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鍩烘湰鐞嗗寲鎬ц唱(zh矛)

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   text{1-鐢插熀鍜攽} + text{鐣颁竵鍩烘捍鍖栫墿} rightarrow text{1-鐣颁竵鍩哄挭鍞憓
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BMIM鍦ㄦ秱鏂欎腑鐨勬噳(y墨ng)鐢ㄥ渚�

1. 姘存€ф秱鏂欎腑鐨勬噳(y墨ng)鐢�

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鐮旂┒琛ㄦ槑锛孊MIM鑳藉鑸囨按鎬фü鑴備腑鐨勬椿鎬у熀鍦�(tu谩n)锛堝缇ュ熀銆佺晶鍩虹瓑锛夌櫦(f膩)鐢熶氦鑱�(li谩n)鍙嶆噳(y墨ng)锛屽舰鎴愪笁缍恫(w菐ng)绲�(lu貌)绲�(ji茅)妲�(g貌u)锛屽緸鑰屽寮�(qi谩ng)娑傚堡鐨勬(j墨)姊板挤(qi谩ng)搴﹀拰鑰愭按鎬�銆傛澶�锛孊MIM閭勫叿鏈変竴瀹氱殑瑕按鎬�锛岃兘澶犲湪娑傝啘琛ㄩ潰褰㈡垚涓€灞よ嚧瀵嗙殑淇濊(h霉)鑶滐紝闃叉姘村垎婊查€�锛屾彁楂樻秱灞ょ殑鎶楄厫铦曡兘鍔涖€�

涓嬭〃鍒楀嚭浜咮MIM鍦ㄦ按鎬ф秱鏂欎腑鐨勫叿楂旀噳(y墨ng)鐢ㄦ晥鏋滐細

寰炶〃涓彲浠ョ湅鍑�锛岄毃钁桞MIM娣诲姞閲忕殑澧炲姞锛屾按鎬ф秱鏂欑殑鍚勯爡鎬ц兘鍧囧緱鍒颁簡椤憲鎻愬崌銆傜壒鍒ユ槸鍦ㄨ€愭按鎬у拰鑰愯厫铦曟€ф柟闈紝BMIM琛ㄧ従(xi脿n)鍑哄劒(y艒u)鐣扮殑鏁堟灉锛岃兘澶犳湁鏁堝欢闀锋秱灞ょ殑浣跨敤澹藉懡銆�

2. 鐠�(hu谩n)姘фü鑴傛秱鏂欎腑鐨勬噳(y墨ng)鐢�

鐠�(hu谩n)姘фü鑴傛秱鏂欎互鍏跺劒(y艒u)鐣扮殑闄勮憲鍔�銆佽€愬寲瀛�(xu茅)鍝佹€у拰姗�(j墨)姊板挤(qi谩ng)搴﹁€岃仦鍚嶏紝寤ｆ硾鎳�(y墨ng)鐢ㄤ簬閲嶉槻鑵愰牁(l菒ng)鍩�銆傜劧鑰�锛屽偝绲�(t菕ng)鐨勭挵(hu谩n)姘фü鑴傛秱鏂欏湪鍥哄寲閬庣▼涓鏄撶敘(ch菐n)鐢熸埃娉″拰鏀剁府鎳�(y墨ng)鍔涳紝灏�(d菐o)鑷存秱灞よ〃闈笉骞虫暣锛屽奖闊垮瑙€璩�(zh矛)閲�銆侭MIM鐨勫姞鍏ュ彲浠ユ敼鍠勯€欎竴鍟忛锛屼績閫�(j矛n)鐠�(hu谩n)姘фü鑴傜殑鍧囧嫽鍥哄寲锛屾笡灏戞埃娉″拰鏀剁府鐝�(xi脿n)璞�銆�

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寰炶〃涓彲浠ョ湅鍑�锛孊MIM鐨勫姞鍏ラ’钁楃府鐭簡鐠�(hu谩n)姘фü鑴傛秱鏂欑殑鍥哄寲鏅傞枔锛屽苟鎻愰珮浜嗘秱灞ょ殑纭害銆侀檮钁楀姏鍜屾姉娌栨搳鎬�銆傜壒鍒ユ槸鍦ㄨ€愬寲瀛�(xu茅)鍝佹€ф柟闈�锛孊MIM琛ㄧ従(xi脿n)鍑哄劒(y艒u)鐣扮殑鏁堟灉锛岃兘澶犳湁鏁堟姷鎶楀悇绋寲瀛�(xu茅)浠嬭唱(zh矛)鐨勪镜铦曪紝寤堕暦娑傚堡鐨勪娇鐢ㄥ＝鍛�銆�

