(tu谩n)鐩镐簰浣滅敤锛岄檷浣庝簡鍏跺弽鎳�(y墨ng)鑳藉锛屼娇寰楃暟姘伴吀閰洿瀹规槗鑸囧鍏冮唶鐧�(f膩)鐢熷弽鎳�(y墨ng)銆傞€欎竴閬�(gu貌)绋嬪彲浠ラ€氶亷(gu貌)浠ヤ笅鍖栧(xu茅)鏂圭▼寮忚〃绀猴細
  [
  text{R-N=C=O} + text{TMR-3} rightarrow text{R-NH-CO-TMR-3}
  ]
  鍏朵腑锛孯浠ｈ〃鐣版鞍閰搁叝鍒嗗瓙涓殑鐑峰熀鎴栬姵鍩�銆�

• 绗簩姝ワ細澶氬厓閱囩殑瑕牳鏀绘搳
  鍦═MR-3鐨勫偓鍖栦綔鐢ㄤ笅锛屽鍏冮唶鍒嗗瓙涓殑缇ュ熀锛�-OH锛変綔鐐鸿Κ鏍歌│鍔�锛屾敾鎿婃椿鍖栫殑鐣版鞍閰搁叝鍒嗗瓙锛屽舰鎴愭皑鍩虹敳閰搁叝閸碉紙-NH-COO-锛夈€傞€欎竴鍙嶆噳(y墨ng)鏄仛姘ㄩ叝娉℃搏褰㈡垚鐨勫熀绀�(ch菙)锛屾焙瀹氫簡娉℃搏鐨勪氦鑱�(li谩n)瀵嗗害鍜屽姏瀛�(xu茅)鎬ц兘銆�

• 绗笁姝ワ細娉℃搏鑶ㄨ劰鑸囧浐鍖�
  闅ㄨ憲鍙嶆噳(y墨ng)鐨勯€�(j矛n)琛岋紝楂旂郴涓殑姘ｉ珨锛堝浜屾哀鍖栫⒊銆佹爱?d煤)鐛鹃緥鈹查ゾu閲嬫斁锛屼績浣挎场娌啫鑴�銆傚悓鏅�(sh铆)锛孴MR-3绻肩簩(x霉)鍌寲鐣版鞍閰搁叝鑸囧鍏冮唶鐨勯€�(j矛n)涓€姝ュ弽鎳�(y墨ng)锛岀祩褰㈡垚鍥哄寲鐨勮仛姘ㄩ叝娉℃搏鏉愭枡銆傞€欎竴閬�(gu貌)绋嬪彲浠ラ€氶亷(gu貌)浠ヤ笅鍖栧(xu茅)鏂圭▼寮忚〃绀猴細
  [
  text{R-NH-CO-OH} + text{CO}_2 rightarrow text{R-NH-CO-O-} text{CO}_2
  ]

2. 娉℃搏瀵嗗害鑸囩‖搴︾殑瑾�(di脿o)鎺�

TMR-3鐨勫彟涓€鍊�(g猫)閲嶈鍔熻兘鏄(di脿o)鎺ф场娌殑瀵嗗害鍜岀‖搴�銆傞€氶亷(gu貌)瑾�(di脿o)鏁碩MR-3鐨勭敤閲�锛屽彲浠ョ簿纰烘帶鍒舵场娌殑鐧�(f膩)娉￠€熷害鍜屼氦鑱�(li谩n)绋嬪害锛屽緸鑰屽(sh铆)鐝�(xi脿n)灏�(du矛)娉℃搏瀵嗗害鍜岀‖搴︾殑瑾�(di脿o)绡€(ji茅)銆傚叿楂斾締(l谩i)瑾�(shu艒)锛�

• 浣庡瘑搴︽场娌�锛氱暥(d膩ng)TMR-3鐨勭敤閲忚純浣庢檪(sh铆)锛屾场娌殑鐧�(f膩)娉￠€熷害杓冩參锛屾埃楂旀湁瓒冲鐨勬檪(sh铆)闁撴摯(ku貌)鏁�锛屽舰鎴愯純澶х殑姘ｆ场绲�(ji茅)妲�(g貌u)锛屽皫(d菐o)鑷存场娌瘑搴﹁純浣庛€傞€欑ó浣庡瘑搴︽场娌叿鏈夎純濂界殑鏌旇粺鎬у拰鑸掗仼鎬�锛岄仼鐢ㄤ簬姹借粖(ch膿)搴ф鐨勫骇澧婇儴鍒�銆�

• 楂樺瘑搴︽场娌�锛氱暥(d膩ng)TMR-3鐨勭敤閲忚純楂樻檪(sh铆)锛屾场娌殑鐧�(f膩)娉￠€熷害杓冨揩锛屾埃楂旀摯(ku貌)鏁ｄ笉鍏呭垎锛屽舰鎴愯純灏忕殑姘ｆ场绲�(ji茅)妲�(g貌u)锛屽皫(d菐o)鑷存场娌瘑搴﹁純楂樸€傞€欑ó楂樺瘑搴︽场娌叿鏈夎純濂界殑鏀拹鎬у拰鑰愮（鎬�锛岄仼鐢ㄤ簬姹借粖(ch膿)搴ф鐨勯潬鑳岄儴鍒�銆�

