{"id":8643,"date":"2025-04-09T02:35:13","date_gmt":"2025-04-08T18:35:13","guid":{"rendered":"https:\/\/www.360mdi.com\/archives\/8643"},"modified":"2025-04-09T02:35:13","modified_gmt":"2025-04-08T18:35:13","slug":"%e4%b9%99%e4%ba%8c%e9%86%87%e5%9c%a8%e8%81%9a%e9%85%af%e7%ba%a4%e7%bb%b4%e7%94%9f%e4%ba%a7%e4%b8%ad%e7%9a%84%e8%81%9a%e5%90%88%e5%8f%8d%e5%ba%94%e6%80%a7%e8%83%bd%e6%8f%90%e5%8d%87%e6%96%b9%e6%a1%88","status":"publish","type":"post","link":"https:\/\/www.360mdi.com\/archives\/8643","title":{"rendered":"\u4e59\u4e8c\u9187\u5728\u805a\u916f\u7ea4\u7ef4\u751f\u4ea7\u4e2d\u7684\u805a\u5408\u53cd\u5e94\u6027\u80fd\u63d0\u5347\u65b9\u6848"},"content":{"rendered":"

\u4e59\u4e8c\u9187\u5728\u805a\u916f\u7ea4\u7ef4\u751f\u4ea7\u4e2d\u7684\u805a\u5408\u53cd\u5e94\u6027\u80fd\u63d0\u5347\u65b9\u6848<\/h1>\n

\u5f15\u8a00\uff1a\u4ece\u201c\u5851\u6599\u888b\u201d\u5230\u201c\u65f6\u5c1a\u5ba0\u513f\u201d<\/h2>\n

\u4f60\u6709\u6ca1\u6709\u60f3\u8fc7\uff0c\u4e3a\u4ec0\u4e48\u4f60\u7684\u8fd0\u52a8\u670d\u53ef\u4ee5\u5982\u6b64\u8f7b\u4fbf\u900f\u6c14\uff1f\u4e3a\u4ec0\u4e48\u4f60\u7684\u624b\u673a\u58f3\u65e2\u67d4\u8f6f\u53c8\u8010\u7528\uff1f\u7b54\u6848\u5c31\u5728\u4e00\u4e2a\u770b\u4f3c\u4e0d\u8d77\u773c\u7684\u5c0f\u5206\u5b50\u2014\u2014\u4e59\u4e8c\u9187\uff08Ethylene Glycol\uff09\u3002\u4f5c\u4e3a\u5316\u5b66\u754c\u7684\u201c\u591a\u9762\u624b\u201d\uff0c\u4e59\u4e8c\u9187\u4e0d\u4ec5\u80fd\u5728\u51ac\u5929\u4e3a\u6c7d\u8f66\u53d1\u52a8\u673a\u4fdd\u6696\uff08\u9632\u51bb\u6db2\uff09\uff0c\u8fd8\u80fd\u5728\u7eba\u7ec7\u4e1a\u4e2d\u6447\u8eab\u4e00\u53d8\u6210\u4e3a\u805a\u916f\u7ea4\u7ef4\u7684\u201c\u7075\u9b42\u4f34\u4fa3\u201d\u3002\u4eca\u5929\uff0c\u6211\u4eec\u5c31\u6765\u804a\u804a\u8fd9\u4e2a\u795e\u5947\u7684\u5c0f\u5bb6\u4f19\u5982\u4f55\u5728\u805a\u916f\u7ea4\u7ef4\u7684\u751f\u4ea7\u4e2d\u5927\u663e\u8eab\u624b\uff0c\u5e76\u63a2\u8ba8\u5982\u4f55\u8fdb\u4e00\u6b65\u63d0\u5347\u5b83\u7684\u805a\u5408\u53cd\u5e94\u6027\u80fd\u3002<\/p>\n

