涓夌敳鍩鸿兒涔欏熀鍝屽棯锛氳В姹哄偝绲�(t菕ng)鍌寲鍔戝付渚�(l谩i)鐨勫仴搴烽毐鎮�

寮曡█

鍦ㄧ従(xi脿n)浠ｅ寲瀛�(xu茅)宸ユキ(y猫)涓�锛屽偓鍖栧姂鎵紨钁楄嚦闂�(gu膩n)閲嶈鐨勮鑹�銆傚畠鍊戜笉鍍呰兘澶犲姞閫熷寲瀛�(xu茅)鍙嶆噳(y墨ng)鐨勯€熷害锛岄倓鑳芥彁楂樺弽鎳�(y墨ng)鐨勬晥鐜囧拰閬告搰鎬�銆傜劧鑰岋紝鍌崇当(t菕ng)鍌寲鍔戝湪甯朵締(l谩i)楂樻晥鍙嶆噳(y墨ng)鐨勫悓鏅�(sh铆)锛屼篃浼撮毃钁椾竴绯诲垪鍋ュ悍闅辨偅鍜岀挵(hu谩n)澧冨晱(w猫n)椤屻€備笁鐢插熀鑳轰箼鍩哄搶鍡紙TMAEP锛変綔鐐轰竴绋柊鍨嬪偓鍖栧姂锛屽洜鍏剁崹(d煤)鐗圭殑鍖栧(xu茅)鎬ц唱(zh矛)鍜屽畨鍏ㄦ€�锛岄€愭几鎴愮偤鏇夸唬鍌崇当(t菕ng)鍌寲鍔戠殑鐞嗘兂閬告搰銆傛湰鏂囧皣瑭崇窗(x矛)浠嬬垂涓夌敳鍩鸿兒涔欏熀鍝屽棯鐨勭壒鎬�銆佹噳(y墨ng)鐢ㄥ強鍏跺湪瑙ｆ焙鍌崇当(t菕ng)鍌寲鍔戝仴搴烽毐鎮ｆ柟闈㈢殑鍎�(y艒u)鍕�(sh矛)銆�

涓€銆佸偝绲�(t菕ng)鍌寲鍔戠殑鍋ュ悍闅辨偅

1.1 鍌崇当(t菕ng)鍌寲鍔戠殑绋(l猫i)

鍌崇当(t菕ng)鍌寲鍔戜富瑕佸寘鎷互涓嬪咕椤�(l猫i)锛�

• 閲戝爆鍌寲鍔�锛氬閴�銆侀垁銆侀幊绛�锛屽唬娉涙噳(y墨ng)鐢ㄤ簬鍔犳矮銆佽劔姘瓑鍙嶆噳(y墨ng)銆�
• 閰稿偓鍖栧姂锛氬纭吀銆侀菇閰�銆佺７閰哥瓑锛屽父鐢ㄤ簬閰寲銆佹按瑙ｇ瓑鍙嶆噳(y墨ng)銆�
• 鍫垮偓鍖栧姂锛氬姘哀鍖栭垑銆佹矮姘у寲閴€绛�锛岀敤浜庝腑鍜屻€佺殏鍖栫瓑鍙嶆噳(y墨ng)銆�

1.2 鍋ュ悍闅辨偅

鍌崇当(t菕ng)鍌寲鍔戝湪浣跨敤閬�(gu貌)绋嬩腑锛屽彲鑳芥渻(hu矛)甯朵締(l谩i)浠ヤ笅鍋ュ悍闅辨偅锛�

• 姣掓€�锛氳ū澶氶噾灞偓鍖栧姂鍜岄吀鍫挎€у偓鍖栧姂鍏锋湁杓冮珮鐨勬瘨鎬э紝闀�(zh菐ng)鏈熸帴瑙稿彲鑳藉皫(d菐o)鑷翠腑姣�銆�
• 鑵愯潟鎬�锛氬挤(qi谩ng)閰稿挤(qi谩ng)鍫垮偓鍖栧姂灏�(du矛)鐨啔鍜岄粡鑶滄湁寮�(qi谩ng)鐑堢殑鑵愯潟浣滅敤锛屽鏄撻€犳垚鍖栧(xu茅)鐕掑偡銆�
• 鐠�(hu谩n)澧冩薄鏌�锛氬偝绲�(t菕ng)鍌寲鍔戝湪浣跨敤鍚庨洠浠ラ檷瑙�锛屽鏄撻€犳垚鐠�(hu谩n)澧冩薄鏌�銆�
• 鏄撶噧鏄撶垎锛氭煇浜涘偓鍖栧姂鍦ㄧ壒瀹氭浠朵笅鏄撶噧鏄撶垎锛屽瓨鍦ㄥ畨鍏ㄩ毐鎮ｃ€�

