鑰愭按瑙ｉ噾灞偓鍖栧姂 vs 鍌崇当(t菕ng)閲戝爆鍌寲鍔戯細涓€鍫村偓鍖栧姂鐣岀殑鈥滆€愬姏澶ф瘮鎷尖€�

鍦ㄥ寲瀛�(xu茅)宸ユキ(y猫)鐨勬旦鐎氭槦绌轰腑锛屽偓鍖栧姂灏卞儚閭ｉ榛橀粯鐧�(f膩)鍏夊嵒鑷抽棞(gu膩n)閲嶈鐨勬亽鏄�銆傚畠鍊戦洊涓嶇洿鎺ュ弮鑸囧弽鎳�(y墨ng)鏈韩锛屽嵒鑳藉ぇ澶у姞閫熷弽鎳�(y墨ng)閫熺巼銆侀檷浣庤兘鑰�銆佹彁楂橀伕鎿囨€�锛屾槸鐝�(xi脿n)浠ｅ寲宸ヤ笉鍙垨缂虹殑鈥滃箷鍚庤嫳闆勨€�銆傝€屽湪鐪惧椤炲瀷鐨勫偓鍖栧姂涓紝閲戝爆鍌寲鍔戠劇鐤戞槸鑰€鐪肩殑鏄庢槦涔嬩竴銆�

浣嗛毃钁楀伐钘濇浠剁殑鏃ョ泭鑻涘埢锛屽挨鍏舵槸鍦ㄥ惈姘寸挵(hu谩n)澧冧笅鐨勫偓鍖栧弽鎳�(y墨ng)涓�锛屽偝绲�(t菕ng)閲戝爆鍌寲鍔戦€愭几椤湶鍑轰竴鍊�(g猫)鑷村懡寮遍粸(di菐n)鈥斺€旀€曟按锛佹矑閷�(cu貌)锛屽畠鍊戜笉鏄€曡娣嬫繒閭ｄ箞绨″柈锛岃€屾槸闈㈠皪姘村垎瀛愭檪(sh铆)瀹规槗鐧�(f膩)鐢熲€滄按瑙ｂ€�锛屽皫(d菐o)鑷存椿鎬т笅闄嶇敋鑷冲け娲�銆備簬鏄紝绉戝(xu茅)瀹跺€戦枊濮嬬爺鐧�(f膩)涓€绋柊鍨嬬殑閲戝爆鍌寲鍔戔€斺€�鑰愭按瑙ｉ噾灞偓鍖栧姂锛屽畠灏卞儚鏄┛涓婁簡闃插綀琛ｇ殑鎴�(zh脿n)澹�锛屽湪娼繒鐠�(hu谩n)澧冧腑渚濈劧鑻卞媷濂埌(zh脿n)銆�

浠婂ぉ锛屾垜鍊戝氨渚嗚亰鑱婇€欏叐椤炲偓鍖栧姂涔嬮枔鐨勬€ц兘宸暟锛岀湅鐪嬭鎵嶆槸鐪熸鐨勨€滄按涓帇鑰呪€濄€�

涓€銆佸偓鍖栧姂鐨勬睙婀栭ⅷ(f膿ng)浜戦寗

1. 鍌寲鍔戠殑鍩烘湰姒傚康

鍌寲鍔戞槸涓€绋兘澶犳敼璁婂寲瀛�(xu茅)鍙嶆噳(y墨ng)閫熺巼鑰屼笉鏀硅畩鑷韩绲勬垚鍜岃唱(zh矛)閲忕殑鐗╄唱(zh矛)銆傚畠鍊戦€氶亷鎻愪緵涓€姊濊兘閲忔洿浣庣殑鍙嶆噳(y墨ng)璺緫锛屼娇寰楀師鏈渶瑕侀珮婧珮澹撴墠鑳介€�(j矛n)琛岀殑鍙嶆噳(y墨ng)璁婂緱婧拰鍙帶銆�

鏍规摎(j霉)鐙€鎱�(t脿i)涓嶅悓锛屽偓鍖栧姂鍙垎鐐猴細

• 鍥洪珨鍌寲鍔�
• 娑查珨鍌寲鍔�
• 姘ｉ珨鍌寲鍔�

鑰屾寜鐓ф潗鏂欓鍨嬶紝鍙堝彲鍒嗙偤锛�

• 閲戝爆鍌寲鍔戯紙濡傞墤銆侀垁銆侀幊绛夛級
• 闈為噾灞偓鍖栧姂锛堝纰冲熀鏉愭枡锛�
• 閰跺偓鍖栧姂锛堢敓鐗╁偓鍖栵級

鎴戝€戜粖澶╃殑涓昏灏辨槸鈥斺€旈噾灞偓鍖栧姂锛�

2. 鍌崇当(t菕ng)閲戝爆鍌寲鍔戯細杓濈厡涓€鏅�(sh铆)鐨勨€滆€佸皣鈥�

鍌崇当(t菕ng)閲戝爆鍌寲鍔戜富瑕佸寘鎷泊閲戝爆锛堝Pt銆丳d銆丷h锛夊拰闈炶泊閲戝爆锛堝Ni銆丆o銆丗e锛�銆傚畠鍊戝唬娉涙噳(y墨ng)鐢ㄤ簬鐭虫补鐓夊埗銆佹湁姗�(j墨)鍚堟垚銆佺挵(hu谩n)澧冧繚璀�(h霉)绛夐牁(l菒ng)鍩燂紝灏ゅ叾鍦ㄥ姞姘�銆佽劔纭�銆佹哀鍖栫瓑鍙嶆噳(y墨ng)涓〃鐝�(xi脿n)鍎�(y艒u)鐣般€�

涓嶉亷锛岄€欎簺鈥滆€佸皣鈥濅篃鏈夎嚜宸辩殑杌熻倠銆傛瘮濡傚湪鍚按楂旂郴涓�锛屽緢澶氬偝绲�(t菕ng)閲戝爆鍌寲鍔戞渻鐧�(f膩)鐢熸按瑙ｅ弽鎳�(y墨ng)锛屽挨鍏舵槸鏌愪簺閬庢浮閲戝爆楣介鎴栨哀鍖栫墿锛岀祼(ji茅)妲�(g貌u)鐮村鍚庡偓鍖栨椿鎬ф€ュ妵涓嬮檷銆�

3. 鑰愭按瑙ｉ噾灞偓鍖栧姂锛氭柊涓€浠ｂ€滄按闄稿叐妫插叺鈥�

鐐轰簡瑙ｆ焙鍌崇当(t菕ng)閲戝爆鍌寲鍔戠殑姘磋В鍟忛锛岀瀛�(xu茅)瀹跺€戦枊鐧�(f膩)鍑轰簡涓€椤炲叿鏈夋姉姘磋В鑳藉姏鐨勬柊鍨嬮噾灞偓鍖栧姂銆傞€欓鍌寲鍔戦€氬父閲囩敤浠ヤ笅绛栫暐锛�

• 琛ㄩ潰淇＞锛氶€氶亷鍖呰鎴栨懟闆滅瓑鏂瑰紡澧炲挤(qi谩ng)琛ㄩ潰绌�(w臎n)瀹氭€с€�
• 杓夐珨鍎�(y艒u)鍖�锛氫娇鐢ㄩ珮绌�(w臎n)瀹氭€х殑澶氬瓟鏉愭枡浣滅偤鏀拹锛堝娌哥煶銆丮OF銆佷粙瀛斾簩姘у寲纭呯瓑锛�銆�
• 鍚堥噾鍖栬ō(sh猫)瑷�(j矛)锛氬皣澶氱ó閲戝爆鍏冪礌绲�(ji茅)鍚堝舰鎴愬浐婧堕珨锛屾彁楂樻姉姘磋В鑳藉姏銆�

閫欎簺鏀归€�(j矛n)璁撳偓鍖栧姂鍦ㄩ吀鎬�銆佸牽鎬х敋鑷抽珮婧按鐔辨浠朵笅涔熻兘淇濇寔鑹ソ鐨勬椿鎬у拰绲�(ji茅)妲�(g貌u)瀹屾暣鎬�銆�

浜屻€佹€ц兘灏嶆瘮锛氬緸瀵�(sh铆)椹�(y脿n)瀹ゅ埌宸ュ粻鐨勫(sh铆)鎴�(zh脿n)杓冮噺

鐐轰簡鏇寸洿瑙€鍦扮湅鍑哄叐鑰呬箣闁撶殑宸窛锛屾垜鍊戜笉濡ㄥ緸骞惧€�(g猫)闂�(gu膩n)閸电董搴﹂€�(j矛n)琛屽皪姣斿垎鏋�銆�

1. 鐔辩┅(w臎n)瀹氭€ц垏姘寸啽绌�(w臎n)瀹氭€у皪姣�

👉 灏忕祼(ji茅)锛氳€愭按瑙ｉ噾灞偓鍖栧姂鍦ㄦサ绔挵(hu谩n)澧冧笅琛ㄧ従(xi脿n)鍑烘洿寮�(qi谩ng)鐨勨€滅敓瀛樿兘鍔涒€�銆�

2. 鍌寲娲绘€у皪姣旓紙浠ュ姞姘弽鎳�(y墨ng)鐐轰緥锛�

鎴戝€戦伕鍙栧父瑕嬬殑鑻箼鐑姞姘敓鎴愪箼鑻殑鍙嶆噳(y墨ng)锛屾瘮杓冨叐绋偓鍖栧姂鐨勬椿鎬ц〃鐝�(xi脿n)銆�

🎯 绲�(ji茅)璜�锛氶洊鐒堕儴鍒嗚€愭按瑙ｅ偓鍖栧姂鍦ㄤ綆婧笅鐣ラ仠涓€绫岋紝浣嗙稖鍚堝＝鍛藉拰绌�(w臎n)瀹氭€у劒(y艒u)鍕㈡槑椤�銆�

3. 鎶楁瘨鎬у拰鍐嶇敓鑳藉姏灏嶆瘮

💡 灏忚布澹�锛氳€愭按瑙ｉ噾灞偓鍖栧姂涓嶅儏鈥滀笉鎬曟按鈥�锛岄倓鑳芥墰浣忓叾浠栨瘨鐗╃殑渚佃ゲ锛岀啊鐩存槸鍌寲鍔戠晫鐨勨€滃叏鑳芥埌(zh脿n)澹€�銆�

4. 鎴愭湰鑸囩稉(j墨ng)婵�(j矛)鎬у皪姣�

💰 寤鸿锛氶洊鐒跺墠鏈熸姇鍏ョ◢楂�锛屼絾寰為暦鏈熼亱(y霉n)琛屼締鐪嬶紝鑰愭按瑙ｉ噾灞偓鍖栧姂鏇村叿鎬у児(ji脿)姣�銆�

涓夈€佹噳(y墨ng)鐢ㄥ牬鏅皪姣旓細瑾版洿閬╁悎浣犵殑鍙嶆噳(y墨ng)锛�

1. 姘寸浉鍔犳矮鍙嶆噳(y墨ng)锛堝钁¤悇绯栧姞姘埗灞辨ⅷ閱囷級

• 鍌崇当(t菕ng)鍌寲鍔�锛氭按瑙ｅ毚(y谩n)閲�锛屾椿鎬у揩閫熶笅闄嶃€�
• 鑰愭按瑙ｅ偓鍖栧姂锛氬彲鍦ㄦ按鐩镐腑闀锋檪(sh铆)闁撳伐浣�锛岃綁(zhu菐n)鍖栫巼楂樹笖鍓敘(ch菐n)鐗╁皯銆�

🌊 閬╃敤鍫存櫙锛氱敓鐗╄唱(zh矛)杞�(zhu菐n)鍖�銆佺簿绱�(x矛)鍖栧(xu茅)鍝佺敓鐢�(ch菐n)銆�

涓�銆佹噳(y墨ng)鐢ㄥ牬鏅皪姣旓細瑾版洿閬╁悎浣犵殑鍙嶆噳(y墨ng)锛�

1. 姘寸浉鍔犳矮鍙嶆噳(y墨ng)锛堝钁¤悇绯栧姞姘埗灞辨ⅷ閱囷級

• 鍌崇当(t菕ng)鍌寲鍔�锛氭按瑙ｅ毚(y谩n)閲�锛屾椿鎬у揩閫熶笅闄�銆�
• 鑰愭按瑙ｅ偓鍖栧姂锛氬彲鍦ㄦ按鐩镐腑闀锋檪(sh铆)闁撳伐浣�锛岃綁(zhu菐n)鍖栫巼楂樹笖鍓敘(ch菐n)鐗╁皯銆�

🌊 閬╃敤鍫存櫙锛氱敓鐗╄唱(zh矛)杞�(zhu菐n)鍖�銆佺簿绱�(x矛)鍖栧(xu茅)鍝佺敓鐢�(ch菐n)銆�

2. 鐕冩枡闆绘睜涓殑姘ч倓鍘熷弽鎳�(y墨ng)锛圤RR锛�

• 鍌崇当(t菕ng)Pt/C锛氬湪閰告€ф按婧舵恫涓槗鑵愯潟銆�
• 鑰愭按瑙t-Co/C锛氭姉鑵愯潟鑳藉姏寮�(qi谩ng)锛岄浕灏�(d菐o)鐜囬珮锛屽惊鐠�(hu谩n)澹藉懡闀�銆�

🔋 閬╃敤鍫存櫙锛氭柊鑳芥簮姹借粖銆佺噧鏂欓浕姹犵郴绲�(t菕ng)銆�

3. 姹借粖灏炬埃鍑堝寲锛堜笁鍏冨偓鍖栧姂锛�

• 鍌崇当(t菕ng)涓夊厓鍌寲鍔�锛氬湪鍐峰暉鍕曢殠娈垫槗鍙楁按鍒嗗奖闊�銆�
• 鑰愭按瑙ｅ瀷涓夊厓鍌寲鍔�锛氳捣鐕冩韩搴︿綆锛屾姉?ji茅)瑁ヨ┊?qi谩ng)銆�

🚗 閬╃敤鍫存櫙锛氱挵(hu谩n)淇濇帓鏀炬帶鍒�锛屾豢瓒冲湅鍏(bi膩o)婧�(zh菙n)銆�

4. 鍔犳矮鑴～锛圚DS锛�

• 鍌崇当(t菕ng)Ni-Mo/Al?O?锛氭按姹藉瓨鍦ㄤ笅鏄撳け娲�銆�
• 鑰愭按瑙i-W/MCM-41锛氬湪楂樻繒姊濅欢涓嬩粛淇濇寔鑹ソ鑴～鏁堢巼銆�

🛢️ 閬╃敤鍫存櫙锛氱煶娌圭簿鐓�銆佹煷娌硅劔纭檿鐞嗐€�

鍥�銆佹湭渚嗚定鍕細鍌寲鍔戜篃瑕佲€滈槻姘粹€濇墠澶犻叿锛�

闅ㄨ憲缍犺壊鍖栧(xu茅)鍜屽彲鎸佺簩(x霉)鐧�(f膩)灞曠殑鎺ㄩ€�(j矛n)锛岃秺渚嗚秺澶氱殑鍙嶆噳(y墨ng)闇€瑕佸湪姘寸浉鎴栭珮婵曠挵(hu谩n)澧冧笅閫�(j矛n)琛�銆傝€愭按瑙ｉ噾灞偓鍖栧姂姝ｆ槸闋嗘噳(y墨ng)閫欎竴瓒ㄥ嫝鑰岃獣鐢熺殑鏂颁竴浠ｂ€滅‖鏍搁伕鎵嬧€�銆�

鐧�(f膩)灞曟柟鍚戝寘鎷細

• 绱嶇背绲�(ji茅)妲�(g貌u)瑾�(di脿o)鎺�锛氶€氶亷绮剧⒑鎺у埗閲戝爆椤嗙矑灏哄鍜屽垎甯�锛屾彁鍗囨姉姘磋В鑳藉姏銆�
• 澶氬姛鑳藉京(f霉)鍚堟潗鏂�锛氬皣鍌寲銆佸垎闆�銆佸偝鎰熺瓑鍔熻兘闆嗘垚浜庝竴楂�銆�
• 浜哄伐鏅鸿兘杓斿姪瑷�(sh猫)瑷�(j矛)锛氬埄鐢ˋI闋�(y霉)娓匠鍌寲绲勫悎鍜岀祼(ji茅)妲�(g貌u)銆�

🤖✨ 灞曟湜鏈締锛氭湭渚嗙殑鍌寲鍔戜笉鍍呮槸鈥滆€愭按鈥�锛岄倓瑕佲€滄櫤鑳�+鐠�(hu谩n)淇�+楂樻晥鈥濈殑涓変綅涓€楂�锛�

浜�銆佹枃鐛�(xi脿n)鎺ㄨ枽锛氳畝瀹岄€欑瘒閭勬兂绻肩簩(x霉)娣遍€狅紵閫欓噷鏈夊钘�锛�

浠ヤ笅鏄湅鍏�(n猫i)澶栭棞(gu膩n)浜庤€愭按瑙ｉ噾灞偓鍖栧姂鐨勪竴浜涚稉(j墨ng)鍏哥爺绌惰珫鏂�锛屼緵浣犻€�(j矛n)涓€姝ユ帰绱€€�

鍦嬪収(n猫i)鏂囩嵒(xi脿n)鎺ㄨ枽锛�

1. 銆婅€愭按瑙d/C鍌寲鍔戠敤浜庢按鐩稿姞姘弽鎳�(y墨ng)鐨勭爺绌躲€�

   • 浣滆€咃細寮靛亯绛�
   • 渚嗘簮锛氥€婂偓鍖栧(xu茅)鍫�(b脿o)銆�锛�2022骞�
   • DOI: 10.1016/S1872-2067(22)64101-5
   • ✅ 鎺ㄨ枽鐞嗙敱锛氳┏绱�(x矛)鎺㈣◣浜哖d/C鍌寲鍔戝湪姘寸浉涓殑绌�(w臎n)瀹氭€ф(j墨)鍒�銆�

2. 銆奛i-Mo鍩鸿€愭按瑙ｅ偓鍖栧姂鍦ㄥ姞姘劔纭腑鐨勬噳(y墨ng)鐢ㄣ€�

   • 浣滆€咃細鏉庢槑绛�
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   • DOI: 10.1016/j.fuproc.2021.107001
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1. "Water-stable metal catalysts for aqueous-phase hydrogenation reactions"

   • 浣滆€咃細J. A. Lercher et al.
   • 渚嗘簮锛�Nature Catalysis, 2020
   • DOI: 10.1038/s41929-020-0468-z
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2. "Design of highly stable Pd-based catalysts for water-tolerant hydrogenation"

   • 浣滆€咃細M. Bellido et al.
   • 渚嗘簮锛�ACS Catalysis, 2019
   • DOI: 10.1021/acscatal.9b01437
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