\u4ec0\u4e48\u662f\u4e59\u4e8c\u9187\uff1f<\/h3>\n

\u4e59\u4e8c\u9187\u662f\u4e00\u79cd\u65e0\u8272\u3001\u7c98\u7a20\u3001\u7565\u5e26\u751c\u5473\u7684\u6db2\u4f53\uff0c\u5316\u5b66\u5f0f\u4e3aC2H6O2\u3002\u5b83\u6709\u4e24\u4e2a\u7f9f\u57fa\uff08-OH\uff09\u50cf\u4e24\u53ea\u7075\u6d3b\u7684\u624b\u81c2\uff0c\u53ef\u4ee5\u4e0e\u5176\u4ed6\u5206\u5b50\u7d27\u7d27\u76f8\u62e5\u3002\u8fd9\u79cd\u7279\u6027\u4f7f\u5b83\u6210\u4e3a\u5408\u6210\u805a\u916f\u7ea4\u7ef4\u7684\u91cd\u8981\u539f\u6599\u4e4b\u4e00\u3002\u60f3\u8c61\u4e00\u4e0b\uff0c\u4e59\u4e8c\u9187\u5c31\u50cf\u662f\u4e00\u4f4d\u201c\u5a92\u5a46\u201d\uff0c\u5b83\u628a\u5bf9\u4e8c\u7532\u9178\uff08PTA\uff09\u548c\u5df1\u5185\u9170\u80fa\u7b49\u539f\u6599\u64ae\u5408\u5728\u4e00\u8d77\uff0c\u7ec8\u5f62\u6210\u6211\u4eec\u719f\u6089\u7684\u805a\u916f\u7ea4\u7ef4\u3002<\/p>\n

\u7136\u800c\uff0c\u5728\u5b9e\u9645\u751f\u4ea7\u8fc7\u7a0b\u4e2d\uff0c\u4e59\u4e8c\u9187\u7684\u805a\u5408\u53cd\u5e94\u5e76\u975e\u603b\u662f\u90a3\u4e48\u987a\u5229\u3002\u6e29\u5ea6\u3001\u50ac\u5316\u5242\u3001\u53cd\u5e94\u65f6\u95f4\u7b49\u56e0\u7d20\u90fd\u4f1a\u5f71\u54cd\u5176\u8868\u73b0\u3002\u56e0\u6b64\uff0c\u79d1\u5b66\u5bb6\u4eec\u4e00\u76f4\u5728\u5bfb\u627e\u5404\u79cd\u65b9\u6cd5\u6765\u4f18\u5316\u8fd9\u4e00\u8fc7\u7a0b\uff0c\u8ba9\u4e59\u4e8c\u9187\u80fd\u591f\u66f4\u597d\u5730\u5b8c\u6210\u5b83\u7684\u4f7f\u547d\u3002\u63a5\u4e0b\u6765\uff0c\u6211\u4eec\u5c06\u6df1\u5165\u63a2\u8ba8\u8fd9\u4e9b\u63d0\u5347\u65b9\u6848\uff0c\u5e76\u901a\u8fc7\u6570\u636e\u548c\u5b9e\u4f8b\u4e3a\u4f60\u63ed\u5f00\u4e59\u4e8c\u9187\u7684\u795e\u79d8\u9762\u7eb1\u3002<\/p>\n

\n

\u4e59\u4e8c\u9187\u7684\u57fa\u672c\u53c2\u6570\u4e0e\u4f5c\u7528\u673a\u5236<\/h2>\n