浜�銆佷笁鐢插熀鑳轰箼鍩哄搶鍡殑鐗规€�

2.1 鍖栧(xu茅)绲�(ji茅)妲�(g貌u)

涓夌敳鍩鸿兒涔欏熀鍝屽棯锛圱MAEP锛夌殑鍖栧(xu茅)绲�(ji茅)妲�(g貌u)濡備笅锛�

2.2 鐗╃悊鎬ц唱(zh矛)

2.3 鍖栧(xu茅)鎬ц唱(zh矛)

• 绌�(w臎n)瀹氭€�锛歍MAEP鍦ㄥ父婧笅绌�(w臎n)瀹氾紝涓嶆槗鍒嗚В銆�
• 鍙嶆噳(y墨ng)鎬�锛歍MAEP鍏锋湁杓冮珮鐨勫弽鎳�(y墨ng)娲绘€э紝鑳藉鏈夋晥鍌寲澶氱ó鏈夋(j墨)鍙嶆噳(y墨ng)銆�
• 瀹夊叏鎬�锛歍MAEP姣掓€т綆锛屽皪(du矛)鐨啔鍜岄粡鑶滅劇(w煤)鍒烘縺鎬э紝浣跨敤瀹夊叏銆�

涓�銆佷笁鐢插熀鑳轰箼鍩哄搶鍡殑鎳�(y墨ng)鐢�

3.1 鏈夋(j墨)鍚堟垚

TMAEP鍦ㄦ湁姗�(j墨)鍚堟垚涓叿鏈夊唬娉涚殑鎳�(y墨ng)鐢�锛岀壒鍒ユ槸鍦ㄤ互涓嬪弽鎳�(y墨ng)涓〃鐝�(xi脿n)鍑鸿壊锛�

• 閰寲鍙嶆噳(y墨ng)锛歍MAEP鑳藉楂樻晥鍌寲閰寲鍙嶆噳(y墨ng)锛岀敓鎴愰珮绱斿害鐨勯叝椤�(l猫i)鍖栧悎鐗�銆�
• 閰拌兒鍖栧弽鎳�(y墨ng)锛歍MAEP鍦ㄩ叞鑳哄寲鍙嶆噳(y墨ng)涓〃鐝�(xi脿n)鍑洪珮閬告搰鎬у拰楂樻敹鐜�銆�
• 鐠�(hu谩n)鍖栧弽鎳�(y墨ng)锛歍MAEP鑳藉淇冮€�(j矛n)鐠�(hu谩n)鍖栧弽鎳�(y墨ng)锛岀敓鎴愮┅(w臎n)瀹氱殑鐠�(hu谩n)鐙€鍖栧悎鐗�銆�

3.2 閱�(y墨)钘ヤ腑闁撻珨

TMAEP鍦ㄩ啱(y墨)钘ヤ腑闁撻珨鐨勫悎鎴愪腑鍏锋湁閲嶈鎳�(y墨ng)鐢�锛岀壒鍒ユ槸鍦ㄤ互涓嬮牁(l菒ng)鍩燂細

• 鎶楃敓绱犲悎鎴�锛歍MAEP鑳藉鍌寲鎶楃敓绱犱腑闁撻珨鐨勫悎鎴�锛屾彁楂樺弽鎳�(y墨ng)鏁堢巼鍜岀敘(ch菐n)鐗╃磾搴︺€�
• 鎶楃梾姣掕棩鐗�锛歍MAEP鍦ㄦ姉鐥呮瘨钘ョ墿鐨勫悎鎴愪腑琛ㄧ従(xi脿n)鍑洪珮鏁堝偓鍖栦綔鐢�銆�
• 鎶楃檶钘ョ墿锛歍MAEP鑳藉淇冮€�(j矛n)鎶楃檶钘ョ墿涓枔楂旂殑鍚堟垚锛屾彁楂樿棩鐗╃殑鐢熺墿娲绘€�銆�

3.3 楂樺垎瀛愭潗鏂�

TMAEP鍦ㄩ珮鍒嗗瓙鏉愭枡鐨勫悎鎴愪腑涔熸湁寤ｆ硾鎳�(y墨ng)鐢�锛岀壒鍒ユ槸鍦ㄤ互涓嬮牁(l菒ng)鍩燂細

• 鑱氭皑閰悎鎴�锛歍MAEP鑳藉鍌寲鑱氭皑閰殑鍚堟垚锛屾彁楂樻潗鏂欑殑鍔涘(xu茅)鎬ц兘鍜岃€愮啽鎬�銆�
• 鐠�(hu谩n)姘фü(sh霉)鑴�锛歍MAEP鍦ㄧ挵(hu谩n)姘фü(sh霉)鑴傜殑鍥哄寲閬�(gu貌)绋嬩腑琛ㄧ従(xi脿n)鍑洪珮鏁堝偓鍖栦綔鐢紝鎻愰珮鏉愭枡鐨勭矘鎺ュ挤(qi谩ng)搴﹀拰鑰愬寲瀛�(xu茅)鎬�銆�
• 鑱氶叞鑳�锛歍MAEP鑳藉淇冮€�(j矛n)鑱氶叞鑳虹殑鍚堟垚锛屾彁楂樻潗鏂欑殑鑰愮（鎬у拰鑰愮啽鎬�銆�

鍥�銆佷笁鐢插熀鑳轰箼鍩哄搶鍡殑鍎�(y艒u)鍕�(sh矛)

4.1 瀹夊叏鎬�

TMAEP鍏锋湁浣庢瘨鎬у拰浣庡埡婵€鎬э紝浣跨敤閬�(gu貌)绋嬩腑涓嶆渻(hu矛)灏�(du矛)鎿嶄綔浜哄摗閫犳垚鍋ュ悍鍗卞銆傝垏鍌崇当(t菕ng)鍌寲鍔戠浉姣旓紝TMAEP鍦ㄥ畨鍏ㄦ€ф柟闈㈠叿鏈夋槑椤劒(y艒u)鍕�(sh矛)銆�

4.2 鐠�(hu谩n)淇濇€�

TMAEP鍦ㄤ娇鐢ㄥ悗鏄撲簬闄嶈В锛屼笉鏈�(hu矛)灏�(du矛)鐠�(hu谩n)澧冮€犳垚姹℃煋銆傝垏鍌崇当(t菕ng)鍌寲鍔戠浉姣旓紝TMAEP鍦ㄧ挵(hu谩n)淇濇€ф柟闈㈠叿鏈夐’钁楀劒(y艒u)鍕�(sh矛)銆�

4.3 楂樻晥鎬�

TMAEP鍏锋湁楂樺弽鎳�(y墨ng)娲绘€у拰楂橀伕鎿囨€�锛岃兘澶犳湁鏁堟彁楂樺弽鎳�(y墨ng)鏁堢巼鍜岀敘(ch菐n)鐗╃磾搴�銆傝垏鍌崇当(t菕ng)鍌寲鍔戠浉姣�锛孴MAEP鍦ㄩ珮鏁堟€ф柟闈㈠叿鏈夋槑椤劒(y艒u)鍕�(sh矛)銆�

4.4 缍�(j墨ng)婵�(j矛)鎬�

TMAEP鐨勭敓鐢�(ch菐n)鎴愭湰杓冧綆锛屼笖鍦ㄤ娇鐢ㄩ亷(gu貌)绋嬩腑娑堣€楅噺灏�锛岃兘澶犳湁鏁堥檷浣庣敓鐢�(ch菐n)鎴愭湰銆傝垏鍌崇当(t菕ng)鍌寲鍔戠浉姣旓紝TMAEP鍦ㄧ稉(j墨ng)婵�(j矛)鎬ф柟闈㈠叿鏈夐’钁楀劒(y艒u)鍕�(sh矛)銆�

浜斻€佷笁鐢插熀鑳轰箼鍩哄搶鍡殑浣跨敤鏂规硶

5.1 浣跨敤姊濅欢

5.2 浣跨敤姝ラ

1. 婧�(zh菙n)鍌欏弽鎳�(y墨ng)鐗�锛氬皣鍙嶆噳(y墨ng)鐗╂寜姣斾緥娣峰悎鍧囧嫽銆�
2. 鍔犲叆鍌寲鍔�锛氭寜姣斾緥鍔犲叆TMAEP鍌寲鍔�銆�
3. 鍔犵啽鍙嶆噳(y墨ng)锛氬皣鍙嶆噳(y墨ng)娣峰悎鐗╁姞鐔辫嚦鎸囧畾婧害锛屼繚鎸佷竴瀹氭檪(sh铆)闁�銆�
4. 鍐峰嵒鍒嗛洟锛氬弽鎳�(y墨ng)绲�(ji茅)鏉熷悗锛屽喎鍗诲弽鎳�(y墨ng)娣峰悎鐗�锛屽垎闆㈢敘(ch菐n)鐗�銆�
5. 绱斿寲鐢�(ch菐n)鐗�锛氬皪(du矛)鐢�(ch菐n)鐗╅€�(j矛n)琛岀磾鍖栬檿鐞�锛屽緱鍒伴珮绱斿害鐢�(ch菐n)鍝併€�

鍏�銆佷笁鐢插熀鑳轰箼鍩哄搶鍡殑甯傚牬(ch菐ng)鍓嶆櫙

6.1 甯傚牬(ch菐ng)闇€姹�

闅ㄨ憲鐠�(hu谩n)淇濇剰璀�(sh铆)鐨勫寮�(qi谩ng)鍜屽仴搴峰畨鍏ㄨ姹傜殑鎻愰珮锛屽競鍫�(ch菐ng)灏�(du矛)瀹夊叏銆佺挵(hu谩n)淇�銆侀珮鏁堢殑鍌寲鍔戦渶姹傛棩鐩婂鍔�銆俆MAEP浣滅偤涓€绋柊鍨嬪偓鍖栧姂锛屽叿鏈夊唬闂婄殑甯傚牬(ch菐ng)鍓嶆櫙銆�

6.2 鎳�(y墨ng)鐢ㄩ牁(l菒ng)鍩�

TMAEP鍦ㄦ湁姗�(j墨)鍚堟垚銆侀啱(y墨)钘ヤ腑闁撻珨銆侀珮鍒嗗瓙鏉愭枡绛夐牁(l菒ng)鍩熷叿鏈夊唬娉涚殑鎳�(y墨ng)鐢ㄥ墠鏅�銆傞毃钁楁妧琛�(sh霉)鐨勯€�(j矛n)姝ュ拰鎳�(y墨ng)鐢ㄧ殑鎷撳睍锛孴MAEP鐨勫競鍫�(ch菐ng)闇€姹傚皣閫�(j矛n)涓€姝ュ鍔�銆�

6.3 鐧�(f膩)灞曡定鍕�(sh矛)

鏈締(l谩i)锛孴MAEP灏囧湪浠ヤ笅骞惧€�(g猫)鏂归潰寰楀埌閫�(j矛n)涓€姝ョ櫦(f膩)灞曪細

• 鏂板瀷鍌寲鍔戠殑闁�(k膩i)鐧�(f膩)锛氶€氶亷(gu貌)鍒嗗瓙瑷�(sh猫)瑷�(j矛)鍜岀祼(ji茅)妲�(g貌u)鍎�(y艒u)鍖�锛岄枊(k膩i)鐧�(f膩)鍑烘€ц兘鏇村劒(y艒u)鐣扮殑TMAEP琛嶇敓鐗�銆�
• 鎳�(y墨ng)鐢ㄩ牁(l菒ng)鍩熺殑鎷撳睍锛氬皣TMAEP鎳�(y墨ng)鐢ㄤ簬鏇村闋�(l菒ng)鍩燂紝濡傛柊鑳芥簮銆佺挵(hu谩n)淇濇潗鏂欑瓑銆�
• 鐢熺敘(ch菐n)宸ヨ棟鐨勫劒(y艒u)鍖�锛氶€氶亷(gu貌)宸ヨ棟鏀归€�(j矛n)鍜屾妧琛�(sh霉)鍓�(chu脿ng)鏂�锛岄檷浣嶵MAEP鐨勭敓鐢�(ch菐n)鎴愭湰锛屾彁楂樼敓鐢�(ch菐n)鏁堢巼銆�

涓�銆佺祼(ji茅)璜�

涓夌敳鍩鸿兒涔欏熀鍝屽棯锛圱MAEP锛変綔鐐轰竴绋柊鍨嬪偓鍖栧姂锛屽叿鏈変綆姣掓€с€侀珮瀹夊叏鎬�銆佺挵(hu谩n)淇濇€у拰楂樻晥鎬х瓑鍎�(y艒u)鍕�(sh矛)锛岃兘澶犳湁鏁堣В姹哄偝绲�(t菕ng)鍌寲鍔戝付渚�(l谩i)鐨勫仴搴烽毐鎮�銆傞毃钁楀競鍫�(ch菐ng)闇€姹傜殑澧炲姞鍜屾噳(y墨ng)鐢ㄩ牁(l菒ng)鍩熺殑鎷撳睍锛孴MAEP灏囧湪鏈締(l谩i)寰楀埌鏇村唬娉涚殑鎳�(y墨ng)鐢ㄥ拰鐧�(f膩)灞�銆傞€氶亷(gu貌)涓嶆柗鐨勬妧琛�(sh霉)鍓�(chu脿ng)鏂板拰宸ヨ棟鍎�(y艒u)鍖�锛孴MAEP鏈夋湜鎴愮偤鏇夸唬鍌崇当(t菕ng)鍌寲鍔戠殑鐞嗘兂閬告搰锛岀偤鍖栧(xu茅)宸ユキ(y猫)鐨勫彲鎸佺簩(x霉)鐧�(f膩)灞曞仛鍑洪噸瑕佽并鐛�(xi脿n)銆�

闄勯寗锛氫笁鐢插熀鑳轰箼鍩哄搶鍡殑鐢�(ch菐n)鍝佸弮鏁�(sh霉)

閫氶亷(gu貌)浠ヤ笂瑭崇窗(x矛)鐨勪粙绱瑰拰鍒嗘瀽锛屾垜鍊戝彲浠ョ湅鍒颁笁鐢插熀鑳轰箼鍩哄搶鍡湪瑙ｆ焙鍌崇当(t菕ng)鍌寲鍔戝仴搴烽毐鎮ｆ柟闈㈢殑宸ㄥぇ娼涘姏銆傚笇鏈涙湰鏂囪兘澶�?y脿n)妯絰鑰呮彁渚涙湁鍍�(ji脿)鍊肩殑淇℃伅锛屽苟淇冮€�(j矛n)TMAEP鍦ㄦ洿澶氶牁(l菒ng)鍩熺殑鎳�(y墨ng)鐢ㄥ拰鐧�(f膩)灞曘€�

鎿�(ku貌)灞曢柋璁€:https://www.newtopchem.com/archives/44944

鎿�(ku貌)灞曢柋璁€:https://www.newtopchem.com/archives/45234

鎿�(ku貌)灞曢柋璁€:https://www.morpholine.org/category/morpholine/page/5397/

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/n-methylimidazole-2/

鎿�(ku貌)灞曢柋璁€:https://www.cyclohexylamine.net/organic-bismuth-catalyst-dabco-mb20-dabco-mb20/

鎿�(ku貌)灞曢柋璁€:https://www.cyclohexylamine.net/cas-110-95-2-tetramethyl-13-diaminopropane/

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/wp-content/uploads/2021/05/137-2.jpg

鎿�(ku貌)灞曢柋璁€:https://www.morpholine.org/reaction-delay-catalyst-polycat-sa-102-delay-catalyst-polycat-sa-102/

鎿�(ku貌)灞曢柋璁€:https://www.newtopchem.com/archives/category/products/rigid-foams-catalyst

鎿�(ku貌)灞曢柋璁€:https://www.newtopchem.com/archives/44365