3. UV鍥哄寲娑傛枡涓殑鎳�(y墨ng)鐢�

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寰炶〃涓彲浠ョ湅鍑�锛孊MIM鐨勫姞鍏ラ’钁楃府鐭簡UV鍥哄寲娑傛枡鐨勫浐鍖栨檪闁�锛屽苟鎻愰珮浜嗘秱灞ょ殑鍏夋兢搴�銆侀檮钁楀姏鍜岃€愮（鎬�銆傜壒鍒ユ槸鍦ㄦ姉榛冭畩鎬ф柟闈紝BMIM琛ㄧ従(xi脿n)鍑哄劒(y艒u)鐣扮殑鏁堟灉锛岃兘澶犳湁鏁堥槻姝㈡秱灞ゅ湪闀锋湡浣跨敤閬庣▼涓嚭鐝�(xi脿n)榛冭畩鐝�(xi脿n)璞�锛屼繚鎸佸叾缇庤鍜岃€愮敤鎬с€�

BMIM灏嶆秱灞ゆ€ц兘鐨勫奖闊挎(j墨)鍒�

1. 鎻愬崌闄勮憲鍔�

BMIM涔嬫墍浠ヨ兘澶犻’钁楁彁鍗囨秱灞ょ殑闄勮憲鍔涳紝涓昏鏄洜鐐哄畠鍏锋湁杓冨挤(qi谩ng)鐨勬サ鎬у拰鍙嶆噳(y墨ng)娲绘€�銆傚湪娑傝啘褰㈡垚閬庣▼涓紝BMIM鑳藉鑸囧熀鏉愯〃闈㈢殑娲绘€у熀鍦�(tu谩n)锛堝缇ュ熀銆佺晶鍩虹瓑锛夌櫦(f膩)鐢熷寲瀛�(xu茅)閸靛悎锛屽舰鎴愮墷鍥虹殑鐣岄潰灞�銆傛澶栵紝BMIM閭勮兘澶犱績閫�(j矛n)娑傝啘鍏�(n猫i)閮ㄧ殑浜よ伅(li谩n)鍙嶆噳(y墨ng)锛屽舰鎴愯嚧瀵嗙殑缍�(w菐ng)绲�(lu貌)绲�(ji茅)妲�(g貌u)锛屽緸鑰屽寮�(qi谩ng)娑傚堡鑸囧熀鏉愪箣闁撶殑绲�(ji茅)鍚堝姏銆�

鐮旂┒琛ㄦ槑锛孊MIM鐨勫姞鍏ュ彲浠ヤ娇娑傚堡鐨勯檮钁楀姏鎻愰珮30%-50%锛屽挨鍏舵槸鍦ㄩ噾灞拰濉戞枡绛夐洠绮樺熀鏉愪笂琛ㄧ従(xi脿n)灏ょ偤鏄庨’銆傞€氶亷鎺冩弿闆诲瓙椤井閺★紙SEM锛夎瀵熺櫦(f膩)鐝�(xi脿n)锛屽惈鏈塀MIM鐨勬秱灞よ〃闈㈡洿鍔犲钩鏁�锛屽瓟闅欑巼鏇翠綆锛岄€欐湁鍔╀簬鎻愰珮娑傚堡鐨勮€愪箙鎬у拰鎶楄厫铦曟€ц兘銆�

2. 鏀瑰杽鑰愯厫铦曟€�

BMIM灏嶆秱灞よ€愯厫铦曟€х殑鎻愬崌涓昏楂旂従(xi脿n)鍦ㄥ叐鍊嬫柟闈細涓€鏄€氶亷褰㈡垚鑷村瘑鐨勪繚璀�(h霉)鑶滐紝闃绘澶栫晫鑵愯潟浠嬭唱(zh矛)锛堝姘�銆佹哀姘�銆佹隘闆㈠瓙绛夛級婊查€忓埌娑傚堡鍏�(n猫i)閮�锛涗簩鏄€氶亷鑸囪厫铦曚粙璩�(zh矛)鐧�(f膩)鐢熷寲瀛�(xu茅)鍙嶆噳(y墨ng)锛屾秷鑰楁湁瀹崇墿璩�(zh矛)锛屽欢绶╄厫铦曢亷绋�銆�

渚嬪锛屽湪娴锋磱鐠�(hu谩n)澧冧腑锛屾隘闆㈠瓙鏄皫(d菐o)鑷撮噾灞厫铦曠殑涓昏鍥犵礌涔嬩竴銆侭MIM鑳藉鑸囨隘闆㈠瓙鐧�(f膩)鐢熺怠(lu貌)鍚堝弽鎳�(y墨ng)锛屽舰鎴愮┅(w臎n)瀹氱殑閰嶅悎鐗�锛屽緸鑰屾湁鏁堝湴鎶戝埗姘洟瀛愮殑鎿�(ku貌)鏁�銆傛澶�锛孊MIM閭勮兘澶犲湪閲戝爆琛ㄩ潰褰㈡垚涓€灞ら垗鍖栬啘锛岄樆姝㈤€�(j矛n)涓€姝ョ殑姘у寲鍙嶆噳(y墨ng)锛岃捣鍒伴暦鏁堥槻璀�(h霉)鐨勪綔鐢�銆�

瀵﹂绲�(ji茅)鏋滆〃鏄庯紝鍚湁BMIM鐨勬秱灞ゅ湪楣介湩瑭﹂涓殑鑰愯厫铦曟檪闁撳彲寤堕暦鑷冲師渚嗙殑2-3鍊�锛岄’绀哄嚭鍎�(y艒u)鐣扮殑鎶楄厫铦曟€ц兘銆傜壒鍒ユ槸鍦ㄦ儭鍔ｇ挵(hu谩n)澧冧笅锛屽鍖栧伐寤�銆佹捣娲嬪钩鑷虹瓑锛孊MIM鐨勬噳(y墨ng)鐢ㄨ兘澶犻’钁楀欢闀锋秱灞ょ殑浣跨敤澹藉懡锛岄檷浣庣董璀�(h霉)鎴愭湰銆�

3. 澧炲挤(qi谩ng)鑰愮（鎬�

BMIM灏嶆秱灞よ€愮（鎬х殑鎻愬崌涓昏寰楃泭浜庡叾鐛�(d煤)鐗圭殑鍒嗗瓙绲�(ji茅)妲�(g貌u)鍜屽劒(y艒u)鐣扮殑鐗╃悊鎬ц兘銆侭MIM鍒嗗瓙涓惈鏈夊墰鎬х殑鍜攽鐠�(hu谩n)鍜屾煍鎬у伌(c猫)閺�锛岃兘澶犲湪娑傝啘涓舰鎴愭湁搴忔帓鍒�锛岃肠浜堟秱灞よ純楂樼殑纭害鍜岄煂鎬�銆傛澶�锛孊MIM閭勮兘澶犱績閫�(j矛n)娑傝啘鍏�(n猫i)閮ㄧ殑浜よ伅(li谩n)鍙嶆噳(y墨ng)锛屽舰鎴愯嚧瀵嗙殑缍�(w菐ng)绲�(lu貌)绲�(ji茅)妲�(g貌u)锛屽緸鑰屾彁楂樻秱灞ょ殑鑰愮（鎬у拰鎶楀妰鍌疯兘鍔涖€�

鐮旂┒琛ㄦ槑锛孊MIM鐨勫姞鍏ュ彲浠ヤ娇娑傚堡鐨勮€愮（鎬ф彁楂�20%-40%锛屽挨鍏舵槸鍦ㄩ珮閫熸懇鎿﹀拰楂樿矤(f霉)鑽锋浠朵笅琛ㄧ従(xi脿n)灏ょ偤绐佸嚭銆傞€氶亷纾ㄦ悕瑭﹂鐧�(f膩)鐝�(xi脿n)锛屽惈鏈塀MIM鐨勬秱灞よ〃闈㈠厜婊�锛岀劇鏄庨’鍔冪棔锛岄’绀哄嚭鍎�(y艒u)鐣扮殑鎶楃（鎼嶆€ц兘銆傛澶�锛孊MIM閭勮兘澶犻檷浣庢秱灞ょ殑鎽╂摝绯绘暩(sh霉)锛屾笡灏戞懇鎿︾敘(ch菐n)鐢熺殑鐔遍噺锛岄€�(j矛n)涓€姝ュ欢闀锋秱灞ょ殑浣跨敤澹藉懡銆�

4. 鎻愰珮鑰愬€欐€�

BMIM灏嶆秱灞よ€愬€欐€х殑鎻愬崌涓昏楂旂従(xi脿n)鍦ㄥ叾鍎�(y艒u)鐣扮殑鍏夌┅(w臎n)瀹氭€у拰鎶楁哀鍖栨€ц兘銆侭MIM鍒嗗瓙涓惈鏈夎睈瀵岀殑鍏辫粵楂旂郴锛岃兘澶犳湁鏁堝惛鏀剁传澶栫窔锛岄槻姝㈡秱鑶滆€佸寲銆傛澶�锛孊MIM閭勮兘澶犺垏鑷敱鍩虹櫦(f膩)鐢熷弽鎳�(y墨ng)锛屾秷鑰楁湁瀹崇墿璩�(zh矛)锛屽欢绶╂哀鍖栭亷绋�锛屽緸鑰屾彁楂樻秱灞ょ殑鑰愬€欐€�銆�

瀵﹂绲�(ji茅)鏋滆〃鏄�锛屽惈鏈塀MIM鐨勬秱灞ゅ湪鎴跺鏆存洭瑭﹂涓殑澶卞厜鐜囧拰绮夊寲鐜囧潎椤憲浣庝簬鏈坊鍔燘MIM鐨勫皪鐓х祫銆傜壒鍒ユ槸鍦ㄩ珮婧�銆侀珮婵�銆佸挤(qi谩ng)绱绶氱瓑鎯″姡鐠�(hu谩n)澧冧笅锛孊MIM鐨勬噳(y墨ng)鐢ㄨ兘澶犻’钁楀欢闀锋秱灞ょ殑浣跨敤澹藉懡锛屼繚鎸佸叾缇庤鍜岃€愮敤鎬с€�

绲�(ji茅)璜栬垏灞曟湜

绺界祼(ji茅)

閫氶亷灏岯MIM鍦ㄦ秱鏂欎腑鐨勬噳(y墨ng)鐢ㄥ強鍏跺皪娑傚堡鎬ц兘鐨勫奖闊块€�(j矛n)琛岃┏绱�(x矛)鍒嗘瀽锛屽彲浠ュ緱鍑轰互涓嬬祼(ji茅)璜栵細

1. 澶氬姛鑳芥€�锛欱MIM浣滅偤涓€绋柊鍨嬪姛鑳芥€ф坊鍔犲姂锛岃兘澶犲湪姘存€ф秱鏂�銆佺挵(hu谩n)姘фü鑴傛秱鏂欏拰UV鍥哄寲娑傛枡绛夊绋珨绯讳腑鐧�(f膩)鎻噸瑕佷綔鐢紝椤憲鎻愬崌娑傚堡鐨勯檮钁楀姏銆佽€愯厫铦曟€�銆佽€愮（鎬у拰鑰愬€欐€�銆�
2. 鍎�(y艒u)鐣扮殑鐗╃悊鍖栧(xu茅)鎬ц唱(zh矛)锛欱MIM鍏锋湁鑹ソ鐨勭啽绌�(w臎n)瀹氭€у拰鍖栧(xu茅)绌�(w臎n)瀹氭€э紝鑳藉鍦ㄨ純瀵殑婧害鑼冨湇鍏�(n猫i)淇濇寔鎬ц兘涓嶈畩銆傛澶栵紝瀹冮倓琛ㄧ従(xi脿n)鍑哄劒(y艒u)鐣扮殑婧惰В鎬�锛岃兘澶犺垏澶氱ó鏈夋(j墨)婧跺姂鍜岃仛鍚堢墿鐩稿锛岄仼鐢ㄤ簬涓嶅悓鐨勬秱鏂欓珨绯�銆�
3. 鐠�(hu谩n)淇濆弸濂�锛欱MIM鐨勫悎鎴愬師鏂欐槗寰楋紝鎴愭湰杓冧綆锛屼笖鍦ㄤ娇鐢ㄩ亷绋嬩腑涓嶆渻閲嬫斁鏈夊鐗╄唱(zh矛)锛岀鍚堢従(xi脿n)浠ｇぞ鏈冨皪鐠�(hu谩n)淇濆瀷娑傛枡鐨勮姹�銆�

灞曟湜

鐩＄BMIM鍦ㄦ秱鏂欒妤�(y猫)涓殑鎳�(y墨ng)鐢ㄥ凡缍�(j墨ng)鍙栧緱浜嗕竴瀹氱殑鎴愭灉锛屼絾浠嶆湁杓冨ぇ鐨勭櫦(f膩)灞曠┖闁�銆傛湭渚嗙殑鐮旂┒鏂瑰悜鍙互闆嗕腑鍦ㄤ互涓嬪咕鍊嬫柟闈細

1. 闁嬬櫦(f膩)鏂板瀷BMIM琛嶇敓鐗�锛氶€氶亷寮曞叆涓嶅悓鐨勫畼鑳藉湗(tu谩n)鎴栨敼璁婂垎瀛愮祼(ji茅)妲�(g貌u)锛岄枊鐧�(f膩)鍑烘洿澶氬叿鏈夌壒瀹氬姛鑳界殑BMIM琛嶇敓鐗�锛屼互婊胯冻涓嶅悓鎳�(y墨ng)鐢ㄥ牬鏅殑闇€姹�銆�
2. 鍎�(y艒u)鍖栧悎鎴愬伐钘�锛氶€�(j矛n)涓€姝ュ劒(y艒u)鍖朆MIM鐨勫悎鎴愬伐钘濓紝闄嶄綆鎴愭湰锛屾彁楂樻敹鐜�锛屾帹鍕曞叾澶ц(gu墨)妯″伐妤�(y猫)鍖栨噳(y墨ng)鐢�銆�
3. 鎷撳睍鎳�(y墨ng)鐢ㄩ牁(l菒ng)鍩�锛氶櫎浜嗘秱鏂欒妤�(y猫)锛孊MIM閭勫彲浠ユ噳(y墨ng)鐢ㄤ簬鍏朵粬闋�(l菒ng)鍩�锛屽娼ゆ粦鍔戙€佸濉戝姂銆佸偓鍖栧姂绛�锛屾帰绱㈠叾鍦ㄩ€欎簺闋�(l菒ng)鍩熺殑娼涘湪鎳�(y墨ng)鐢ㄥ児鍊�銆�
4. 娣卞叆鐮旂┒浣滅敤姗�(j墨)鍒�锛氶€氶亷鏇村鐨勫椹楀拰鐞嗚珫鐮旂┒锛屾繁鍏ユ帰瑷嶣(t脿i)MIM灏嶆秱灞ゆ€ц兘鐨勫奖闊挎(j墨)鍒讹紝鐐洪€�(j矛n)涓€姝ュ劒(y艒u)鍖栭厤鏂规彁渚涚悊璜栨敮鎸�銆�

绺戒箣锛孊MIM浣滅偤涓€绋叿鏈夊唬闂婃噳(y墨ng)鐢ㄥ墠鏅殑鍔熻兘鎬ф坊鍔犲姂锛屽繀灏囧湪鏈締鐨勬秱鏂欒妤�(y猫)涓櫦(f膩)鎻秺渚嗚秺閲嶈鐨勪綔鐢�銆傞毃钁楁妧琛�(sh霉)鐨勪笉鏂烽€�(j矛n)姝ュ拰甯傚牬闇€姹傜殑鎸佺簩(x霉)澧為暦锛孊MIM鏈夋湜鎴愮偤鎺ㄥ嫊娑傛枡琛屾キ(y猫)鍓�(chu脿ng)鏂扮櫦(f膩)灞曠殑闂�(gu膩n)閸靛姏閲�銆�

鎿�(ku貌)灞曢柋璁€:https://www.newtopchem.com/archives/44371

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/jeffcat-dmdee-catalyst-cas11225-78-5-huntsman/

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/cas-753-73-1/

鎿�(ku貌)灞曢柋璁€:https://www.newtopchem.com/archives/44655

鎿�(ku貌)灞曢柋璁€:https://www.cyclohexylamine.net/dabco-eg-pc-cat-td-33eg-niax-a-533/

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/anhydrous-tin-tetrachloride-2/

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/wp-content/uploads/2022/08/stannous-octoate-CAS-301-10-0–T-9.pdf

鎿�(ku貌)灞曢柋璁€:https://www.cyclohexylamine.net/dabco-pt304-polyurethane-rigid-foam-catalyst-pt304/

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/nt-cat-1028-catalyst-cas100515-56-6-newtopchem/

鎿�(ku貌)灞曢柋璁€:https://www.bdmaee.net/cas-68928-76-7/