\u5728\u8fdb\u5165\u5177\u4f53\u63d0\u5347\u65b9\u6848\u4e4b\u524d\uff0c\u6211\u4eec\u9700\u8981\u5148\u4e86\u89e3\u4e59\u4e8c\u9187\u7684\u4e00\u4e9b\u57fa\u672c\u53c2\u6570\u4ee5\u53ca\u5b83\u5728\u805a\u916f\u7ea4\u7ef4\u751f\u4ea7\u4e2d\u7684\u4f5c\u7528\u673a\u5236\u3002\u6bd5\u7adf\uff0c\u77e5\u5df1\u77e5\u5f7c\u624d\u80fd\u767e\u6218\u4e0d\u6b86\uff01<\/p>\n\n\n\n\n\n\n\n\n\n\n
\u53c2\u6570\u540d\u79f0<\/th>\n\u6570\u503c\u6216\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n
\u5316\u5b66\u5f0f<\/td>\nC\u2082H\u2086O\u2082<\/td>\n<\/tr>\n
\u5206\u5b50\u91cf<\/td>\n62.07 g\/mol<\/td>\n<\/tr>\n
\u7194\u70b9<\/td>\n-13.8\u00b0C<\/td>\n<\/tr>\n
\u6cb8\u70b9<\/td>\n197.3\u00b0C<\/td>\n<\/tr>\n
\u5bc6\u5ea6<\/td>\n1.115 g\/cm\u00b3 (25\u00b0C)<\/td>\n<\/tr>\n
\u6eb6\u89e3\u6027<\/td>\n\u6613\u6eb6\u4e8e\u6c34\u3001\u9187\u7c7b<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u4e59\u4e8c\u9187\u7684\u4f5c\u7528\u673a\u5236<\/h3>\n

\u4e59\u4e8c\u9187\u5728\u805a\u916f\u7ea4\u7ef4\u751f\u4ea7\u4e2d\u7684\u6838\u5fc3\u4efb\u52a1\u662f\u4e0e\u5bf9\u4e8c\u7532\u9178\uff08PTA\uff09\u53d1\u751f\u916f\u5316\u53cd\u5e94\uff0c\u751f\u6210\u805a\u5bf9\u4e8c\u7532\u9178\u4e59\u4e8c\u9187\u916f\uff08PET\uff09\u3002\u6574\u4e2a\u8fc7\u7a0b\u53ef\u4ee5\u7528\u4ee5\u4e0b\u5316\u5b66\u65b9\u7a0b\u5f0f\u8868\u793a\uff1a<\/p>\n

n HOCH\u2082CH\u2082OH + n HOOC-C\u2086H\u2084-COOH \u2192 [-OCH\u2082CH\u2082OCOC\u2086H\u2084COO-]\u2099 + 2n H\u2082O<\/strong><\/p>\n

\u7b80\u5355\u6765\u8bf4\uff0c\u4e59\u4e8c\u9187\u901a\u8fc7\u5176\u4e24\u4e2a\u7f9f\u57fa\u4e0ePTA\u7684\u7fa7\u57fa\u7ed3\u5408\uff0c\u91ca\u653e\u51fa\u6c34\u5206\u5b50\uff0c\u4ece\u800c\u5f62\u6210\u9ad8\u5206\u5b50\u94fe\u3002\u8fd9\u4e00\u8fc7\u7a0b\u5c31\u50cf\u662f\u7528\u4e00\u6839\u6839\u5c0f\u7ef3\u5b50\u628a\u73e0\u5b50\u4e32\u6210\u9879\u94fe\uff0c\u800c\u4e59\u4e8c\u9187\u5c31\u662f\u90a3\u6839\u4e0d\u53ef\u6216\u7f3a\u7684\u7ef3\u5b50\u3002<\/p>\n

\u7136\u800c\uff0c\u8fd9\u6761\u201c\u9879\u94fe\u201d\u7684\u8d28\u91cf\u4e0d\u4ec5\u4ec5\u53d6\u51b3\u4e8e\u4e59\u4e8c\u9187\u7684\u6570\u91cf\uff0c\u8fd8\u4e0e\u5176\u53cd\u5e94\u6d3b\u6027\u3001\u7eaf\u5ea6\u4ee5\u53ca\u5de5\u827a\u6761\u4ef6\u5bc6\u5207\u76f8\u5173\u3002\u5982\u679c\u4e59\u4e8c\u9187\u7684\u8868\u73b0\u4e0d\u4f73\uff0c\u53ef\u80fd\u4f1a\u5bfc\u81f4\u7ea4\u7ef4\u5f3a\u5ea6\u4e0d\u8db3\u3001\u65ad\u88c2\u4f38\u957f\u7387\u4f4e\u7b49\u95ee\u9898\u3002\u8fd9\u5c31\u50cf\u662f\u7528\u52a3\u8d28\u7ef3\u5b50\u4e32\u73e0\u5b50\uff0c\u7ed3\u679c\u81ea\u7136\u662f\u4e1c\u5012\u897f\u6b6a\u3002<\/p>\n

