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鏂扮櫢閰搁墠锛圔ismuth Neodecanoate锛夛紝浣滅偤涓€绋噸瑕佺殑鏈夋(j墨)閲戝爆鍖栧悎鐗╋紝鍦ㄥ鍊�(g猫)闋�(l菒ng)鍩熷睍鐝�(xi脿n)鍑哄唬娉涚殑鎳�(y墨ng)鐢ㄥ墠鏅�銆傚叾鍖栧(xu茅)寮忕偤Bi(ND)3锛屽叾涓璑D浠ｈ〃鏂扮櫢閰告牴闆㈠瓙锛坣eodecanoate锛夈€傛柊鐧搁吀閴嶅洜鍏剁崹(d煤)鐗圭殑鐗╃悊鍜屽寲瀛�(xu茅)鎬ц唱(zh矛)锛岃寤ｆ硾鎳�(y墨ng)鐢ㄤ簬娑傛枡銆佹补澧�銆佸鏂欐坊鍔犲姂銆佸偓鍖栧姂绛夐牁(l菒ng)鍩�銆傝繎骞翠締锛岄毃钁楃挵(hu谩n)淇濇剰璀�(sh铆)鐨勫寮�(qi谩ng)鍜屾妧琛�(sh霉)鐨勯€�(j矛n)姝ワ紝鏂扮櫢閰搁墠鐨勭爺绌跺拰鎳�(y墨ng)鐢ㄩ€愭几鎴愮偤瀛�(xu茅)琛�(sh霉)鐣屽拰宸ユキ(y猫)鐣岀殑鐔遍粸(di菐n)瑭遍銆�

鏈爺绌舵棬鍦ㄦ帰瑷庢柊鐧搁吀閴嶅湪涓嶅悓姘ｅ€欐浠朵笅鐨勬€ц兘琛ㄧ従(xi脿n)銆傛埃鍊欐浠跺皪鏉愭枡鐨勬€ц兘鏈夎憲椤憲褰遍熆锛屽挨鍏舵槸鍦ㄦサ绔韩搴�銆佹繒搴�銆佸厜鐓х瓑鐠�(hu谩n)澧冧笅锛屾潗鏂欑殑绌�(w臎n)瀹氭€�銆佽€愪箙鎬у拰鍔熻兘鎬у彲鑳芥渻(hu矛)鐧�(f膩)鐢熼’钁楄畩鍖�銆傚洜姝わ紝浜嗚В鏂扮櫢閰搁墠鍦ㄤ笉鍚屾埃鍊欐浠朵笅鐨勮鐐�锛屽皪浜庡叾鍦ㄥ(sh铆)闅涙噳(y墨ng)鐢ㄤ腑鐨勫劒(y艒u)鍖栧拰鏀归€�(j矛n)鍏锋湁閲嶈鎰忕京銆�

鏈枃灏囧緸浠ヤ笅骞惧€�(g猫)鏂归潰灞曢枊瑷庤珫锛氶鍏堬紝浠嬬垂鏂扮櫢閰搁墠鐨勫熀鏈悊鍖栨€ц唱(zh矛)鍜岀敘(ch菐n)鍝佸弮鏁�(sh霉)锛涘叾娆★紝鍒嗘瀽鍏跺湪涓嶅悓姘ｅ€欐浠朵笅鐨勬€ц兘琛ㄧ従(xi脿n)锛屽寘鎷韩搴︺€佹繒搴�銆佸厜鐓х瓑鍥犵礌鐨勫奖闊�锛涘啀娆�锛岀祼(ji茅)鍚堝湅鍏�(n猫i)澶栨枃鐛�(xi脿n)锛屾帰瑷庢柊鐧搁吀閴嶅湪鐗瑰畾鎳�(y墨ng)鐢ㄩ牁(l菒ng)鍩熺殑琛ㄧ従(xi脿n)锛屽娑傛枡銆佸鏂欐坊鍔犲姂绛夛紱鍚�锛岀附绲�(ji茅)鐮旂┒绲�(ji茅)鏋�锛屽苟鎻愬嚭鏈締鐨勭爺绌舵柟鍚戝拰鏀归€�(j矛n)寤鸿銆�

閫氶亷鏈爺绌�锛屾垜鍊戝笇鏈涜兘澶�?y脿n)妯鹃箍閿煎緳G鐨勯枊鐧�(f膩)鍜屾噳(y墨ng)鐢ㄦ彁渚涚悊璜栦緷鎿�(j霉)鍜屾妧琛�(sh霉)鏀寔锛屾帹鍕�(d貌ng)鍏跺湪鏇村闋�(l菒ng)鍩熺殑寤ｆ硾鎳�(y墨ng)鐢�銆�

鏂扮櫢閰搁墠鐨勫熀鏈悊鍖栨€ц唱(zh矛)鑸囩敘(ch菐n)鍝佸弮鏁�(sh霉)

鏂扮櫢閰搁墠鏄竴绋湁姗�(j墨)閲戝爆鍖栧悎鐗╋紝鍏锋湁鑹ソ鐨勭啽绌�(w臎n)瀹氭€у拰鍖栧(xu茅)鎯版€�銆傚叾鍒嗗瓙绲�(ji茅)妲�(g貌u)鐢遍墠闆㈠瓙锛圔i3?锛夊拰涓夊€�(g猫)鏂扮櫢閰告牴闆㈠瓙锛圢D?锛夌祫鎴愶紝鍖栧(xu茅)寮忕偤Bi(ND)?銆傛柊鐧搁吀閴嶇殑鏅堕珨绲�(ji茅)妲�(g貌u)灞簬鍠枩鏅剁郴锛岀┖闁撶兢鐐篜2?/c锛屾櫠鑳炲弮鏁�(sh霉)鐐篴 = 10.56 ?, b = 14.89 ?, c = 17.92 ?, 尾 = 96.7掳銆備互涓嬫槸鏂扮櫢閰搁墠鐨勪富瑕佺悊鍖栨€ц唱(zh矛)鍜岀敘(ch菐n)鍝佸弮鏁�(sh霉)锛�

1. 鐗╃悊鎬ц唱(zh矛)

2. 鍖栧(xu茅)鎬ц唱(zh矛)

鏂扮櫢閰搁墠鍏锋湁杓冮珮鐨勫寲瀛�(xu茅)绌�(w臎n)瀹氭€�锛屼笉鏄撹垏鍏朵粬甯歌鍖栧(xu茅)鐗╄唱(zh矛)鐧�(f膩)鐢熷弽鎳�(y墨ng)銆傚畠鍦ㄧ┖姘ｄ腑杓冪偤绌�(w臎n)瀹氾紝浣嗗湪楂樻韩涓嬫渻(hu矛)鐧�(f膩)鐢熷垎瑙�锛岀敓鎴愭哀鍖栭墠锛圔i?O?锛夊拰鍏朵粬鍓敘(ch菐n)鐗┿€傛柊鐧搁吀閴嶇殑閰告€ц純寮�(qi谩ng)锛岃兘澶犺垏鍫挎€х墿璩�(zh矛)鐧�(f膩)鐢熶腑鍜屽弽鎳�(y墨ng)锛岀敓鎴愮浉鎳�(y墨ng)鐨勯菇椤炪€傛澶�锛屾柊鐧搁吀閴嶉倓鍏锋湁涓€瀹氱殑鍌寲娲绘€�锛岃兘澶犲湪鏌愪簺鍖栧(xu茅)鍙嶆噳(y墨ng)涓綔鐐哄偓鍖栧姂浣跨敤銆�

3. 鐔辩┅(w臎n)瀹氭€�

鏂扮櫢閰搁墠鐨勭啽绌�(w臎n)瀹氭€ф槸鍏堕噸瑕佺壒鎬т箣涓€銆傜爺绌惰〃鏄庯紝鏂扮櫢閰搁墠鍦ㄥ父婧笅闈炲父绌�(w臎n)瀹�锛屼絾鍦ㄨ純楂樻韩搴︿笅鏈�(hu矛)閫愭几鍒嗚В銆傛牴鎿�(j霉)鏂囩嵒(xi脿n)鍫�(b脿o)閬�锛屾柊鐧搁吀閴嶇殑鍒嗚В婧害绱勭偤200掳C宸﹀彸锛屽叿楂斿垎瑙ｉ亷绋嬪涓嬶細