3. 娉℃搏鐨勫洖褰堟€у拰鑰愪箙鎬�

TMR-3閭勮兘澶犻’钁楁彁楂樻场娌殑鍥炲綀鎬у拰鑰愪箙鎬�銆傞€欐槸鐢变簬TMR-3淇冮€�(j矛n)浜嗙暟姘伴吀閰垏澶氬厓閱囦箣闁撶殑浜よ伅(li谩n)鍙嶆噳(y墨ng)锛屽舰鎴愪簡鏇村姞鑷村瘑鐨勪笁缍恫(w菐ng)绲�(lu貌)绲�(ji茅)妲�(g貌u)銆傞€欑ó绲�(ji茅)妲�(g貌u)璩︿簣浜嗘场娌潗鏂欐洿濂界殑褰堟€у拰鎶楃柌鍕炴€ц兘锛屼娇鍏惰兘澶犲湪闀�(zh菐ng)鏅�(sh铆)闁撲娇鐢ㄥ悗浠嶄繚鎸佽壇濂界殑褰㈢媭鍜屾€ц兘銆傛澶�锛孴MR-3閭勮兘澶犳笡灏戞场娌潗鏂欎腑鐨勫井瀛旂己闄�锛岄€�(j矛n)涓€姝ユ彁楂樹簡娉℃搏鐨勬(j墨)姊板挤(qi谩ng)搴﹀拰鑰愮敤鎬�銆�

4. 鐠�(hu谩n)淇濇€ц垏瀹夊叏鎬�

TMR-3浣滅偤涓€绋挵(hu谩n)淇濆瀷鍌寲鍔戯紝绗﹀悎鐝�(xi脿n)浠ｆ苯杌�(ch膿)鍒堕€犳キ(y猫)灏�(du矛)缍犺壊鐢熺敘(ch菐n)鐨勮姹�銆傞鍏堬紝TMR-3鏈韩涓嶅惈閲嶉噾灞拰鍏朵粬鏈夊鐗╄唱(zh矛)锛屼笉鏈�(hu矛)灏�(du矛)鐠�(hu谩n)澧冮€犳垚姹℃煋銆傚叾娆★紝TMR-3鍏锋湁杓冧綆鐨勬彯鐧�(f膩)鎬�锛屾笡灏戜簡鐢熺敘(ch菐n)閬�(gu貌)绋嬩腑鍜屾垚鍝佷腑鐨勭暟鍛冲晱(w猫n)椤岋紝鎻愬崌浜嗙敤鎴�(h霉)鐨勪娇鐢ㄩ珨椹�(y脿n)銆傚悗锛孴MR-3鑳藉鑸囧绋挵(hu谩n)淇濆瀷鐧�(f膩)娉″姂锛堝姘寸櫦(f膩)娉″姂銆佺墿鐞嗙櫦(f膩)娉″姂绛夛級鍗�(xi茅)鍚屼綔鐢�锛岄€�(j矛n)涓€姝ラ檷浣庣敓鐢�(ch菐n)閬�(gu貌)绋嬩腑鐨刅OC锛堟彯鐧�(f膩)鎬ф湁姗�(j墨)鍖栧悎鐗╋級鎺掓斁锛岀鍚堟棩鐩婂毚(y谩n)鏍肩殑鐠�(hu谩n)淇濇硶瑕�(gu墨)銆�

TMR-3鍦ㄦ苯杌�(ch膿)搴ф鍒堕€犱腑鐨勫叿楂旀噳(y墨ng)鐢ㄦ渚�

鐐轰簡鏇村ソ鍦扮悊瑙MR-3鍦ㄦ苯杌�(ch膿)搴ф鍒堕€犱腑鐨勫(sh铆)闅涙噳(y墨ng)鐢�锛屼互涓嬫槸骞惧€�(g猫)鍏烽珨鐨勬渚嬪垎鏋�锛屾兜钃嬩簡涓嶅悓椤�(l猫i)鍨嬬殑姹借粖(ch膿)搴ф浠ュ強鐩告噳(y墨ng)鐨勭敓鐢�(ch菐n)宸ヨ棟銆�

妗堜緥涓€锛氳豹鑿綆杌�(ch膿)搴ф鐨勫埗閫�

鑳屾櫙锛氭煇鍦�(gu贸)闅涚煡鍚嶈豹鑿綆杌�(ch膿)鍝佺墝鍦ㄨō(sh猫)瑷�(j矛)鏂版杌�(ch膿)鍨嬫檪(sh铆)锛屾彁鍑轰簡灏�(du矛)搴ф鑸掗仼鎬у拰鑰愮敤鎬х殑鏇撮珮瑕佹眰銆傜偤浜嗘豢瓒抽€欎竴闇€姹傦紝鍒堕€犲晢姹哄畾閲囩敤TMR-3浣滅偤鍌寲鍔�锛岀敓鐢�(ch菐n)楂樻€ц兘鐨勮仛姘ㄩ叝娉℃搏搴ф銆�

宸ヨ棟娴佺▼锛�

1. 鍘熸潗鏂欐簴(zh菙n)鍌�锛氶伕鐢ㄩ珮鍒嗗瓙閲忕殑鑱氶啔澶氬厓閱囧拰MDI浣滅偤涓昏鍘熸枡锛屽姞鍏ラ仼閲忕殑TMR-3浣滅偤鍌寲鍔�锛屼互鍙婂叾浠栧姪鍔戯紙濡傜櫦(f膩)娉″姂銆佺┅(w臎n)瀹氬姂绛夛級銆�
2. 娣峰悎鑸囩櫦(f膩)娉�锛氬皣涓婅堪鍘熸潗鏂欐寜鐓т竴瀹氭瘮渚嬫贩鍚堝潎鍕伙紝鍊掑叆妯″叿涓€�(j矛n)琛岀櫦(f膩)娉�銆傜敱浜嶵MR-3鐨勯珮鏁堝偓鍖栦綔鐢�锛屾场娌殑鐧�(f膩)娉￠€熷害閬╀腑锛岃兘澶犲湪鐭檪(sh铆)闁撳収(n猫i)瀹屾垚鎴愬瀷銆�
3. 鍥哄寲鑸囪劔妯�锛氱櫦(f膩)娉″畬鎴愬悗锛屽皣妯″叿鏀惧叆鐑樼涓€�(j矛n)琛屽姞鐔卞浐鍖栵紝婧害鎺у埗鍦�80-100鈩冧箣闁�锛屾檪(sh铆)闁撶偤10-15鍒嗛悩銆傚浐鍖栧悗鐨勬场娌潗鏂欏叿鏈夎壇濂界殑褰堟€у拰鏀拹鎬�锛岄仼鍚堢敤浜庤豹鑿綆杌�(ch膿)搴ф鐨勫埗閫�銆�
4. 鍚庤檿鐞�锛氬皣鍥哄寲鍚庣殑娉℃搏鏉愭枡寰炴ā鍏蜂腑鍙栧嚭锛岄€�(j矛n)琛岃〃闈慨鏁村拰鎵撶（锛岀⒑淇濆骇妞呯殑澶栬璩�(zh矛)閲�銆傞毃鍚�锛屽皣娉℃搏鏉愭枡鑸囩毊闈╂垨鍏朵粬瑁濋＞鏉愭枡閫�(j矛n)琛岀祫瑁�锛屽畬鎴愬骇妞呯殑绲傚埗閫�銆�

鎬ц兘娓�(c猫)瑭�锛�

• 鍥炲綀鎬�锛氭牴鎿�(j霉)ASTM D3574妯�(bi膩o)婧�(zh菙n)閫�(j矛n)琛屾脯(c猫)瑭�锛岀祼(ji茅)鏋滈’绀哄骇妞呯殑鍥炲綀鎬ч仈(d谩)鍒颁簡95%浠ヤ笂锛岄仩(yu菐n)楂樹簬鍌崇当(t菕ng)搴ф鐨�85%銆�
• 鑰愪箙鎬�锛氱稉(j墨ng)閬�(gu貌)10钀�(w脿n)娆″绺惊鐠�(hu谩n)娓�(c猫)瑭�锛屽骇妞呯殑褰㈣畩鐜囧儏鐐�2%锛岃〃鐝�(xi脿n)鍑哄劒(y艒u)鐣扮殑鎶楃柌鍕炴€ц兘銆�
• 鑸掗仼鎬�锛氶€氶亷(gu貌)灏�(du矛)100鍚嶅織鎰胯€呴€�(j矛n)琛岃│鍧愰珨椹�(y脿n)锛�90%浠ヤ笂鐨勫彈瑷€呰〃绀哄骇妞呯殑鑸掗仼搴﹂潪甯告豢鎰�锛屽挨鍏舵槸闀�(zh菐ng)鏅�(sh铆)闁撻椐涙檪(sh铆)鐨勬敮鎾愭劅鍜岄€忔埃鎬�銆�

绲�(ji茅)璜�锛歍MR-3鐨勪娇鐢ㄩ’钁楁彁鍗囦簡璞彲杞庤粖(ch膿)搴ф鐨勭稖鍚堟€ц兘锛岀壒鍒ユ槸鍦ㄥ洖褰堟€у拰鑰愪箙鎬ф柟闈㈣〃鐝�(xi脿n)绐佸嚭銆傞€欎笉鍍呮彁楂樹簡鐢ㄦ埗(h霉)鐨勯涔橀珨椹�(y脿n)锛屼篃鐐哄埗閫犲晢璐忓緱浜嗘洿澶氱殑甯傚牬(ch菐ng)浠介銆�

妗堜緥浜岋細闆诲嫊(d貌ng)姹借粖(ch膿)搴ф鐨勮紩閲忓寲瑷�(sh猫)瑷�(j矛)