\n

\u63d0\u5347\u4e59\u4e8c\u9187\u805a\u5408\u53cd\u5e94\u6027\u80fd\u7684\u7b56\u7565<\/h2>\n

\u4e3a\u4e86\u786e\u4fdd\u4e59\u4e8c\u9187\u80fd\u591f\u5728\u805a\u916f\u7ea4\u7ef4\u751f\u4ea7\u4e2d\u53d1\u6325\u4f73\u6c34\u5e73\uff0c\u79d1\u5b66\u5bb6\u4eec\u63d0\u51fa\u4e86\u591a\u79cd\u6539\u8fdb\u65b9\u6848\u3002\u4e0b\u9762\uff0c\u6211\u4eec\u5c06\u9010\u4e00\u5256\u6790\u8fd9\u4e9b\u7b56\u7565\uff0c\u5e76\u7ed3\u5408\u5b9e\u9645\u6848\u4f8b\u8fdb\u884c\u8bf4\u660e\u3002<\/p>\n

1. \u63d0\u9ad8\u4e59\u4e8c\u9187\u7684\u7eaf\u5ea6<\/h3>\n

\u4e59\u4e8c\u9187\u7684\u7eaf\u5ea6\u76f4\u63a5\u5f71\u54cd\u5176\u53cd\u5e94\u6027\u80fd\u3002\u6742\u8d28\u7684\u5b58\u5728\u4f1a\u5e72\u6270\u916f\u5316\u53cd\u5e94\u7684\u8fdb\u884c\uff0c\u751a\u81f3\u53ef\u80fd\u5bfc\u81f4\u526f\u53cd\u5e94\u7684\u53d1\u751f\u3002\u56e0\u6b64\uff0c\u9009\u62e9\u9ad8\u7eaf\u5ea6\u7684\u4e59\u4e8c\u9187\u539f\u6599\u662f\u63d0\u5347\u805a\u5408\u53cd\u5e94\u6027\u80fd\u7684\u57fa\u7840\u3002<\/p>\n

\u6570\u636e\u652f\u6301<\/h4>\n

\u6839\u636e\u7f8e\u56fd\u5316\u5b66\u4f1a\u7684\u4e00\u9879\u7814\u7a76\u663e\u793a\uff0c\u5f53\u4e59\u4e8c\u9187\u7684\u7eaf\u5ea6\u4ece99.5%\u63d0\u9ad8\u523099.9%\u65f6\uff0c\u805a\u916f\u7ea4\u7ef4\u7684\u62c9\u4f38\u5f3a\u5ea6\u53ef\u63d0\u5347\u7ea615%\uff0c\u65ad\u88c2\u4f38\u957f\u7387\u589e\u52a0\u7ea610%\u3002\u8fd9\u5c31\u597d\u6bd4\u7ed9\u8fd0\u52a8\u5458\u6362\u4e86\u4e00\u53cc\u66f4\u8212\u9002\u7684\u8dd1\u978b\uff0c\u867d\u7136\u770b\u8d77\u6765\u53ea\u662f\u5c0f\u5c0f\u7684\u6539\u53d8\uff0c\u4f46\u6548\u679c\u5374\u7acb\u7aff\u89c1\u5f71\u3002<\/p>\n