[ text{Bi(ND)?} rightarrow text{Bi?O?} + 3 text{C??H??COOH} ]

鍦ㄥ(sh铆)闅涙噳(y墨ng)鐢ㄤ腑锛屾柊鐧搁吀閴嶇殑鐔辩┅(w臎n)瀹氭€у皪浜庡叾鍦ㄩ珮婧挵(hu谩n)澧冧笅鐨勪娇鐢ㄨ嚦闂�(gu膩n)閲嶈銆備緥濡�锛屽湪娑傛枡鍜屽鏂欏姞宸ラ亷绋嬩腑锛屾潗鏂欏線寰€闇€瑕佹壙鍙楄純楂樼殑婧害锛屽洜姝ゆ柊鐧搁吀閴嶇殑鐔辩┅(w臎n)瀹氭€х洿鎺ュ奖闊垮叾鍦ㄩ€欎簺闋�(l菒ng)鍩熺殑鎳�(y墨ng)鐢ㄦ晥鏋�銆�

4. 鍏夌┅(w臎n)瀹氭€�

鏂扮櫢閰搁墠鐨勫厜绌�(w臎n)瀹氭€т篃鏄叾鎬ц兘鐨勯噸瑕佺祫鎴愰儴鍒嗐€傜爺绌惰〃鏄�锛屾柊鐧搁吀閴嶅湪绱鍏夌収灏勪笅鏈�(hu矛)鐧�(f膩)鐢熶竴瀹氱▼搴︾殑闄嶈В锛屽皫(d菐o)鑷村叾椤忚壊璁婃繁鎴栧け鍘婚儴鍒嗗姛鑳姐€傜偤浜嗘彁楂樻柊鐧搁吀閴嶇殑鍏夌┅(w臎n)瀹氭€�锛岄€氬父鏈�(hu矛)鍦ㄩ厤鏂逛腑娣诲姞绱绶氬惛鏀跺姂鎴栧叾浠栧厜绌�(w臎n)瀹氬姂銆傚湅澶栨枃鐛�(xi脿n)涓彁鍒�锛屾坊鍔犻仼閲忕殑鍙楅樆鑳洪鍏夌┅(w臎n)瀹氬姂锛圚ALS锛夊彲浠ユ湁鏁堝欢绶╂柊鐧搁吀閴嶇殑鍏夐檷瑙ｉ亷绋嬶紝寰炶€屽欢闀峰叾浣跨敤澹藉懡銆�

5. 闆诲(xu茅)鎬ц唱(zh矛)

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6. 鐢熺墿鐩稿鎬�

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涓嶅悓姘ｅ€欐浠跺皪鏂扮櫢閰搁墠鎬ц兘鐨勫奖闊�

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1. 婧害灏嶆柊鐧搁吀閴嶆€ц兘鐨勫奖闊�

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姝ゅ锛屾竻鑿ぇ瀛�(xu茅)鏉愭枡绉戝(xu茅)鑸囧伐绋嬬郴鐨勪竴闋�(xi脿ng)鐮旂┒琛ㄦ槑锛屾柊鐧搁吀閴嶄綔鐐轰竴绋劒(y艒u)鑹殑澧炲鍔�锛岃兘澶犲湪鑱氭隘涔欑儻锛圥VC锛変腑鏀瑰杽鍏舵煍闊屾€у拰鍔犲伐鎬ц兘銆傝┎鐮旂┒閫氶亷宸ず鎺冩弿閲忕啽娉曪紙DSC锛夊拰鐔遍噸鍒嗘瀽锛圱GA锛夋妧琛�(sh霉)锛岃┏绱�(x矛)鍒嗘瀽浜嗘柊鐧搁吀閴嶅皪PVC鐔辩┅(w臎n)瀹氭€у拰姗�(j墨)姊版€ц兘鐨勫奖闊�锛屽苟鎻愬嚭浜嗘敼閫�(j矛n)鍏舵噳(y墨ng)鐢ㄦ晥鏋滅殑寤鸿銆傜爺绌惰〃鏄�锛屾柊鐧搁吀閴嶇殑鍔犲叆鍙互椤憲鎻愰珮PVC鐨勭啽绌�(w臎n)瀹氭€у拰鏌旈煂鎬э紝浣垮叾鍦ㄩ珮婧挵(hu谩n)澧冧笅鐨勫姞宸ユ€ц兘寰楀埌椤憲鏀瑰杽銆�

鏂扮櫢閰搁墠鍦ㄧ壒瀹氭噳(y墨ng)鐢ㄩ牁(l菒ng)鍩熺殑琛ㄧ従(xi脿n)

鏂扮櫢閰搁墠鐢变簬鍏跺劒(y艒u)鐣扮殑鐗╃悊鍜屽寲瀛�(xu茅)鎬ц兘锛屽唬娉涙噳(y墨ng)鐢ㄤ簬娑傛枡銆佸鏂欐坊鍔犲姂銆佸偓鍖栧姂绛夐牁(l菒ng)鍩熴€傛湰绡€(ji茅)灏囩祼(ji茅)鍚堝湅鍏�(n猫i)澶栨枃鐛�(xi脿n)锛岃┏绱�(x矛)鎺㈣◣鏂扮櫢閰搁墠鍦ㄩ€欎簺鐗瑰畾鎳�(y墨ng)鐢ㄩ牁(l菒ng)鍩熺殑琛ㄧ従(xi脿n)锛屽苟鍒嗘瀽鍏跺湪涓嶅悓姘ｅ€欐浠朵笅鐨勯仼鎳�(y墨ng)鎬�銆�

1. 娑傛枡闋�(l菒ng)鍩�

鏂扮櫢閰搁墠鍦ㄦ秱鏂欎腑鐨勬噳(y墨ng)鐢ㄤ富瑕侀珨鐝�(xi脿n)鍦ㄥ叾浣滅偤鍌寲鍔戝拰澧炲鍔戠殑浣滅敤銆傜爺绌惰〃鏄�锛屾柊鐧搁吀閴嶈兘澶犱績閫�(j矛n)鑱氭皑閰秱鏂欎腑鐨勪氦鑱�(li谩n)鍙嶆噳(y墨ng)锛屾彁楂樻秱灞ょ殑闄勮憲鍔涘拰鑰愮（鎬�銆傚湪楂樻韩鍜岄珮婵曞害鐠�(hu谩n)澧冧笅锛屾柊鐧搁吀閴嶇殑鐔辩┅(w臎n)瀹氭€у拰鎶楀惛婵曟€ц兘浣垮叾鍦ㄦ埗澶栨秱鏂欎腑琛ㄧ従(xi脿n)鍑鸿壊銆備緥濡�锛屼腑鍦嬬瀛�(xu茅)闄㈠寲瀛�(xu茅)鐮旂┒鎵€鐨勪竴闋�(xi脿ng)鐮旂┒琛ㄦ槑锛屾柊鐧搁吀閴嶇殑鍔犲叆鍙互椤憲鎻愰珮鑱氭皑閰秱鏂欑殑浜よ伅(li谩n)瀵嗗害鍜屾(j墨)姊板挤(qi谩ng)搴�锛屼娇鍏跺湪鎯″姡鐠�(hu谩n)澧冧笅鐨勮€愪箙鎬у緱鍒伴’钁楁彁鍗�銆�

姝ゅ锛屾柊鐧搁吀閴嶉倓鍏锋湁鑹ソ鐨勫厜绌�(w臎n)瀹氭€э紝鑳藉鍦ㄧ传澶栧厜鐓у皠涓嬩繚鎸佹秱灞ょ殑鑹叉兢鍜屾€ц兘銆傜爺绌惰〃鏄�锛屾坊鍔犻仼閲忕殑鍙楅樆鑳洪鍏夌┅(w臎n)瀹氬姂锛圚ALS锛夊彲浠ラ€�(j矛n)涓€姝ユ彁楂樻柊鐧搁吀閴嶇殑鍏夌┅(w臎n)瀹氭€э紝寤堕暦娑傛枡鐨勪娇鐢ㄥ＝鍛�銆傚洜姝�锛屾柊鐧搁吀閴嶅湪鎴跺娑傛枡涓殑鎳�(y墨ng)鐢ㄥ墠鏅唬闂�锛屽挨鍏堕仼鐢ㄤ簬楂橀€熷叕璺�銆佹⿱姊�銆佸缓绛戝澧荤瓑闇€瑕侀暦鏈熸毚闇插湪闄藉厜鍜岄洦姘翠腑鐨勫牬鏅�銆�

2. 濉戞枡娣诲姞鍔戦牁(l菒ng)鍩�

鏂扮櫢閰搁墠鍦ㄥ鏂欐坊鍔犲姂涓殑鎳�(y墨ng)鐢ㄤ富瑕侀珨鐝�(xi脿n)鍦ㄥ叾浣滅偤澧炲鍔戝拰鐔辩┅(w臎n)瀹氬姂鐨勪綔鐢ㄣ€傜爺绌惰〃鏄�锛屾柊鐧搁吀閴嶈兘澶犻’钁楁彁楂樿仛姘箼鐑紙PVC锛夌殑鏌旈煂鎬у拰鍔犲伐鎬ц兘锛屽悓鏅�(sh铆)澧炲挤(qi谩ng)鍏剁啽绌�(w臎n)瀹氭€с€傚湪楂樻韩鐠�(hu谩n)澧冧笅锛屾柊鐧搁吀閴嶇殑鍔犲叆鍙互鏈夋晥闃叉PVC鐨勭啽鍒嗚В锛屽欢闀峰叾浣跨敤澹藉懡銆備緥濡�锛屾竻鑿ぇ瀛�(xu茅)鏉愭枡绉戝(xu茅)鑸囧伐绋嬬郴鐨勪竴闋�(xi脿ng)鐮旂┒琛ㄦ槑锛屾柊鐧搁吀閴嶇殑鍔犲叆鍙互椤憲鎻愰珮PVC鐨勭啽绌�(w臎n)瀹氭€у拰鏌旈煂鎬�锛屼娇鍏跺湪楂樻韩鐠�(hu谩n)澧冧笅鐨勫姞宸ユ€ц兘寰楀埌椤憲鏀瑰杽銆�

姝ゅ锛屾柊鐧搁吀閴嶉倓鍏锋湁鑹ソ鐨勬姉鍚告繒鎬ц兘锛岃兘澶犲湪楂樻繒搴︾挵(hu谩n)澧冧笅淇濇寔濉戞枡鍒跺搧鐨勫昂瀵哥┅(w臎n)瀹氭€у拰姗�(j墨)姊版€ц兘銆傜爺绌惰〃鏄庯紝鏂扮櫢閰搁墠鐨勫姞鍏ュ彲浠ユ湁鏁堥槻姝㈠鏂欏埗鍝佸湪娼繒鐠�(hu谩n)澧冧笅鐨勮畩褰㈠拰闁嬭锛屽欢闀峰叾浣跨敤澹藉懡銆傚洜姝�锛屾柊鐧搁吀閴嶅湪濉戞枡娣诲姞鍔戜腑鐨勬噳(y墨ng)鐢ㄥ墠鏅唬闂�锛屽挨鍏堕仼鐢ㄤ簬绠￠亾銆侀浕绾�銆佽杽鑶滅瓑闇€瑕侀暦鏈熸毚闇插湪娼繒鐠�(hu谩n)澧冧腑鐨勫牬鏅�銆�

3. 鍌寲鍔戦牁(l菒ng)鍩�

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姝ゅ锛屾柊鐧搁吀閴嶉倓鍏锋湁鑹ソ鐨勫厜绌�(w臎n)瀹氭€э紝鑳藉鍦ㄧ传澶栧厜鐓у皠涓嬩繚鎸佸偓鍖栧姂鐨勬椿鎬у拰鎬ц兘銆傜爺绌惰〃鏄庯紝娣诲姞閬╅噺鐨勫彈闃昏兒椤炲厜绌�(w臎n)瀹氬姂锛圚ALS锛夊彲浠ラ€�(j矛n)涓€姝ユ彁楂樻柊鐧搁吀閴嶇殑鍏夌┅(w臎n)瀹氭€�锛屽欢闀峰偓鍖栧姂鐨勪娇鐢ㄥ＝鍛�銆傚洜姝�锛屾柊鐧搁吀閴嶅湪鍌寲鍔戦牁(l菒ng)鍩熺殑鎳�(y墨ng)鐢ㄥ墠鏅唬闂�锛屽挨鍏堕仼鐢ㄤ簬鎴跺鍖栧伐鐢熺敘(ch菐n)鍜屽厜鍌寲鍙嶆噳(y墨ng)绛夐渶瑕侀暦鏈熸毚闇插湪闄藉厜鍜岄洦姘翠腑鐨勫牬鏅�銆�

绲�(ji茅)璜栬垏灞曟湜

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1. 婧害灏嶆柊鐧搁吀閴嶆€ц兘鐨勫奖闊�锛氭柊鐧搁吀閴嶅湪甯告韩鍜屼綆婧挵(hu谩n)澧冧笅鍏锋湁鑹ソ鐨勭啽绌�(w臎n)瀹氭€�锛屼絾鍦ㄩ珮婧挵(hu谩n)澧冧笅鏈�(hu矛)鐧�(f膩)鐢熷垎瑙ｅ弽鎳�(y墨ng)锛屽皫(d菐o)鑷村叾鎬ц兘涓嬮檷銆傚洜姝わ紝鍦ㄩ珮婧挵(hu谩n)澧冧笅浣跨敤鏂扮櫢閰搁墠鏅�(sh铆)锛屾噳(y墨ng)閲囧彇閬╃暥(d膩ng)?sh霉)濮嗛浄o(h霉)鎺柦锛屽闄嶄綆婧害鎴栨坊鍔犵┅(w臎n)瀹氬姂銆�

2. 婵曞害灏嶆柊鐧搁吀閴嶆€ц兘鐨勫奖闊�锛氭柊鐧搁吀閴嶅湪浣庢繒搴︾挵(hu谩n)澧冧笅鍏锋湁鑹ソ鐨勬姉鍚告繒鎬ц兘锛屼絾鍦ㄩ珮婵曞害鐠�(hu谩n)澧冧笅鍙兘鐧�(f膩)鐢熸按瑙ｅ弽鎳�(y墨ng)锛屽皫(d菐o)鑷村叾鎬ц兘涓嬮檷銆傚洜姝わ紝鍦ㄩ珮婵曞害鐠�(hu谩n)澧冧笅浣跨敤鏂扮櫢閰搁墠鏅�(sh铆)锛屾噳(y墨ng)閲囧彇閬╃暥(d膩ng)?sh霉)濮嗚幈璐濊儳?锛屽瀵嗗皝鍖呰鎴栨坊鍔犻槻娼姂銆�

3. 鍏夌収灏嶆柊鐧搁吀閴嶆€ц兘鐨勫奖闊�锛氭柊鐧搁吀閴嶅湪寮卞厜鐓х挵(hu谩n)澧冧笅鍏锋湁鑹ソ鐨勫厜绌�(w臎n)瀹氭€�锛屼絾鍦ㄥ挤(qi谩ng)鍏夌収鐠�(hu谩n)澧冧笅鍙兘鐧�(f膩)鐢熷厜闄嶈В鍙嶆噳(y墨ng)锛屽皫(d菐o)鑷村叾鎬ц兘涓嬮檷銆傚洜姝�锛屽湪寮�(qi谩ng)鍏夌収鐠�(hu谩n)澧冧笅浣跨敤鏂扮櫢閰搁墠鏅�(sh铆)锛屾噳(y墨ng)閲囧彇閬╃暥(d膩ng)?sh霉)濮嗛浄o(h霉)鎺柦锛屽娣诲姞绱绶氬惛鏀跺姂鎴栦娇鐢ㄩ伄鍏夋潗鏂�銆�

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