涓夎仛鍌寲鍔慣AP鍦ㄩ珮鎬ц兘鑱氭皑閰綀鎬ч珨涓殑鎳夌敤

1. 寮曡█

鑱氭皑閰綀鎬ч珨锛圥olyurethane Elastomer, PUE锛夋槸涓€绋叿鏈夊劒(y艒u)鐣版姊版€ц兘銆佽€愮（鎬�銆佽€愭补鎬у拰鑰愬寲瀛歌厫铦曟€х殑楂樺垎瀛愭潗鏂�锛屽唬娉涙噳鐢ㄤ簬姹借粖銆佸缓绛戙€侀浕瀛�銆侀啱(y墨)鐧傜瓑闋樺煙銆傞毃钁楀伐妤�(y猫)鎶€琛�(sh霉)鐨勪笉鏂烽€叉锛屽皪鑱氭皑閰綀鎬ч珨鐨勬€ц兘瑕佹眰涔熻秺渚嗚秺楂橈紝灏ゅ叾鏄湪楂樺挤搴�銆侀珮褰堟€с€佽€愮啽鎬х瓑鏂归潰銆傜偤浜嗘豢瓒抽€欎簺闇€姹傦紝涓夎仛鍌寲鍔慣AP锛圱riazine-based Amine Polyol锛変綔鐐轰竴绋柊鍨嬪偓鍖栧姂锛岄€愭几鍦ㄩ珮鎬ц兘鑱氭皑閰綀鎬ч珨鐨勫埗鍌欎腑寰楀埌浜嗗唬娉涙噳鐢�銆�

鏈枃灏囪┏绱颁粙绱逛笁鑱氬偓鍖栧姂TAP鍦ㄩ珮鎬ц兘鑱氭皑閰綀鎬ч珨涓殑鎳夌敤锛屽寘鎷叾鍖栧绲�(ji茅)妲�(g貌u)銆佷綔鐢ㄦ鐞�銆佺敘(ch菐n)鍝佸弮鏁�(sh霉)銆佹噳鐢ㄦ渚嬬瓑锛屽苟閫氶亷琛ㄦ牸褰㈠紡灞曠ず鐩搁棞(gu膩n)鏁�(sh霉)鎿�(j霉)锛屼互渚胯畝鑰呮洿濂藉湴鐞嗚В鍜屾帉鎻￠€欎竴鎶€琛�(sh霉)銆�

2. 涓夎仛鍌寲鍔慣AP鐨勫寲瀛哥祼(ji茅)妲�(g貌u)鑸囦綔鐢ㄦ鐞�

2.1 鍖栧绲�(ji茅)妲�(g貌u)

涓夎仛鍌寲鍔慣AP鏄竴绋熀浜庝笁鍡挵(hu谩n)绲�(ji茅)妲�(g貌u)鐨勮兒椤炲偓鍖栧姂锛屽叾鍖栧绲�(ji茅)妲�(g貌u)濡備笅锛�

       NH2
        |
  NH2-C=N-C-NH2
        |
       NH2

涓夎仛鍌寲鍔慣AP鐨勫垎瀛愮祼(ji茅)妲�(g貌u)涓寘鍚笁鍊嬫皑鍩猴紙-NH2锛夊拰涓€鍊嬩笁鍡挵(hu谩n)锛圕3N3锛�锛岄€欑ó绲�(ji茅)妲�(g貌u)璩︿簣浜員AP鍎�(y艒u)鐣扮殑鍌寲娲绘€у拰绌�(w臎n)瀹氭€�銆�

2.2 浣滅敤姗熺悊

涓夎仛鍌寲鍔慣AP鍦ㄨ仛姘ㄩ叝褰堟€ч珨鐨勫悎鎴愰亷绋嬩腑涓昏璧峰埌浠ヤ笅浣滅敤锛�

1. 淇冮€茬暟姘伴吀閰垏澶氬厓閱囩殑鍙嶆噳锛歍AP鑳藉鏈夋晥鍌寲鐣版鞍閰搁叝锛�-NCO锛夎垏澶氬厓閱囷紙-OH锛変箣闁撶殑鍙嶆噳锛岀敓鎴愯仛姘ㄩ叝閺堟銆�
2. 鎺у埗鍙嶆噳閫熺巼锛歍AP鐨勫偓鍖栨椿鎬у彲浠ラ€氶亷瑾�(di脿o)绡€(ji茅)鍏剁敤閲忎締鎺у埗鍙嶆噳閫熺巼锛屽緸鑰屽鐝�(xi脿n)灏嶈仛姘ㄩ叝褰堟€ч珨鍒嗗瓙绲�(ji茅)妲�(g貌u)鐨勭簿纰鸿(di脿o)鎺�銆�
3. 鎻愰珮浜よ伅(li谩n)瀵嗗害锛歍AP鑳藉淇冮€茶仛姘ㄩ叝閺堟涔嬮枔鐨勪氦鑱�(li谩n)鍙嶆噳锛屾彁楂樻潗鏂欑殑浜よ伅(li谩n)瀵嗗害锛屽緸鑰屽寮峰叾姗熸鎬ц兘鍜岃€愮啽鎬с€�

3. 涓夎仛鍌寲鍔慣AP鐨勭敘(ch菐n)鍝佸弮鏁�(sh霉)

涓夎仛鍌寲鍔慣AP鐨勭敘(ch菐n)鍝佸弮鏁�(sh霉)濡備笅琛ㄦ墍绀猴細

4. 涓夎仛鍌寲鍔慣AP鍦ㄩ珮鎬ц兘鑱氭皑閰綀鎬ч珨涓殑鎳夌敤

4.1 鎻愰珮姗熸鎬ц兘

涓夎仛鍌寲鍔慣AP鑳藉椤憲鎻愰珮鑱氭皑閰綀鎬ч珨鐨勬姊版€ц兘锛屽寘鎷媺浼稿挤搴�銆佹柗瑁備几闀风巼銆佹挄瑁傚挤搴︾瓑銆備互涓嬫槸閫氶亷瀵﹂寰楀埌鐨勬暩(sh霉)鎿�(j霉)锛�

4.2 鎻愰珮鑰愮啽鎬�

涓夎仛鍌寲鍔慣AP鑳藉鎻愰珮鑱氭皑閰綀鎬ч珨鐨勮€愮啽鎬�锛屼娇鍏跺湪楂樻韩鐠�(hu谩n)澧冧笅浠嶈兘淇濇寔鑹ソ鐨勬姊版€ц兘銆備互涓嬫槸閫氶亷鐔辫€佸寲瀵﹂寰楀埌鐨勬暩(sh霉)鎿�(j霉)锛�

4.3 鎻愰珮鑰愬寲瀛歌厫铦曟€�

涓夎仛鍌寲鍔慣AP鑳藉鎻愰珮鑱氭皑閰綀鎬ч珨鐨勮€愬寲瀛歌厫铦曟€�锛屼娇鍏跺湪閰�銆佸牽銆佹补绛夊寲瀛镐粙璩�(zh矛)涓粛鑳戒繚鎸佽壇濂界殑鎬ц兘銆備互涓嬫槸閫氶亷鍖栧鑵愯潟瀵﹂寰楀埌鐨勬暩(sh霉)鎿�(j霉)锛�

4.4 鎻愰珮鍔犲伐鎬ц兘

涓夎仛鍌寲鍔慣AP鑳藉鏀瑰杽鑱氭皑閰綀鎬ч珨鐨勫姞宸ユ€ц兘锛屼娇鍏跺湪娉ㄥ銆佹摖鍑虹瓑鍔犲伐閬庣▼涓洿鍔犻爢鏆�銆備互涓嬫槸閫氶亷鍔犲伐瀵﹂寰楀埌鐨勬暩(sh霉)鎿�(j霉)锛�

5. 鎳夌敤妗堜緥

5.1 姹借粖宸ユキ(y猫)

鍦ㄦ苯杌婂伐妤�(y猫)涓紝鑱氭皑閰綀鎬ч珨寤ｆ硾鎳夌敤浜庡瘑灏佷欢銆佹笡闇囧櫒銆佽吉鑳庣瓑閮ㄤ欢銆備娇鐢ㄤ笁鑱氬偓鍖栧姂TAP鍒跺倷鐨勮仛姘ㄩ叝褰堟€ч珨鍏锋湁鏇撮珮鐨勬姊版€ц兘鍜岃€愮啽鎬�锛岃兘澶犻’钁楁彁楂樻苯杌婇儴浠剁殑浣跨敤澹藉懡鍜屽畨鍏ㄦ€�銆�

5.2 寤虹瓚琛屾キ(y猫)

鍦ㄥ缓绛戣妤�(y猫)涓紝鑱氭皑閰綀鎬ч珨甯哥敤浜庨槻姘存潗鏂�銆佸瘑灏佽啝銆佷繚婧潗鏂欑瓑銆備娇鐢ㄤ笁鑱氬偓鍖栧姂TAP鍒跺倷鐨勮仛姘ㄩ叝褰堟€ч珨鍏锋湁鏇村ソ鐨勮€愬寲瀛歌厫铦曟€у拰鍔犲伐鎬ц兘锛岃兘澶犳彁楂樺缓绛戞潗鏂欑殑鑰愪箙鎬у拰鏂藉伐鏁堢巼銆�

5.3 闆诲瓙琛屾キ(y猫)

鍦ㄩ浕瀛愯妤�(y猫)涓紝鑱氭皑閰綀鎬ч珨甯哥敤浜庨浕绾滆濂�銆佺禃绶ｆ潗鏂欑瓑銆備娇鐢ㄤ笁鑱氬偓鍖栧姂TAP鍒跺倷鐨勮仛姘ㄩ叝褰堟€ч珨鍏锋湁鏇撮珮鐨勮€愮啽鎬у拰姗熸鎬ц兘锛岃兘澶犳彁楂橀浕瀛愮敘(ch菐n)鍝佺殑鍙潬鎬у拰瀹夊叏鎬�銆�

5.4 閱�(y墨)鐧傝妤�(y猫)

鍦ㄩ啱(y墨)鐧傝妤�(y猫)涓紝鑱氭皑閰綀鎬ч珨甯哥敤浜庝汉宸ュ櫒瀹�銆佸皫绠°€佸瘑灏佷欢绛�銆備娇鐢ㄤ笁鑱氬偓鍖栧姂TAP鍒跺倷鐨勮仛姘ㄩ叝褰堟€ч珨鍏锋湁鏇村ソ鐨勭敓鐗╃浉瀹规€у拰鑰愬寲瀛歌厫铦曟€�锛岃兘澶犳彁楂橀啱(y墨)鐧傚櫒姊扮殑瀹夊叏鎬у拰浣跨敤澹藉懡銆�

6. 绲�(ji茅)璜�

涓夎仛鍌寲鍔慣AP浣滅偤涓€绋柊鍨嬪偓鍖栧姂锛屽湪楂樻€ц兘鑱氭皑閰綀鎬ч珨鐨勫埗鍌欎腑鍏锋湁寤ｆ硾鐨勬噳鐢ㄥ墠鏅�銆傞€氶亷瑾�(di脿o)绡€(ji茅)TAP鐨勭敤閲忥紝鍙互椤憲鎻愰珮鑱氭皑閰綀鎬ч珨鐨勬姊版€ц兘銆佽€愮啽鎬�銆佽€愬寲瀛歌厫铦曟€у拰鍔犲伐鎬ц兘锛屽緸鑰屾豢瓒充笉鍚岃妤�(y猫)灏嶉珮鎬ц兘鏉愭枡鐨勯渶姹�銆傞毃钁楁妧琛�(sh霉)鐨勪笉鏂烽€叉锛屼笁鑱氬偓鍖栧姂TAP鍦ㄨ仛姘ㄩ叝褰堟€ч珨涓殑鎳夌敤灏囨渻鏇村姞寤ｆ硾锛岀偤宸ユキ(y猫)鐧�(f膩)灞曟彁渚涘挤鏈夊姏鐨勬敮鎸�銆�

7. 鏈締灞曟湜

闅ㄨ憲鐠�(hu谩n)淇濊姹傜殑涓嶆柗鎻愰珮锛屾湭渚嗕笁鑱氬偓鍖栧姂TAP鐨勭爺鐧�(f膩)鏂瑰悜?q奴)鈷忣弴骞尖拝涓╤(hu谩n)淇濇€у拰鍙寔绾�(x霉)鎬�銆傞€氶亷鏀归€插悎鎴愬伐钘濆拰鍎�(y艒u)鍖栧垎瀛愮祼(ji茅)妲�(g貌u)锛屽彲浠ラ€蹭竴姝ユ彁楂楾AP鐨勫偓鍖栨椿鎬у拰绌�(w臎n)瀹氭€э紝鍚屾檪闄嶄綆鍏跺皪鐠�(hu谩n)澧冪殑褰遍熆銆傛澶�锛岄毃钁楁柊鏉愭枡鍜屾柊鎶€琛�(sh霉)鐨勪笉鏂锋秾鐝�(xi脿n)锛屼笁鑱氬偓鍖栧姂TAP鍦ㄨ仛姘ㄩ叝褰堟€ч珨涓殑鎳夌敤灏囨渻鏇村姞澶氭ǎ鍖栧拰绮剧窗鍖栵紝鐐哄伐妤�(y猫)鐧�(f膩)灞曞付渚嗘洿澶氱殑鍙兘鎬�銆�

8. 绺界祼(ji茅)

鏈枃瑭崇窗浠嬬垂浜嗕笁鑱氬偓鍖栧姂TAP鍦ㄩ珮鎬ц兘鑱氭皑閰綀鎬ч珨涓殑鎳夌敤锛屽寘鎷叾鍖栧绲�(ji茅)妲�(g貌u)銆佷綔鐢ㄦ鐞嗐€佺敘(ch菐n)鍝佸弮鏁�(sh霉)銆佹噳鐢ㄦ渚嬬瓑銆傞€氶亷琛ㄦ牸褰㈠紡灞曠ず浜嗙浉闂�(gu膩n)鏁�(sh霉)鎿�(j霉)锛屼互渚胯畝鑰呮洿濂藉湴鐞嗚В鍜屾帉鎻￠€欎竴鎶€琛�(sh霉)銆傚笇鏈涙湰鏂囪兘澶犵偤鐩搁棞(gu膩n)闋樺煙鐨勭爺绌朵汉鍝″拰宸ョ▼鎶€琛�(sh霉)浜哄摗鎻愪緵鏈夊児鍊肩殑鍙冭€冿紝鎺ㄥ嫊涓夎仛鍌寲鍔慣AP鍦ㄨ仛姘ㄩ叝褰堟€ч珨涓殑閫蹭竴姝ユ噳鐢ㄥ拰鐧�(f膩)灞�銆�

娉�锛氭湰鏂囧収(n猫i)瀹圭偤鍘熷壍(chu脿ng)锛屾棬鍦ㄦ彁渚涢棞(gu膩n)浜庝笁鑱氬偓鍖栧姂TAP鍦ㄩ珮鎬ц兘鑱氭皑閰綀鎬ч珨涓噳鐢ㄧ殑鍏ㄩ潰浠嬬垂銆傛枃涓暩(sh霉)鎿�(j霉)鐐烘ā鎿暩(sh霉)鎿�(j霉)锛屽儏渚涘弮鑰�銆�

鎿村睍闁辫畝:https://www.newtopchem.com/archives/44166

鎿村睍闁辫畝:https://www.cyclohexylamine.net/reactive-catalyst-dabco-reactive-catalyst/

鎿村睍闁辫畝:https://www.bdmaee.net/tetramethyldipropylene-triamine-cas-6711-48-4-bis-3-dimethylpropylaminoamine/

鎿村睍闁辫畝:https://www.newtopchem.com/archives/555

鎿村睍闁辫畝:https://www.morpholine.org/category/morpholine/page/6/

鎿村睍闁辫畝:https://www.newtopchem.com/archives/472

鎿村睍闁辫畝:https://www.newtopchem.com/archives/44830

鎿村睍闁辫畝:https://www.newtopchem.com/archives/1590

鎿村睍闁辫畝:https://www.bdmaee.net/nt-cat-nem-catalyst-cas100-74-3-newtopchem/

鎿村睍闁辫畝:https://www.newtopchem.com/archives/1830