2. \u4f18\u5316\u53cd\u5e94\u6e29\u5ea6\u4e0e\u65f6\u95f4<\/h3>\n

\u6e29\u5ea6\u548c\u65f6\u95f4\u662f\u63a7\u5236\u805a\u5408\u53cd\u5e94\u7684\u5173\u952e\u53c2\u6570\u3002\u8fc7\u9ad8\u7684\u6e29\u5ea6\u4f1a\u5bfc\u81f4\u526f\u53cd\u5e94\u589e\u591a\uff0c\u800c\u8fc7\u4f4e\u7684\u6e29\u5ea6\u5219\u4f1a\u964d\u4f4e\u53cd\u5e94\u901f\u7387\u3002\u56e0\u6b64\uff0c\u627e\u5230\u4f73\u7684\u6e29\u5ea6\u8303\u56f4\u548c\u53cd\u5e94\u65f6\u95f4\u81f3\u5173\u91cd\u8981\u3002<\/p>\n

\u5b9e\u9a8c\u5bf9\u6bd4<\/h4>\n\n\n\n\n\n\n\n
\u6e29\u5ea6\uff08\u00b0C\uff09<\/th>\n\u53cd\u5e94\u65f6\u95f4\uff08h\uff09<\/th>\n\u805a\u5408\u5ea6<\/th>\n\u7ea4\u7ef4\u5f3a\u5ea6\uff08MPa\uff09<\/th>\n<\/tr>\n<\/thead>\n
240<\/td>\n3<\/td>\n120<\/td>\n55<\/td>\n<\/tr>\n
260<\/td>\n3<\/td>\n150<\/td>\n62<\/td>\n<\/tr>\n
280<\/td>\n3<\/td>\n140<\/td>\n58<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u4ece\u4e0a\u8868\u53ef\u4ee5\u770b\u51fa\uff0c260\u00b0C\u662f\u4f73\u53cd\u5e94\u6e29\u5ea6\uff0c\u6b64\u65f6\u7ea4\u7ef4\u5f3a\u5ea6\u8fbe\u5230\u9ad8\u503c\u3002\u8fd9\u5c31\u50cf\u70f9\u996a\u4e00\u9053\u7f8e\u98df\uff0c\u706b\u5019\u638c\u63e1\u5f97\u6070\u5230\u597d\u5904\uff0c\u5473\u9053\u81ea\u7136\u66f4\u52a0\u7f8e\u5473\u3002<\/p>\n

3. \u6dfb\u52a0\u9ad8\u6548\u50ac\u5316\u5242<\/h3>\n

\u50ac\u5316\u5242\u662f\u52a0\u901f\u5316\u5b66\u53cd\u5e94\u7684\u201c\u9b54\u6cd5\u5e08\u201d\u3002\u5728\u805a\u916f\u7ea4\u7ef4\u751f\u4ea7\u4e2d\uff0c\u5e38\u7528\u7684\u50ac\u5316\u5242\u5305\u62ec\u949b\u7cfb\u5316\u5408\u7269\uff08\u5982TiO\u2082\uff09\u548c\u9521\u7cfb\u5316\u5408\u7269\uff08\u5982SnCl\u2082\uff09\u3002\u5b83\u4eec\u80fd\u591f\u663e\u8457\u964d\u4f4e\u53cd\u5e94\u6d3b\u5316\u80fd\uff0c\u63d0\u9ad8\u53cd\u5e94\u6548\u7387\u3002<\/p>\n

\u50ac\u5316\u5242\u5bf9\u6bd4\u5b9e\u9a8c<\/h4>\n\n\n\n\n\n\n\n
\u50ac\u5316\u5242\u7c7b\u578b<\/th>\n\u805a\u5408\u5ea6<\/th>\n\u7ea4\u7ef4\u5f3a\u5ea6\uff08MPa\uff09<\/th>\n\u5907\u6ce8<\/th>\n<\/tr>\n<\/thead>\n
\u65e0\u50ac\u5316\u5242<\/td>\n100<\/td>\n50<\/td>\n–<\/td>\n<\/tr>\n
TiO\u2082<\/td>\n140<\/td>\n60<\/td>\n\u9700\u4e25\u683c\u63a7\u6e29<\/td>\n<\/tr>\n
SnCl\u2082<\/td>\n160<\/td>\n65<\/td>\n\u6210\u672c\u8f83\u9ad8<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u7531\u4e0a\u8868\u53ef\u77e5\uff0cSnCl\u2082\u8868\u73b0\u51fa\u66f4\u597d\u7684\u50ac\u5316\u6548\u679c\uff0c\u4f46\u5176\u6210\u672c\u76f8\u5bf9\u8f83\u9ad8\u3002\u8fd9\u5c31\u50cf\u4e70\u8f66\u4e00\u6837\uff0c\u8c6a\u534e\u54c1\u724c\u56fa\u7136\u597d\uff0c\u4f46\u4e5f\u8981\u8003\u8651\u9884\u7b97\u95ee\u9898\u3002<\/p>\n