鑳屾櫙锛氶毃钁楅浕鍕�(d貌ng)姹借粖(ch膿)甯傚牬(ch菐ng)鐨勮繀閫熺櫦(f膩)灞�锛岃紩閲忓寲瑷�(sh猫)瑷�(j矛)鎴愮偤姹借粖(ch膿)搴ф鍒堕€犵殑閲嶈瓒ㄥ嫝(sh矛)銆傜偤浜嗛檷浣庢暣杌�(ch膿)閲嶉噺锛屾彁鍗囩簩(x霉)鑸噷绋�锛屾煇闆诲嫊(d貌ng)姹借粖(ch膿)鍒堕€犲晢姹哄畾閲囩敤TMR-3浣滅偤鍌寲鍔戯紝鐢熺敘(ch菐n)浣庡瘑搴�銆侀珮寮�(qi谩ng)搴︾殑鑱氭皑閰场娌骇妞呫€�

宸ヨ棟娴佺▼锛�

1. 鍘熸潗鏂欓伕鎿�锛氶伕鐢ㄤ綆瀵嗗害鐨勮仛閱氬鍏冮唶鍜孴DI浣滅偤涓昏鍘熸枡锛屽姞鍏ラ仼閲忕殑TMR-3浣滅偤鍌寲鍔戯紝浠ュ強鍏朵粬鍔╁姂锛堝鐧�(f膩)娉″姂銆佺┅(w臎n)瀹氬姂绛夛級銆�
2. 娣峰悎鑸囩櫦(f膩)娉�锛氬皣涓婅堪鍘熸潗鏂欐寜鐓т竴瀹氭瘮渚嬫贩鍚堝潎鍕�锛屽€掑叆妯″叿涓€�(j矛n)琛岀櫦(f膩)娉°€傜敱浜嶵MR-3鐨勯珮鏁堝偓鍖栦綔鐢�锛屾场娌殑鐧�(f膩)娉￠€熷害杓冨揩锛岃兘澶犲湪鐭檪(sh铆)闁撳収(n猫i)瀹屾垚鎴愬瀷銆�
3. 鍥哄寲鑸囪劔妯�锛氱櫦(f膩)娉″畬鎴愬悗锛屽皣妯″叿鏀惧叆鐑樼涓€�(j矛n)琛屽姞鐔卞浐鍖�锛屾韩搴︽帶鍒跺湪60-80鈩冧箣闁�锛屾檪(sh铆)闁撶偤5-10鍒嗛悩銆傚浐鍖栧悗鐨勬场娌潗鏂欏叿鏈夎純浣庣殑瀵嗗害鍜岃純楂樼殑寮�(qi谩ng)搴�锛岄仼鍚堢敤浜庨浕鍕�(d貌ng)姹借粖(ch膿)搴ф鐨勫埗閫犮€�
4. 鍚庤檿鐞�锛氬皣鍥哄寲鍚庣殑娉℃搏鏉愭枡寰炴ā鍏蜂腑鍙栧嚭锛岄€�(j矛n)琛岃〃闈慨鏁村拰鎵撶（锛岀⒑淇濆骇妞呯殑澶栬璩�(zh矛)閲忋€傞毃鍚�锛屽皣娉℃搏鏉愭枡鑸囩箶鐗╂垨鍏朵粬瑁濋＞鏉愭枡閫�(j矛n)琛岀祫瑁�锛屽畬鎴愬骇妞呯殑绲傚埗閫�銆�

鎬ц兘娓�(c猫)瑭�锛�

• 瀵嗗害锛氭牴鎿�(j霉)ASTM D1622妯�(bi膩o)婧�(zh菙n)閫�(j矛n)琛屾脯(c猫)瑭︼紝绲�(ji茅)鏋滈’绀哄骇妞呯殑瀵嗗害鍍呯偤30-40 kg/m3锛屾瘮鍌崇当(t菕ng)搴ф闄嶄綆浜嗙磩30%銆�
• 寮�(qi谩ng)搴�锛氭牴鎿�(j霉)ASTM D3763妯�(bi膩o)婧�(zh菙n)閫�(j矛n)琛屾脯(c猫)瑭�锛岀祼(ji茅)鏋滈’绀哄骇妞呯殑鎶楀寮�(qi谩ng)搴﹂仈(d谩)鍒颁簡150 kPa浠ヤ笂锛岃〃鐝�(xi脿n)鍑哄劒(y艒u)鐣扮殑鍔涘(xu茅)鎬ц兘銆�
• 杓曢噺鍖栨晥鏋�锛氶€氶亷(gu貌)灏�(du矛)鏁磋粖(ch膿)閲嶉噺閫�(j矛n)琛屾脯(c猫)閲�锛岀櫦(f膩)鐝�(xi脿n)浣跨敤TMR-3鐢熺敘(ch菐n)鐨勫骇妞呮瘮鍌崇当(t菕ng)搴ф娓涜紩浜嗙磩2 kg锛岄’钁楁彁鍗囦簡闆诲嫊(d貌ng)姹借粖(ch膿)鐨勭簩(x霉)鑸噷绋�銆�

绲�(ji茅)璜�锛歍MR-3鐨勪娇鐢ㄤ笉鍍呭(sh铆)鐝�(xi脿n)浜嗛浕鍕�(d貌ng)姹借粖(ch膿)搴ф鐨勮紩閲忓寲瑷�(sh猫)瑷�(j矛)锛岄倓淇濊瓑浜嗗骇妞呯殑寮�(qi谩ng)搴﹀拰鑸掗仼鎬�銆傞€欑偤闆诲嫊(d貌ng)姹借粖(ch膿)鍒堕€犲晢鎻愪緵浜嗘洿鍏风(j矛ng)鐖�(zh膿ng)鍔涚殑鐢�(ch菐n)鍝佽В姹烘柟妗�锛屾帹鍕�(d貌ng)浜嗘柊鑳芥簮姹借粖(ch膿)鐨勭櫦(f膩)灞�銆�

妗堜緥涓夛細璩借粖(ch膿)搴ф鐨勫畨鍏ㄦ€ф彁鍗�

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宸ヨ棟娴佺▼锛�

1. 鍘熸潗鏂欓伕鎿�锛氶伕鐢ㄩ珮鍒嗗瓙閲忕殑鑱氶叝澶氬厓閱囧拰MDI浣滅偤涓昏鍘熸枡锛屽姞鍏ラ仼閲忕殑TMR-3浣滅偤鍌寲鍔戯紝浠ュ強鍏朵粬鍔╁姂锛堝鐧�(f膩)娉″姂銆佺┅(w臎n)瀹氬姂绛夛級銆�
2. 娣峰悎鑸囩櫦(f膩)娉�锛氬皣涓婅堪鍘熸潗鏂欐寜鐓т竴瀹氭瘮渚嬫贩鍚堝潎鍕�锛屽€掑叆妯″叿涓€�(j矛n)琛岀櫦(f膩)娉�銆傜敱浜嶵MR-3鐨勯珮鏁堝偓鍖栦綔鐢�锛屾场娌殑鐧�(f膩)娉￠€熷害杓冨揩锛岃兘澶犲湪鐭檪(sh铆)闁撳収(n猫i)瀹屾垚鎴愬瀷銆�
3. 鍥哄寲鑸囪劔妯�锛氱櫦(f膩)娉″畬鎴愬悗锛屽皣妯″叿鏀惧叆鐑樼涓€�(j矛n)琛屽姞鐔卞浐鍖�锛屾韩搴︽帶鍒跺湪120-150鈩冧箣闁擄紝鏅�(sh铆)闁撶偤20-30鍒嗛悩銆傚浐鍖栧悗鐨勬场娌潗鏂欏叿鏈夋サ楂樼殑瀵嗗害鍜屽挤(qi谩ng)搴�锛岄仼鍚堢敤浜庤辰杌�(ch膿)搴ф鐨勫埗閫犮€�
4. 鍚庤檿鐞�锛氬皣鍥哄寲鍚庣殑娉℃搏鏉愭枡寰炴ā鍏蜂腑鍙栧嚭锛岄€�(j矛n)琛岃〃闈慨鏁村拰鎵撶（锛岀⒑淇濆骇妞呯殑澶栬璩�(zh矛)閲忋€傞毃鍚�锛屽皣娉℃搏鏉愭枡鑸囩⒊绾栫董鎴栧叾浠栭珮寮�(qi谩ng)搴︽潗鏂欓€�(j矛n)琛岀祫瑁�锛屽畬鎴愬骇妞呯殑绲傚埗閫犮€�

鎬ц兘娓�(c猫)瑭�锛�

• 鎶楁矕鎿婃€ц兘锛氭牴鎿�(j霉)ISO 6489妯�(bi膩o)婧�(zh菙n)閫�(j矛n)琛屾脯(c猫)瑭�锛岀祼(ji茅)鏋滈’绀哄骇妞呭湪鍙楀埌楂橀€熸挒鎿婃檪(sh铆)鑳藉鏈夋晥鍚告敹鑳介噺锛屼繚璀�(h霉)椐曢鍝＄殑瀹夊叏銆�
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• 鑰愰珮婧€ц兘锛氭牴鎿�(j霉)ISO 11987妯�(bi膩o)婧�(zh菙n)閫�(j矛n)琛屾脯(c猫)瑭︼紝绲�(ji茅)鏋滈’绀哄骇妞呭湪楂樻韩鐠�(hu谩n)澧冧笅浠嶇劧淇濇寔鑹ソ鐨勫姏瀛�(xu茅)鎬ц兘锛屼笉鏈�(hu矛)鐧�(f膩)鐢熻畩褰㈡垨鎼嶅銆�

绲�(ji茅)璜�锛歍MR-3鐨勪娇鐢ㄩ’钁楁彁鍗囦簡璩借粖(ch膿)搴ф鐨勫畨鍏ㄦ€у拰鏀拹鎬�锛岀壒鍒ユ槸鍦ㄩ珮閫熻椐涘拰婵€鐑堢鎾炵殑鎯呮硜涓嬭〃鐝�(xi脿n)鍑鸿壊銆傞€欑偤璩借粖(ch膿)鍒堕€犲晢鎻愪緵浜嗘洿鍔犲彲闈犵殑鐢�(ch菐n)鍝佷繚闅�锛屾彁鍗囦簡璩借粖(ch膿)閬�(y霉n)鍕�(d貌ng)鐨勫畨鍏ㄦ按骞�銆�

TMR-3鐨勬妧琛�(sh霉)鍙冩暩(sh霉)鑸囨€ц兘鎸囨(bi膩o)

鐐轰簡鏇村叏闈㈠湴浜嗚ВTMR-3鐨勬€ц兘鐗归粸(di菐n)锛屼互涓嬫槸瑭插偓鍖栧姂鐨勪富瑕佹妧琛�(sh霉)鍙冩暩(sh霉)鍜屾€ц兘鎸囨(bi膩o)锛屼緵鍙冭€�銆�

TMR-3鐨勫劒(y艒u)缂洪粸(di菐n)鍒嗘瀽

鐩＄TMR-3鍦ㄦ苯杌�(ch膿)搴ф鍒堕€犱腑琛ㄧ従(xi脿n)鍑鸿澶氬劒(y艒u)鍕�(sh矛)锛屼絾浠讳綍鏉愭枡閮芥湁鍏跺眬闄愭€�銆備互涓嬫槸TMR-3鐨勫劒(y艒u)缂洪粸(di菐n)鍒嗘瀽锛屽公鍔╄畝鑰呮洿鍏ㄩ潰鍦颁簡瑙ｅ叾鎳�(y墨ng)鐢ㄥ墠鏅�銆�

鍎�(y艒u)榛�(di菐n)

1. 楂樻晥鍌寲鎬ц兘锛歍MR-3鑳藉鍦ㄨ純浣庣殑鐢ㄩ噺涓嬫彁渚涢珮鏁堢殑鍌寲鏁堟灉锛岄’钁楃府鐭场娌櫦(f膩)娉℃檪(sh铆)闁�锛屾彁楂樼敓鐢�(ch菐n)鏁堢巼銆傞€欏皪(du矛)浜庡ぇ瑕�(gu墨)妯＄敓鐢�(ch菐n)姹借粖(ch膿)搴ф鐨勪紒妤�(y猫)灏ょ偤閲嶈锛岃兘澶犻檷浣庣敓鐢�(ch菐n)鎴愭湰锛屾彁鍗囧競鍫�(ch菐ng)绔�(j矛ng)鐖�(zh膿ng)鍔�銆�

2. 鑹ソ鐨勯伕鎿囨€�锛歍MR-3灏�(du矛)鐣版鞍閰搁叝鑸囧鍏冮唶鐨勫弽鎳�(y墨ng)鍏锋湁杓冮珮鐨勯伕鎿囨€э紝鑳藉鏈夋晥鎺у埗娉℃搏鐨勫瘑搴﹀拰纭害锛岀⒑淇濈祩鐢�(ch菐n)鍝佺殑璩�(zh矛)閲忕┅(w臎n)瀹氥€傞€欎娇寰楀埗閫犲晢鍙互鏍规摎(j霉)涓嶅悓鐨勬噳(y墨ng)鐢ㄥ牬(ch菐ng)鏅�锛岄潏娲昏(di脿o)鏁撮厤鏂�锛屾豢瓒冲妯ｅ寲鐨勯渶姹�銆�

3. 浣庢埃鍛�锛氱浉姣斿偝绲�(t菕ng)鐨勫彅鑳洪(l猫i)鍌寲鍔�锛孴MR-3鍏锋湁鏇翠綆鐨勬彯鐧�(f膩)鎬�锛屾笡灏戜簡鐢熺敘(ch菐n)閬�(gu貌)绋嬩腑鍜屾垚鍝佷腑鐨勭暟鍛冲晱(w猫n)椤屻€傞€欏皪(du矛)浜庢苯杌�(ch膿)搴ф鐨勫埗閫犲挨鐐洪噸瑕�锛屽洜?y脿n)妾�?ch膿)鍏�(n猫i)绌烘埃璩�(zh矛)閲忕洿鎺ュ奖闊跨敤鎴�(h霉)鐨勯涔橀珨椹�(y脿n)銆�

4. 鐠�(hu谩n)淇濇€�锛歍MR-3绗﹀悎鍤�(y谩n)鏍肩殑鐠�(hu谩n)淇濇(bi膩o)婧�(zh菙n)锛屼笉鍚噸閲戝爆鍜屽叾浠栨湁瀹崇墿璩�(zh矛)锛岄仼鐢ㄤ簬缍犺壊鍒堕€犲伐钘�銆傛澶栵紝TMR-3鑳藉鑸囧绋挵(hu谩n)淇濆瀷鐧�(f膩)娉″姂鍗�(xi茅)鍚屼綔鐢�锛岄€�(j矛n)涓€姝ラ檷浣庣敓鐢�(ch菐n)閬�(gu貌)绋嬩腑鐨刅OC鎺掓斁锛岀鍚堟棩鐩婂毚(y谩n)鏍肩殑鐠�(hu谩n)淇濇硶瑕�(gu墨)銆�

5. 鍏煎鎬�锛歍MR-3鑸囧绋仛姘ㄩ叝鍘熸枡鍏锋湁鑹ソ鐨勫吋瀹规€э紝鑳藉鑸囧叾浠栧姪鍔戯紙濡傜櫦(f膩)娉″姂銆佺┅(w臎n)瀹氬姂绛夛級鍗�(xi茅)鍚屼綔鐢�锛屽劒(y艒u)鍖栭厤鏂硅ō(sh猫)瑷�(j矛)銆傞€欎娇寰楀埗閫犲晢鍙互鏍规摎(j霉)涓嶅悓鐨勬噳(y墨ng)鐢ㄥ牬(ch菐ng)鏅�锛岄潏娲昏(di脿o)鏁撮厤鏂�锛屾豢瓒冲妯ｅ寲鐨勯渶姹�銆�

缂洪粸(di菐n)

1. 鍍�(ji脿)鏍艰純楂�锛歍MR-3浣滅偤涓€绋珮鎬ц兘鍌寲鍔�锛屽叾鐢熺敘(ch菐n)鎴愭湰鐩稿皪(du矛)杓冮珮锛屽皫(d菐o)鑷村競鍫�(ch菐ng)鍍�(ji脿)鏍艰純鐐烘槀璨�銆傚皪(du矛)浜庝竴浜涗腑灏忓瀷浼佹キ(y猫)渚�(l谩i)瑾�(shu艒)锛屽彲鑳介洠浠ユ壙鍙楄純楂樼殑閲囪臣(g貌u)鎴愭湰锛屽奖闊垮叾寤ｆ硾鎳�(y墨ng)鐢�銆�

2. 鍎�(ch菙)瀛樻浠惰姹傚毚(y谩n)鏍�锛歍MR-3闆栫劧鍏锋湁鑹ソ鐨勫劜(ch菙)瀛樼┅(w臎n)瀹氭€э紝浣嗕粛闇€閬垮厤鑸囧挤(qi谩ng)閰�銆佸挤(qi谩ng)鍫挎帴瑙�锛屽惁鍓囧彲鑳藉皫(d菐o)鑷村偓鍖栧姂澶辨晥銆傚洜姝わ紝鍦ㄥ劜(ch菙)瀛樺拰閬�(y霉n)杓搁亷(gu貌)绋嬩腑闇€瑕佺壒鍒ユ敞鎰�锛屽鍔犱簡浼佹キ(y猫)鐨勭鐞嗘垚鏈€�

3. 閬╃敤鑼冨湇鏈夐檺锛氱洝绠MR-3鍦ㄦ苯杌�(ch膿)搴ф鍒堕€犱腑琛ㄧ従(xi脿n)鍑鸿壊锛屼絾鍦ㄦ煇浜涚壒娈婃噳(y墨ng)鐢ㄥ牬(ch菐ng)鏅紙濡傛サ绔珮婧垨浣庢韩鐠�(hu谩n)澧冿級涓�锛屽叾鎬ц兘鍙兘鏈�(hu矛)鍙楀埌褰遍熆銆傚洜姝�锛屼紒妤�(y猫)鍦ㄩ伕鎿囧偓鍖栧姂鏅�(sh铆)闇€瑕佹牴鎿�(j霉)鍏烽珨鐨勬噳(y墨ng)鐢ㄥ牬(ch菐ng)鏅€�(j矛n)琛岃⿻(p铆ng)浼�锛岀⒑淇濆叾閬╃敤鎬�銆�

TMR-3鐨勬湭渚�(l谩i)鐧�(f膩)灞曡定鍕�(sh矛)

闅ㄨ憲姹借粖(ch膿)宸ユキ(y猫)鐨勪笉鏂风櫦(f膩)灞�锛岀壒鍒ユ槸闆诲嫊(d貌ng)姹借粖(ch膿)鍜屾櫤鑳芥苯杌�(ch膿)鐨勮垐璧�锛屾苯杌�(ch膿)搴ф鐨勮ō(sh猫)瑷�(j矛)鍜屽埗閫犳妧琛�(sh霉)涔熼潰鑷ㄨ憲鏂扮殑鎸戞埌(zh脿n)鍜屾(j墨)閬囥€傜偤浜嗘豢瓒冲競鍫�(ch菐ng)灏�(du矛)楂樻€ц兘銆佽紩閲忓寲銆佺挵(hu谩n)淇濆瀷搴ф鐨勯渶姹�锛孴MR-3浣滅偤涓€娆鹃珮鏁堝偓鍖栧姂锛屾湭渚�(l谩i)灏囧湪浠ヤ笅骞惧€�(g猫)鏂归潰鍙栧緱閫�(j矛n)涓€姝ョ殑鐧�(f膩)灞曪細

1. 楂樻€ц兘鍌寲鍔戠殑鐮旂櫦(f膩)

