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BDMAEE鑸囧叾浠栧偓鍖栧姂鐨勬瘮杓�

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寰炴垚鏈晥鐩婅搴︿締鐪�锛孊DMAEE鍚屾ǎ鍏峰倷绔剁埈鍎�(y艒u)鍕�銆傞洊鐒跺叾鍠綅鍍规牸鐣ラ珮浜庨儴鍒嗘櫘閫氬偓鍖栧姂锛屼絾鐢变簬鍏剁敤閲忓皯銆佹晥鐜囬珮锛岀稖鍚堜娇鐢ㄦ垚鏈弽鑰屾洿浣庛€備互A33锛堜笁涔欑儻浜岃兒锛夌偤渚�锛岄洊鐒跺叾鍒濆鍍规牸杓冧綆锛屼絾鍦ㄥ闅涚敓鐢�(ch菐n)涓線寰€闇€瑕佹洿楂樼殑娣诲姞閲忔墠鑳介仈鍒扮浉鍚岀殑鍌寲鏁堟灉锛岀祩灏�(d菐o)鑷寸附鎴愭湰涓婂崌銆傜浉姣斾箣涓�锛孊DMAEE鐨勫劒(y艒u)鍖栭厤鏂瑰彲浠ユ笡灏戠磩20%鐨勫偓鍖栧姂鐢ㄩ噺锛屽緸鑰屽鐝�(xi脿n)椤憲鐨勬垚鏈瘈(ji茅)绱勩€�

鍦ㄧ挵(hu谩n)淇濇€ц兘鏂归潰锛孊DMAEE鐨勫劒(y艒u)鍕㈡洿鍔犵獊鍑恒€傝垏鍚湁閲嶉噾灞洟瀛愮殑鏈夋閷鍌寲鍔戠浉姣�锛孊DMAEE瀹屽叏閬垮厤浜嗛噸閲戝爆姹℃煋鐨勯ⅷ(f膿ng)闅�锛岀鍚堟棩鐩婂毚鏍肩殑鐠�(hu谩n)淇濇硶瑕�(gu墨)瑕佹眰銆傛澶�锛孊DMAEE鐨勫垎瑙ｇ敘(ch菐n)鐗╂洿鐐烘竻娼�锛屼笉鏈冪敘(ch菐n)鐢熸湁姣掓湁瀹崇墿璩�(zh矛)锛岄€欏皪淇濋殰宸ヤ汉鍋ュ悍鍜岀挵(hu谩n)澧冧繚璀烽兘鍏锋湁閲嶈鎰忕京銆�

鍚庡緸鎿嶄綔渚垮埄鎬ц€冩叜锛孊DMAEE涔熻〃鐝�(xi脿n)鍑鸿澶氬劒(y艒u)榛炪€傜浉姣旂矘搴﹁純楂樼殑TPP锛堢７閰镐笁閰級锛孊DMAEE鍏锋湁鏇村ソ鐨勬祦鍕曟€�锛屼究浜庣簿纰鸿▓閲忓拰鍧囧嫽鍒嗘暎銆傝€屼笖鍏舵彯鐧�(f膩)鎬ч仼涓�锛屾棦涓嶆渻閫犳垚閬庡鐨勬悕澶�锛屼篃涓嶆渻寮曡捣瀹夊叏鍟忛锛岀偤鐢熺敘(ch菐n)宸ヨ棟鐨勭┅(w臎n)瀹氶亱琛屾彁渚涗簡鍙潬淇濋殰銆�

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BDMAEE灏嶆苯杌婂骇妞呰垝閬╂€х殑褰遍熆

BDMAEE鍦ㄦ苯杌婂骇妞呬腑鐨勬噳(y墨ng)鐢�锛屼笉鍍呭儏鏄竴鍊嬬啊鍠殑鍖栧(xu茅)鍙嶆噳(y墨ng)閬庣▼锛屾洿鍍忔槸鐐轰箻瀹㈡墦閫犱竴鍊嬭垝閬╃殑"绉诲嫊瀹㈠怀"銆傞€氶亷绮剧⒑瑾�(di脿o)鎺ц仛姘ㄩ叝杌熸场鐨勬€ц兘鍙冩暩(sh霉)锛孊DMAEE鑳藉椤憲鎻愬崌搴ф鐨勫鍊嬭垝閬╂€ф寚妯�(bi膩o)锛岃畵姣忎竴娆￠涔橀兘璁婂緱鏇村姞鎰滄剰銆�

棣栫暥(d膩ng)鍏舵矕鐨勬槸搴ф鐨勬敮鎾愭€ц兘銆傜稉(j墨ng)閬嶣DMAEE鍎�(y艒u)鍖栫殑鑱氭皑閰场娌睍鐝�(xi脿n)鍑哄崜瓒婄殑澹撶府寮峰害鍜屽洖寰�(f霉)鑳藉姏銆傚椹楁暩(sh霉)鎿�(j霉)椤ず锛岄噰鐢˙DMAEE鍒跺倷鐨勬场娌湪缍�(j墨ng)姝�10钀澹撶府寰挵(hu谩n)鍚庯紝渚濈劧鑳藉淇濇寔鍒濆楂樺害鐨�95%浠ヤ笂銆傞€欑ó鎸佷箙鐨勫綀鎬х壒鎬�锛岀⒑淇濅簡搴ф鍦ㄩ暦鏅傞枔浣跨敤閬庣▼涓绲傝兘澶犵偤涔樺鎻愪緵绌�(w臎n)瀹氱殑鏀拹鍔�锛屾湁鏁堢珐瑙ｉ椐涚柌鍕�銆傛濡備竴浣嶇稉(j墨ng)椹楄睈瀵岀殑鍙告鎵€瑷€锛�"浠ュ墠闁嬮暦閫旇粖骞惧€嬪皬鏅傚悗鑵板氨鐗瑰垾閰哥棝锛屾彌浜嗗付BDMAEE娉℃搏鐨勫骇妞呭悗锛屾劅瑕哄氨鍍忓潗鍦ㄥ閲岀殑娌欑櫦(f膩)涓€妯ｈ垝鏈�銆�"

鍏舵鏄骇妞呯殑閫忔埃鎬ц兘銆侭DMAEE鑳藉椤憲鏀瑰杽娉℃搏鐨勫瓟闅欑祼(ji茅)妲�(g貌u)锛屽舰鎴愬潎鍕荤窗瀵嗙殑姘ｅ瓟缍�(w菐ng)绲�(lu貌)銆傞€欑ó鍎�(y艒u)鍖栧悗鐨勬场娌祼(ji茅)妲�(g貌u)涓嶅儏鎻愰珮浜嗙┖姘ｆ祦閫氭€э紝閭勮兘鏈夋晥鍚告敹姹楁恫鍜屾繒姘�锛屼繚鎸佸骇妞呭共鐖借垝閬�銆傚挨鍏舵槸鍦ㄧ値鐔辩殑澶忓锛岄€欑ó閫忔埃鎬у劒(y艒u)鍕㈠挨鐐烘槑椤�銆傜浉闂�(gu膩n)娓│琛ㄦ槑锛岄厤鍌橞DMAEE娉℃搏鐨勫骇妞呰〃闈㈡韩搴﹀彲姣旀櫘閫氬骇妞呬綆3-5鈩�锛屽ぇ澶ф彁鍗囦簡涔樺潗鑸掗仼搴︺€傞洠鎬湁杌婁富瑾�(di脿o)渚冮亾锛�"浠ュ墠闁嬭粖鎬曠啽锛岀従(xi脿n)鍦ㄥ嵆浣跨┛鐭げ涔熶笉鐢ㄦ摂(d膩n)蹇冪矘鍦ㄥ骇妞呬笂浜�銆�"

绗笁鏄骇妞呯殑瑙告劅楂旈銆侭DMAEE璩︿簣娉℃搏鎭板埌濂借檿鐨勮粺纭害锛屾棦涓嶆渻璁撲汉瑕哄緱閬庝簬鍍电‖锛屼篃涓嶆渻鍑虹従(xi脿n)濉岄櫡鐒″姏鐨勬劅瑕�銆傞€欑ó瀹岀編鐨勫钩琛′締婧愪簬BDMAEE灏嶆场娌瘑搴﹀拰鍥炲綀鎬х殑绮炬簴(zh菙n)瑾�(di脿o)鎺�銆傛暩(sh霉)鎿�(j霉)椤ず锛岀悊鎯崇媭鎱�(t脿i)涓嬬殑娉℃搏瀵嗗害鎳�(y墨ng)缍寔鍦�35-45kg/m3涔嬮枔锛屾鏅傚骇妞呮棦鍏峰倷瓒冲鐨勬敮鎾愬姏锛屽張鑳芥彁渚涙煍杌熻垝閬╃殑瑙告劅銆傛濡傛煇姹借粖鍝佺墝鐨勯甯ō(sh猫)瑷堝斧鎵€瑾細"濂界殑搴ф鎳�(y墨ng)瑭插儚鎿佹姳涓€妯ｆ韩鏌�锛屽張鍍忚偐鑶€涓€妯ｅ彲闈�锛孊DMAEE骞姪鎴戝€戝鐝�(xi脿n)浜嗛€欑ó寰鐨勫钩琛°€�"

鍚庝笉寰椾笉鎻愮殑鏄骇妞呯殑鑰愮敤鎬�銆侭DMAEE涓嶅儏鑳芥彁鍗囨场娌殑姗熸鎬ц兘锛岄倓鑳藉寮峰叾鎶楄€佸寲鑳藉姏銆傞€氶亷寮曞叆BDMAEE锛屾场娌殑鑰愮啽鎬у拰鎶楃传澶栫窔鎬ц兘寰楀埌椤憲鎻愰珮锛屼娇鐢ㄥ＝鍛藉欢闀�30%浠ヤ笂銆傞€欐剰鍛宠憲鍗充娇缍�(j墨ng)閬庡骞翠娇鐢紝搴ф渚濈劧鑳藉淇濇寔鍒濈殑鑸掗仼搴﹀拰缇庤搴�銆備竴浣嶉暦鏈熶娇鐢˙DMAEE搴ф鐨勭敤鎴舵劅鎱ㄩ亾锛�"闁嬩簡浜斿勾鐨勮粖锛屽骇妞呯湅璧蜂締閭勬槸璺熸柊鐨勪竴妯ｏ紝鍧愯憲涔熶竴榛炰笉瑕哄緱绱�銆�"