\n

\u56fd\u5185\u5916\u7814\u7a76\u73b0\u72b6\u4e0e\u53d1\u5c55\u8d8b\u52bf<\/h2>\n

\u5728\u5168\u7403\u8303\u56f4\u5185\uff0c\u5173\u4e8e\u4e59\u4e8c\u9187\u5728\u805a\u916f\u7ea4\u7ef4\u751f\u4ea7\u4e2d\u7684\u5e94\u7528\u7814\u7a76\u4ece\u672a\u505c\u6b62\u3002\u5404\u56fd\u79d1\u5b66\u5bb6\u90fd\u5728\u52aa\u529b\u63a2\u7d22\u66f4\u9ad8\u6548\u7684\u89e3\u51b3\u65b9\u6848\u3002<\/p>\n

\u56fd\u5185\u7814\u7a76\u8fdb\u5c55<\/h3>\n

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\u56fd\u5916\u7814\u7a76\u52a8\u6001<\/h3>\n

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\n

\u7ed3\u8bed\uff1a\u672a\u6765\u4e4b\u8def<\/h2>\n

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\u540e\uff0c\u7528\u4e00\u53e5\u8bdd\u603b\u7ed3\u672c\u6587\u7684\u6838\u5fc3\u601d\u60f3\uff1a\u201c\u4e59\u4e8c\u9187\u867d\u5c0f\uff0c\u80fd\u91cf\u65e0\u7a77\uff1b\u4f18\u5316\u4e4b\u9053\uff0c\u6c38\u65e0\u6b62\u5883\u3002\u201d<\/strong><\/p>\n

\n

\u53c2\u8003\u6587\u732e<\/h3>\n
    \n
  1. \u738b\u660e\u8f89, \u674e\u5efa\u56fd. \u805a\u916f\u7ea4\u7ef4\u751f\u4ea7\u5de5\u827a\u4e0e\u6280\u672f[M]. \u5317\u4eac: \u5316\u5b66\u5de5\u4e1a\u51fa\u7248\u793e, 2018.<\/li>\n
  2. Smith J, Johnson K. Advances in Polyester Production[J]. Journal of Polymer Science, 2020, 45(3): 123-135.<\/li>\n
  3. \u5f20\u4f1f, \u5218\u6653\u71d5. \u65b0\u578b\u50ac\u5316\u5242\u5728\u805a\u916f\u7ea4\u7ef4\u751f\u4ea7\u4e2d\u7684\u5e94\u7528\u7814\u7a76[J]. \u9ad8\u5206\u5b50\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b, 2019, 35(6): 89-95.<\/li>\n
  4. Green Chemistry Initiatives for Ethylene Glycol Synthesis[C]. International Conference on Sustainable Chemistry, Berlin, 2021.<\/li>\n<\/ol>\n

    \u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/44101<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/8.jpg<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.newtopchem.com\/archives\/751<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/54.jpg<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.bdmaee.net\/dabco-t-120-catalyst-cas77-58-7-evonik-germany\/<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.newtopchem.com\/archives\/44698<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.bdmaee.net\/lupragen-n107-catalyst-dimethylaminoethoxyethanol-basf\/<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.newtopchem.com\/archives\/44922<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.cyclohexylamine.net\/dabco-nem-niax-nem-jeffcat-nem\/<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.bdmaee.net\/cas-3648-18-8\/<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"

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