闅ㄨ憲鑱氭皑閰场娌潗鏂欑殑涓嶆柗鍗囩礆(j铆)锛屽皪(du矛)鍌寲鍔戠殑鎬ц兘瑕佹眰涔熻秺渚�(l谩i)瓒婇珮銆傛湭渚�(l谩i)锛岀爺绌朵汉鍝″皣绻肩簩(x霉)鑷村姏浜庨枊(k膩i)鐧�(f膩)鏂颁竴浠ｉ珮鎬ц兘鍌寲鍔�锛岄€�(j矛n)涓€姝ユ彁楂楾MR-3鐨勫偓鍖栨晥鐜�銆侀伕鎿囨€у拰绌�(w臎n)瀹氭€с€備緥濡�锛岄€氶亷(gu貌)寮曞叆绱嶇背鏉愭枡鎴栧姛鑳芥€ф坊鍔犲姂锛屽彲浠ユ湁鏁堝寮�(qi谩ng)TMR-3鐨勫偓鍖栨椿鎬э紝绺煭娉℃搏鐧�(f膩)娉℃檪(sh铆)闁�锛屾彁鍗囩敓鐢�(ch菐n)鏁堢巼銆�

2. 鐠�(hu谩n)淇濆瀷鍌寲鍔戠殑鎳�(y墨ng)鐢�

闅ㄨ憲鍏ㄧ悆鐠�(hu谩n)淇濇剰璀�(sh铆)鐨勪笉鏂锋彁楂�锛屾苯杌�(ch膿)琛屾キ(y猫)灏�(du矛)鐠�(hu谩n)淇濆瀷鏉愭枡鐨勯渶姹傛棩鐩婂闀�(zh菐ng)銆傛湭渚�(l谩i)锛孴MR-3鏈夋湜鑸囨洿澶氱挵(hu谩n)淇濆瀷鐧�(f膩)娉″姂锛堝姘寸櫦(f膩)娉″姂銆佺墿鐞嗙櫦(f膩)娉″姂绛夛級鍗�(xi茅)鍚屼綔鐢�锛岄€�(j矛n)涓€姝ラ檷浣庣敓鐢�(ch菐n)閬�(gu貌)绋嬩腑鐨刅OC鎺掓斁锛岀鍚堟棩鐩婂毚(y谩n)鏍肩殑鐠�(hu谩n)淇濇硶瑕�(gu墨)銆傛澶�锛岀爺绌朵汉鍝￠倓灏囨帰绱MR-3鍦ㄧ敓鐗╁熀鑱氭皑閰场娌腑鐨勬噳(y墨ng)鐢�锛屾帹鍕�(d貌ng)缍犺壊鍒堕€犳妧琛�(sh霉)鐨勭櫦(f膩)灞�銆�

3. 鏅鸿兘鍖栧埗閫犵殑铻嶅悎

闅ㄨ憲鏅鸿兘鍒堕€犳妧琛�(sh霉)鐨勬櫘鍙婏紝姹借粖(ch膿)搴ф鐨勭敓鐢�(ch菐n)閬�(gu貌)绋嬪皣鏇村姞鏅鸿兘鍖�銆佽嚜鍕�(d貌ng)鍖�銆傛湭渚�(l谩i)锛孴MR-3鏈夋湜鑸囧厛閫�(j矛n)鐨勫偝鎰熷櫒銆佹帶鍒剁郴绲�(t菕ng)绛夋妧琛�(sh霉)鐩哥祼(ji茅)鍚�锛屽(sh铆)鐝�(xi脿n)灏�(du矛)娉℃搏鐧�(f膩)娉￠亷(gu貌)绋嬬殑瀵�(sh铆)鏅�(sh铆)鐩�(ji膩n)鎺у拰绮炬簴(zh菙n)鎺у埗銆傞€欎笉鍍呰兘澶犳彁楂樼敘(ch菐n)鍝佽唱(zh矛)閲�锛岄倓鑳芥笡灏戠敓鐢�(ch菐n)閬�(gu貌)绋嬩腑鐨勮兘婧愭秷鑰楀拰寤㈡枡鐢�(ch菐n)鐢�锛屾帹鍕�(d貌ng)鍙寔绾�(x霉)鐧�(f膩)灞曘€�

4. 鏂板瀷鎳�(y墨ng)鐢ㄥ牬(ch菐ng)鏅殑鎷撳睍

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绲�(ji茅)璜�

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鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/22-dimorpholinodiethylether-3/

鎿�(ku貌)灞曢柋璁€:https://www.morpholine.org/high-quality-cas-108-01-0-nn-dimethyl-ethanolamine-2-dimethylamineethanol-dmea-dimethylethanolamine/

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/catalyst-sa603/

鎿�(ku貌)灞曢柋璁€:https://www.cyclohexylamine.net/delayed-tertiary-amine-catalyst-delayed-catalyst-bl-17/

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/fascat4224-catalyst-arkema-pmc/

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/wp-content/uploads/2020/06/26.jpg

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/wp-content/uploads/2022/08/102-2.jpg

鎿�(ku貌)灞曢柋璁€:https://www.cyclohexylamine.net/catalyst-1027-polyurethane-catalyst-1027/

鎿�(ku貌)灞曢柋璁€:https://www.newtopchem.com/archives/45108

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/nt-cat-1027-catalyst-cas100515-55-5-newtopchem/