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3. 鎳�(y墨ng)鐢ㄦ€ц兘鍙冩暩(sh霉)

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鍦ㄦ苯杌婂伐妤�(y猫)閭佸悜鏅鸿兘鍖�銆侀浕鍕曞寲鍜屽彲鎸佺簩(x霉)鐧�(f膩)灞曠殑閫茬▼涓紝BDMAEE灏囩辜绾�(x霉)鎵紨钁椾笉鍙垨缂虹殑瑙掕壊銆傚畠涓嶅儏濉戦€犱簡浠婂ぉ鐨勮垝閬╅涔橀珨椹楋紝鏇村皣寮曢牁(l菒ng)鏈締姹借粖搴ф鎶€琛�(sh霉)鐨勯潻鏂版柟鍚�銆傛濡備竴浣嶈硣娣卞伐绋嬪斧鎵€瑷€锛�"BDMAEE鐨勫児鍊间笉鍍呭湪浜庡畠瑙ｆ焙浜嗕粈涔堝晱椤岋紝鏇村湪浜庡畠闁嬪暉浜嗘€庢ǎ鐨勫彲鑳芥€�銆�"

璁撴垜鍊戞湡寰咃紝鍦˙DMAEE鐨勫姪鍔涗笅锛屾湭渚嗙殑姹借粖搴ф灏囨洿鍔犳櫤鑳姐€佹洿鍔犵挵(hu谩n)淇�銆佹洿鍔犺布鍚堜汉楂旈渶姹傦紝鐐烘瘡涓€浣嶄箻瀹㈠付渚嗚秴瓒婃湡寰呯殑鑸掗仼楂旈?锛涜洘S鏈変竴澶╋紝鐣�(d膩ng)鎴戝€戣珖?w霉)鎾堫帀鍥庮媰铻榬锛屼笉鍐嶅儏鍍呴棞(gu膩n)娉ㄥ畠鐨勬潗璩�(zh矛)鍜岄€犲瀷锛岃€屾槸鏇村鍦版劅鍙楀埌瀹冩墍鎵胯級鐨勪汉鏂囬棞(gu膩n)鎳峰拰鎶€琛�(sh霉)榄呭姏銆�

鍙冭€冩枃鐛�

[1] 寮靛亯鏄�, 鏉庢泬鏉�. 鑱氭皑閰粺娉″偓鍖栧姂鐨勭爺绌堕€插睍[J]. 楂樺垎瀛愭潗鏂欑瀛�(xu茅)鑸囧伐绋�, 2018, 34(5): 12-18.

[2] Smith J R, Chen Y L. Advances in polyurethane foam catalyst technology[M]. Springer Science & Business Media, 2015.

[3] 鐜嬪織寮�, 鍔夊缓鍦�. 姹借粖搴ф鐢ㄨ仛姘ㄩ叝娉℃搏鏉愭枡鐨勭櫦(f膩)灞曡定鍕J]. 姹借粖宸ョ▼, 2019, 41(2): 213-218.

[4] Anderson M P, Taylor D C. Polyurethane foam for automotive seating: current status and future directions[J]. Journal of Applied Polymer Science, 2017, 134(15): 45678.

[5] 榛冮簵鑿�, 瓒欏缓鍦�. 鏂板瀷鑱氭皑閰偓鍖栧姂鐨勫悎鎴愯垏鎳�(y墨ng)鐢╗J]. 鍔熻兘鏉愭枡, 2020, 51(3): 301-306.

鎿村睍闁辫畝:https://www.morpholine.org/efficient-reaction-type-equilibrium-catalyst-reactive-equilibrium-catalyst/

鎿村睍闁辫畝:https://www.bdmaee.net/high-quality-nn-dicyclohexylmethylamine-cas-7560-83-0/

鎿村睍闁辫畝:https://www.bdmaee.net/wp-content/uploads/2022/08/70.jpg

鎿村睍闁辫畝:https://www.cyclohexylamine.net/pentamethyldiethylenetriamine-pc-5-hard-foam-catalyst/

鎿村睍闁辫畝:https://www.newtopchem.com/archives/44655

鎿村睍闁辫畝:https://www.morpholine.org/67874-71-9/

鎿村睍闁辫畝:https://www.newtopchem.com/archives/535

鎿村睍闁辫畝:https://www.newtopchem.com/archives/39974

鎿村睍闁辫畝:https://www.morpholine.org/category/morpholine/page/6/

鎿村睍闁辫畝:https://www.newtopchem.com/archives/44551