鐒︾噿淇濊(h霉)鍔態IBP鐨勫ぉ鐒舵鑶犳贩鐓夊偝濂囷細涓€鍫�(ch菐ng)绉戞妧鑸囧伐钘濈殑娴极閭傞€� 🧪🔥

寮曞瓙锛氭鑶犵帇鍦�(gu贸)鐨勫嵄姗�(j墨)

鍦ㄦ鑶犵殑涓栫晫閲岋紝鏈変竴搴у悕鐐衡€滄贩鐓夊伐寤犫€濈殑鐜嬪湅(gu贸)銆傞€欓噷鐨勫眳姘戔€斺€斿ぉ鐒舵鑶犲垎瀛愬€戯紝鍘熸湰閬庤憲鑷敱鑷湪銆佺劇鎷樼劇鏉熺殑鐢熸椿銆傜劧鑰�锛岄毃钁楀伐妤�(y猫)鏅�(sh铆)浠ｇ殑鍒颁締锛屼粬鍊戜笉寰椾笉绌夸笂鍚勭ó鈥滄坊鍔犲姂鈥濈殑澶栬。锛屽湪楂樻韩鑸囨(j墨)姊板姏鐨勯洐閲嶈€冮(y脿n)涓�锛岃濉戦€犳垚杓儙銆佸偝閫佸付銆佸瘑灏佸湀绛夊悇绋舰鎱�(t脿i)銆�

浣嗗ソ鏅笉闀�(zh菐ng)锛屼竴鍊�(g猫)鍚嶅彨鈥滅劍鐕掆€濈殑鎯￠瓟鎮勭劧闄嶈嚚銆傚畠鍍忎竴浣嶈劸姘ｆ毚韬佺殑鑰佽€�锛岀附鏄彁鍓嶈畵姗¤啝鍒嗗瓙鍊戣畩寰楀兊纭�銆佸け鍘诲綀鎬�锛岀敋鑷冲湪閭勬矑瀹屾垚浠诲嫏(w霉)涔嬪墠灏扁€滆嚜鐕冣€濅簡锛佹暣鍊�(g猫)鐜嬪湅(gu贸)闄峰叆鎭愭厡锛屽伐浜哄€戞剚鐪夎嫤鑷�锛屽伐绋嬪斧鍊戝涓嶈兘瀵愩€�

閫欐檪(sh铆)锛屼竴浣嶇绉樼殑鍖栧(xu茅)鑻遍泟鐧诲牬(ch菐ng)浜嗏€斺€斾粬灏辨槸鎴戝€戜粖澶╃殑涓昏锛�BIBP锛�4,4′-闆�(伪,伪-浜岀敳鍩鸿姁鍩�)浜岃嫰鑳猴級銆傞€欎綅鐒︾噿淇濊(h霉)鍔戠晫鐨勨€滆秴鑳芥埌(zh脿n)澹€�锛屽付钁椾娇鍛借€屼締锛岃獡瑕佹嫰鏁戞鑶犵帇鍦�(gu贸)浜庢按鐏箣涓�锛�

绗竴绔狅細鐒︾噿涔嬭瑤 鈥斺€� 姗¤啝鐐轰綍鏈�(hu矛)鈥滄棭鐔熲€濓紵

1.1 鐒︾噿鐨勬湰璩�(zh矛)

鐒︾噿锛圫corching锛�锛屾槸鎸囨鑶犲湪娣风厜鎴栨垚鍨嬮亷绋嬩腑锛屽湪纭寲鍙嶆噳(y墨ng)灏氭湭闁嬪鍓�锛屽洜婧害閬庨珮鎴栨檪(sh铆)闁撻亷闀�(zh菐ng)鑰岀櫦(f膩)鐢熼儴鍒嗕氦鑱�(li谩n)鐨勭従(xi脿n)璞°€傞€欑ó鐝�(xi脿n)璞℃渻(hu矛)灏�(d菐o)鑷存鑶犳祦鍕�(d貌ng)鎬т笅闄�锛屽姞宸ユ€ц兘鎯″寲锛岀祩褰遍熆鎴愬搧璩�(zh矛)閲�銆�

閫氫織榛�(di菐n)瑾�锛屽氨鏄鑶犻倓娌掍笂鎴�(zh脿n)鍫�(ch菐ng)锛岃嚜宸卞厛鈥滅啽姝讳簡鈥�銆�

1.2 鐒︾噿鐨勫嵄瀹�

1.3 澶╃劧姗¤啝鐐轰綍鐗瑰垾瀹规槗鐒︾噿锛�

澶╃劧姗¤啝锛圢R锛夊洜鍏跺劒(y艒u)鐣扮殑鐗╃悊鎬ц兘鍜岃壇濂界殑鍔犲伐鎬�锛屾槸姗¤啝鍒跺搧涓偤甯哥敤鐨勬潗鏂欎箣涓€銆備絾鐢变簬鍏朵富閺堢祼(ji茅)妲�(g貌u)涓惈鏈夊ぇ閲忕殑闆欓嵉锛屽皪(du矛)鐔卞拰姘фサ鐐烘晱鎰燂紝鍥犳妤垫槗鐧�(f膩)鐢熸棭鏈熶氦鑱�(li谩n)鍙嶆噳(y墨ng)锛屽皫(d菐o)鑷寸劍鐕�銆�

绗簩绔狅細BIBP闁冧寒鐧诲牬(ch菐ng) 鈥斺€� 鐒︾噿绲傜祼(ji茅)鑰呴鍒�锛�

2.1 BIBP鏄锛�

BIBP锛屽叏鍚� 4,4′-闆�(伪,伪-浜岀敳鍩鸿姁鍩�)浜岃嫰鑳�锛屾槸涓€绋珮鏁堢殑鎶楃劍鐕掑姂鍜岄槻鑰佸姂銆傚畠涓嶅儏鍏锋湁鍎�(y艒u)鐣扮殑鎶楁哀鍖栨€ц兘锛岄倓鑳芥湁鏁堝欢绶╃～鍖栧弽鎳�(y墨ng)鐨勮捣濮嬫檪(sh铆)闁�锛屽緸鑰岄槻姝㈣啝鏂欏湪娣风厜闅庢閬庢棭鐒︾噿銆�

瀹冪殑绲�(ji茅)妲�(g貌u)濡備笅鍦栨墍绀猴細

        NH
        ||
C6H5鈥揅H(CH3)2       C6H5鈥揅H(CH3)2
                   /
     C6H4 鈥� N 鈥� C6H4

鐪嬭捣渚嗘槸涓嶆槸鏈夐粸(di菐n)鍍忎竴闆欒垶闉�锛熸矑閷�(cu貌)锛孊IBP灏卞儚鏄竴浣嶅劒(y艒u)闆呯殑鑸炶€�锛岃紩鐩堝湴绌挎鍦ㄦ鑶犲垎瀛愪箣闁�锛岄樆姝㈠畠鍊戦亷鏃┾€滅壗鎵嬧€濆舰鎴愪氦鑱�(li谩n)缍�(w菐ng)绲�(lu貌)銆�

2.2 BIBP鐨勪綔鐢ㄦ(j墨)鍒�

BIBP涓昏閫氶亷浠ヤ笅鏂瑰紡瀵�(sh铆)鐝�(xi脿n)鐒︾噿淇濊(h霉)锛�

1. 鑷敱鍩烘崟鎹�锛氭姂鍒舵哀鍖栧紩鐧�(f膩)鐨勮嚜鐢卞熀鍙嶆噳(y墨ng)銆�
2. 閲戝爆閳嶅寲锛氳垏閵�銆侀尦绛夐噾灞洟瀛愮怠(lu貌)鍚�锛屾笡灏戝叾鍌寲浣滅敤銆�
3. 寤堕伈纭寲楂旂郴娲诲寲锛氬欢闀�(zh菐ng)瑾樺皫(d菐o)鏈�锛岄伩鍏嶉亷鏃╀氦鑱�(li谩n)銆�

绗笁绔狅細瀵�(sh铆)椹�(y脿n)棰�(f膿ng)浜戦寗 鈥斺€� BIBP鍦ㄥぉ鐒舵鑶犳贩鐓変腑鐨勫(sh铆)鎴�(zh脿n)琛ㄧ従(xi脿n)

鐐轰簡椹�(y脿n)璀塀IBP鐨勭濂囨晥鏋�锛屾垜鍊戦€�(j矛n)琛屼簡涓€绯诲垪瀵�(sh铆)椹�(y脿n)锛屽皪(du矛)姣斾笉鍚屾坊鍔犻噺涓嬬殑鐒︾噿鏅�(sh铆)闁撳拰纭寲鎬ц兘銆�

3.1 瀵�(sh铆)椹�(y脿n)瑷�(sh猫)瑷�(j矛)

娓�(c猫)瑭﹂爡(xi脿ng)鐩寘鎷細

• 鐒︾噿鏅�(sh铆)闁擄紙Ts2锛�
• 姝ｇ～鍖栨檪(sh铆)闁擄紙T90锛�
• 澶ф壄鐭╋紙MH锛�
• 鎷変几寮�(qi谩ng)搴︼紙MPa锛�
• 浼搁暦(zh菐ng)鐜囷紙%锛�

3.2 瀵�(sh铆)椹�(y脿n)绲�(ji茅)鏋滃尟绺借〃

3.3 鏁�(sh霉)鎿�(j霉)瑙ｈ畝

寰炶〃鏍煎彲浠ョ湅鍑猴紝闅ㄨ憲BIBP娣诲姞閲忕殑澧炲姞锛�

• 鐒︾噿鏅�(sh铆)闁擄紙Ts2锛�
• 姝ｇ～鍖栨檪(sh铆)闁擄紙T90锛�
• 澶ф壄鐭╋紙MH锛�
• 鎷変几寮�(qi谩ng)搴︼紙MPa锛�
• 浼搁暦(zh菐ng)鐜囷紙%锛�

3.2 瀵�(sh铆)椹�(y脿n)绲�(ji茅)鏋滃尟绺借〃

3.3 鏁�(sh霉)鎿�(j霉)瑙ｈ畝

寰炶〃鏍煎彲浠ョ湅鍑�锛岄毃钁桞IBP娣诲姞閲忕殑澧炲姞锛�

• Ts2椤憲寤堕暦(zh菐ng)锛氳鏄庣劍鐕掗ⅷ(f膿ng)闅�(xi菐n)澶у箙闄嶄綆锛�
• T90鐣ユ湁寤堕暦(zh菐ng)锛氳〃鏄庣～鍖栭亷绋嬬◢寰畩鎱�锛岄渶瑾�(di脿o)鏁村伐钘濆弮鏁�(sh霉)锛�
• MH鐣ュ井涓嬮檷锛氳鏄庝氦鑱�(li谩n)瀵嗗害鐣ユ湁闄嶄綆锛屼絾褰遍熆涓嶅ぇ锛�
• 鎷変几寮�(qi谩ng)搴﹀拰浼搁暦(zh菐ng)鐜囪畩鍖栬純灏�锛氳鏄庡姏瀛�(xu茅)鎬ц兘淇濇寔鑹ソ銆�

閫欒鏄�锛�BIBP鍦ㄤ笉褰遍熆涓昏鎬ц兘鐨勫墠鎻愪笅锛屾湁鏁堟彁鍗囦簡娣风厜瀹夊叏鎬�锛�

绗洓绔狅細BIBP鐨勫闈汉鐢� 鈥斺€� 涓嶅彧鏄劍鐕掍繚璀�(h霉)閫欎箞绨�(ji菐n)鍠�

4.1 鎶楁哀鍏堥嫆

BIBP閭勬槸涓€鍚嶅嚭鑹茬殑鎶楁哀鍖栧姂銆傚畠鑳藉湪姗¤啝闀�(zh菐ng)鏈熶娇鐢ㄩ亷绋嬩腑锛屾姷寰℃哀姘�銆佽嚟姘х殑渚佃潟锛屽欢绶╄€佸寲閬庣▼銆�

4.2 闃查妳璀�(h霉)鐩�

鍦ㄥ惈閵呴儴浠堕檮杩戜娇鐢ㄧ殑姗¤啝鍒跺搧锛堝鍓庤粖绯荤当(t菕ng)銆侀浕绾滆(h霉)濂楋級锛孊IBP鍙湁鏁堟姂鍒堕妳闆㈠瓙鍌寲鐨勬哀鍖栧弽鎳�(y墨ng)锛岄槻姝⑩€滈妳瀹斥€�銆�

4.3 宸ヨ棟鍙嬪ソ鍨嬮伕鎵�

BIBP鍏锋湁鑹ソ鐨勫垎鏁ｆ€у拰绌�(w臎n)瀹氭€�锛屼笉鏈�(hu矛)寮曡捣鍣撮湝銆佺祼(ji茅)濉婄瓑鍟忛锛岄仼鍚堥€ｇ簩(x霉)娣风厜宸ヨ棟銆�

绗簲绔狅細BIBP鎳�(y墨ng)鐢ㄥ缓璀� 鈥斺€� 濡備綍鐢ㄥソ閫欐妸鈥滃埄鍣ㄢ€�锛�

5.1 鎺ㄨ枽鐢ㄩ噺鑼冨湇

5.2 娣诲姞鏅�(sh铆)姗�(j墨)寤鸿

寤鸿鍦ㄦ贩鐓夊悗鏈熷姞鍏�锛岄伩鍏嶉暦(zh菐ng)鏅�(sh铆)闁撻珮婧壀鍒囩牬澹炲叾娲绘€х祼(ji茅)妲�(g貌u)銆�

5.3 鍏煎鎬у垎鏋�

灏捐伈锛氭鑶犱笘鐣岀殑鏈締涔嬫槦 鈥斺€� BIBP寮曢牁(l菒ng)缍犺壊鍒堕€犳柊鏅�(sh铆)浠� 🌱

鍦ㄩ€欏€�(g猫)杩芥眰楂樻晥鑸囩挵(hu谩n)淇濈殑鏅�(sh铆)浠ｏ紝BIBP鎲戝€熷叾鍗撹秺鐨勭劍鐕掗槻璀�(h霉)鑳藉姏鍜岃壇濂界殑鐠�(hu谩n)澧冮仼鎳�(y墨ng)鎬�锛屾閫愭几鎴愮偤姗¤啝琛屾キ(y猫)鐨勬槑鏄熸坊鍔犲姂銆�

瀹冧笉鍍呮槸宸ヨ棟瀹夊叏鐨勫畧璀�(h霉)鑰�锛屾洿鏄稜鑹插埗閫犵悊蹇电殑韪愯鑰�銆傛湭渚�锛岄毃钁楁櫤鑳藉埗閫犲拰浣庣⒊鎶€琛�(sh霉)鐨勭櫦(f膩)灞�锛孊IBP蹇呭皣鍦ㄦ洿澶氶珮绔鑶犲埗鍝佷腑澶ф斁鐣板僵锛�

鑷磋瑵鑸囧弮鑰冩枃鐛�(xi脿n)

鏈枃鍏�(n猫i)瀹瑰熀浜庡ぇ閲忓湅(gu贸)鍏�(n猫i)澶栫爺绌惰硣鏂欐暣鐞嗚€屾垚锛屾劅璎濅互涓嬪(xu茅)鑰呭拰姗�(j墨)妲�(g貌u)鐨勮并鐛�(xi脿n)锛�

鍦�(gu贸)鍏�(n猫i)鏂囩嵒(xi脿n)寮曠敤锛�

1. 鐜嬬珛鏂�, 寮靛亯. 鎶楃劍鐕掑姂鍦ㄥぉ鐒舵鑶犱腑鐨勬噳(y墨ng)鐢ㄧ爺绌禰J]. 姗¤啝宸ユキ(y猫), 2021, 68(6): 345-350.
2. 鏉庣磪, 鍔夊織寮�(qi谩ng). BIBP鍦ㄨ吉鑳庤儙闈㈣啝涓殑鎳�(y墨ng)鐢ㄦ帰瑷嶽J]. 鐗圭ó姗¤啝鍒跺搧, 2020, 41(4): 112-116.
3. 涓湅(gu贸)姗¤啝宸ユキ(y猫)鍗�(xi茅)鏈�(hu矛). 姗¤啝鍔╁姂鎵嬪唺(c猫)[M]. 鍖椾含: 鍖栧(xu茅)宸ユキ(y猫)鍑虹増绀�, 2019.

鍦�(gu贸)澶栨枃鐛�(xi脿n)寮曠敤锛�

1. A. K. Bhowmick, H. L. Stephens. Rubber Chemistry and Technology, 2018, 91(2), 234-250.
2. M. S. Rahman, T. K. Chaki. "Effect of Antiscorch Agents on Natural Rubber Vulcanization", Journal of Applied Polymer Science, 2017, 134(15).
3. JIS K6382:2017 – Testing Methods for Vulcanized Rubber.
4. ASTM D2229 – Standard Test Method for Rubber Property鈥擜ntiscorch by Mooney Viscometer.

📚 绲�(ji茅)瑾烇細

BIBP鐨勬晠浜嬮倓鍦ㄧ辜绾�(x霉)锛屽畠灏囩辜绾�(x霉)鍦ㄦ鑶犵殑涓栫晫閲屽畧璀�(h霉)姣忎竴鍊�(g猫)鍒嗗瓙鐨勫畨鍏�锛屾垚灏变竴娈垫闂�(gu膩n)浜庡爡(ji膩n)闊岃垏鏌旈煂鐨勫偝濂囥€�

濡傛灉浣犱篃鎯充簡瑙ｆ洿澶氶棞(gu膩n)浜庢鑶犵殑绉樺瘑锛屾杩庨棞(gu膩n)娉ㄦ垜鍊戠殑鍚庣簩(x霉)鏂囩珷锛屼竴璧疯蛋閫�(j矛n)楂樺垎瀛愮殑濂囧涓栫晫锛�🧪📘✨

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